Exam 6: Thermochemistry

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Calculate the heat released (kJ)in the reaction of 3.50 g of acetylene (C2H2)and excess hydrogen gas to form ethane gas: C2H2(g)+ 2H2(g) →\rarr C2H6(g) Given: 2C2H2(g)+ 5O2(g) →\rarr 4CO2(g)+ 2H2O(g), Δ\Delta H = -2320 kJ/mol 2C2H6(g)+ 7O2(g) →\rarr 4CO2(g)+ 6H2O(g), Δ\Delta H = -3040 kJ/mol 2H2(g)+ O2(g) →\rarr 2H2O(g), Δ\Delta H = -572 kJ/mol

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The total heat of hydration of 1.00 mol of gas phase Li+ ions and Cl - ions is -865 kJ.The lattice energy of LiCl(s)is 828 kJ/mol.Calculate the heat of solution of LiCl.

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Given 2Al(s)+ (3/2)O2(g) →\rarr Al2O3(s), Δ\Delta H°f = -1,670 kJ/mol for Al2O3 (s). Determine Δ\Delta H° for the reaction 2Al2O3(s) →\rarr 4Al(s)+ 3O2(g).

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Given the specific heat for aluminum is 0.900 J/g·°C, how much heat is released when a 3.8 g sample of Al cools from 450.0°C to 25°C.

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The specific heat of silver is 0.235 J/g·°C.How many joules of heat are required to heat a 75 g silver spoon from 20°C to 35°C?

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Glycine, C2H5O2N, is important for biological energy.The combustion reaction of glycine is given by the equation 4C2H5O2N(s)+ 9O2(g) →\rarr 8CO2(g)+ 10H2O(l)+ 2N2(g) Δ\Delta H°rxn = -3857 kJ/mol Given that Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol and Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, calculate the enthalpy of formation of glycine.

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The heat of combustion of propane, C3H8, 2220 kJ/mol.The specific heat of copper is 0.385 J/g.°C.How many grams of propane must be burned to raise the temperature of a 10.0 kg block of copper from 25.0°C to 65.0°C, assuming none of the heat is lost to the surroundings

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The value of Δ\Delta H°rxn for the following reaction is -6535 kJ/mol. 2C6H6(l)+ 15O2(g) →\rarr 12CO2(g)+ 6H2O(g) How many kilojoules of heat will be evolved during the combustion of 16.0 g of C6H6(l)?

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How many grams of ethylene (C2H4)would have to be burned to produce 450 kJ of heat? C2H4(g)+ 3O2(g) →\rarr 2CO2(g)+ H2O(l), Δ\Delta H°rxn = -1411 kJ/mol

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A 0.1946 g piece of magnesium metal is burned in a constant-volume calorimeter that has a heat capacity of 1349 J/°C.The calorimeter contains 500.g of water and the temperature rise is 1.40°C.Calculate the heat of combustion of magnesium metal in kJ/g, given that the specific heat of water = 4.184 J/g·°C.

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A 26.2 g piece of copper metal is heated from 21.5°C to 201.6°C.Calculate the amount of heat absorbed by the metal.The specific heat of Cu is 0.385 J/g·°C.

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The heat of solution of ammonium chloride is 15.2 kJ/mol.If a 6.134 g sample of NH4Cl is added to 65.0 mL of water in a calorimeter at 24.5°C, what is the minimum temperature reached by the solution? (The specific heat of water = 4.18 J/g·°C; the heat capacity of the calorimeter = 365.J/°C.)

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Calculate the heat required when 2.50 mol of A reacts with excess B and A2B according to the reaction: 2A + B + A2B →\rarr 2AB + A2 Given:  Calculate the heat required when 2.50 mol of A reacts with excess B and A<sub>2</sub>B according to the reaction: 2A + B + A<sub>2</sub>B  \rarr  2AB + A<sub>2</sub> <sub> </sub>Given:

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When 18.5 g of HgO(s)is decomposed to form Hg(l)and O2(g), 7.75 kJ of heat is absorbed at standard-state conditions.What is the standard enthalpy of formation ( Δ\Delta H°f)of HgO(s)?

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Which of the following has a Δ\Delta H°f = 0 kJ/mol?

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Suppose a 50.0 g block of silver (specific heat = 0.2350 J/g·°C)at 100°C is placed in contact with a 50.0 g block of iron (specific heat = 0.4494 J/g·°C)at 0°C, and the two blocks are insulated from the rest of the universe.The final temperature of the two blocks

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The combustion of pentane produces heat according to the equation C5H12(l)+ 8O2(g) →\rarr 5CO2(g)+ 6H2O(l), Δ\Delta H°rxn= -3,510 kJ/mol How many grams of CO2 are produced per 2.50 × 103 kJ of heat released?

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At 25°C, the following heats of reaction are known:  At 25°C, the following heats of reaction are known:      At the same temperature, use the above data to calculate the heat released (kJ)when 3.40 moles of ClF(g)reacts with excess F<sub>2</sub>: ClF(g)+ F<sub>2</sub>(g) \rarr  ClF<sub>3</sub>(g) At the same temperature, use the above data to calculate the heat released (kJ)when 3.40 moles of ClF(g)reacts with excess F2: ClF(g)+ F2(g) →\rarr ClF3(g)

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The heat of solution of LiCl is -37.1 kJ/mol, and the lattice energy of LiCl(s)is 828 kJ/mol.Calculate the total heat of hydration of 1.00 mol of gas phase Li+ ions and Cl- ions.

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