Exam 6: Thermochemistry

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Octane (C8H18)undergoes combustion according to the following thermochemical equation: 2C8H18(l)+ 25O2(g) →\rarr 16CO2(g)+ 18H2O(l) Δ\Delta H°rxn = -11,020 kJ/mol. Given that Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol and Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, calculate the standard enthalpy of formation of octane.

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Find Δ\Delta H°rxn for the reaction CH4(g)+ 2O2(g) →\rarr CO2(g)+ 2H2O(l). [ Δ\Delta H°f (CH4(g))= -74.8 kJ/mol; Δ\Delta H°f (CO2(g))= -393.5 kJ/mol; Δ\Delta H°f (H2O(l))= -285.5 kJ/mol]

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Thermal energy is

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The heat of solution of NH4NO3 is 26.2 kJ/mol.Is heat evolved or absorbed when a solution of NH4NO3 is diluted by addition of more water?

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A beaker contains 115 g of ethanol at 18.2°C.If the ethanol absorbs 1125 J of heat without losing heat to the surroundings, what will be the final temperature of the ethanol? The specific heat of ethanol is 2.46 J/g.°C.

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The heat of solution of calcium chloride CaCl2 is -82.8 kJ/mol, and the combined heats of hydration of 1.00 mole of gaseous calcium ions and 2.00 mole of gaseous chloride ions is -2327 kJ.What is the lattice energy of calcium chloride?

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Determine the heat given off to the surroundings when 9.0 g of aluminum reacts according to the equation 2Al + Fe2O3 →\rarr Al2O3 + 2Fe, Δ\Delta H°rxn= -849 kJ/mol.

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A 22.0 g block of copper at 45°C absorbs 2.50 kJ of heat.Given the specific heat of Cu is 0.385 J/g·°C what will be the final temperature of the Cu?

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The specific heat of gold is 0.129 J/g·°C.What is the molar heat capacity of gold?

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Acetylene (C2H2)undergoes combustion in excess oxygen to generate gaseous carbon dioxide and water.Given Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol, Δ\Delta H°f[H2O(g)] = -241.8 kJ/mol, and Δ\Delta H°f [C2H2(g)] = 226.6 kJ/mol, how much energy is released (kJ)when 10.5 moles of acetylene is burned?

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For which of these reactions will the difference between Δ\Delta H° and Δ\Delta E° be the greatest?

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A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter.The temperature of the calorimeter and the 1.000 kg of water contained therein rose from 20.22°C to 22.82°C.The heat capacity of the calorimeter is 2.21 kJ/°C.The heat capacity of water = 4.184 J/g·°C.How much heat was given off during combustion of the sample of pentane?

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Which of the following processes is exothermic, given the following: N2(g)+ 2 O2(g) →\rarr N2O4(l) Δ\Delta H° = 9.67 kJ/mol N2(g)+ 2 O2(g) →\rarr 2 NO2(g) Δ\Delta H° = 67.70 kJ/mol

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A gas is compressed in a cylinder from a volume of 20.0 L to 2.0 L by a constant pressure of 10.0 atm.Calculate the amount of work done on the system.

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Ethanol undergoes combustion in oxygen to produce carbon dioxide gas and liquid water.The standard heat of combustion of ethanol, C2H5OH(l), is -1366.8 kJ/mol.Given that Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol and Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, what is the standard enthalpy of formation of ethanol?

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A 0.1326 g sample of magnesium was burned in an oxygen bomb calorimeter.The total heat capacity of the calorimeter plus water was 5,760 J/°C.If the temperature rise of the calorimeter with water was 0.570°C, calculate the enthalpy of combustion of magnesium. Mg(s)+ 1/2O2(g) →\rarr MgO(s)

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Aluminum metal has a specific heat of 0.900 J/g·°C.Calculate the amount of heat required to raise the temperature of 10.5 moles of Al from 30.5 °C to 225°C.

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Find the standard enthalpy of formation of ethylene, C2H4(g), given the following data: heat of combustion of C2H4(g) = -1411 kJ/mol; Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol; Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol.

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Calculate the amount of heat necessary to raise the temperature of 135.0 g of water from 50.4°F to 85.0°F.The specific heat of water = 4.184 J/g·°C.

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Chemical energy is

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