Exam 6: Thermochemistry
Exam 1: Chemistry: the Study of Change168 Questions
Exam 2: Atoms, Molecules, and Ions156 Questions
Exam 3: Mass Relationships in Chemical Reactions194 Questions
Exam 4: Reactions in Aqueous Solutions186 Questions
Exam 5: Gases121 Questions
Exam 6: Thermochemistry118 Questions
Exam 7: Quantum Theory and the Electronic Structure of Atoms136 Questions
Exam 8: Periodic Relationships Among the Elements144 Questions
Exam 9: Chemical Bonding I: Basic Concepts137 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals147 Questions
Exam 11: Intermolecular Forces and Liquids and Solids149 Questions
Exam 12: Physical Properties of Solutions122 Questions
Exam 13: Chemical Kinetics130 Questions
Exam 14: Chemical Equilibrium109 Questions
Exam 15: Acids and Bases178 Questions
Exam 16: Acid-Base Equilibria and Solubility Equilibria131 Questions
Exam 17: Entropy Free Energy and Equilibrium128 Questions
Exam 18: Electrochemistry154 Questions
Exam 19: Nuclear Chemistry133 Questions
Exam 20: Chemistry in the Atmosphere50 Questions
Exam 21: Metallurgy and the Chemistry of Metals63 Questions
Exam 22: Nonmetallic Elements and Their Compounds52 Questions
Exam 23: Transition Metal Chemistry and Coordination Compounds92 Questions
Exam 24: Organic Chemistry67 Questions
Exam 25: Synthetic and Natural Organic Polymers50 Questions
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Given the following H° values,
H2(g)+
O2(g) H2O(l), H°f = -285.8 kJ/mol
H2O2(l), H2(g)+ O2(g), H°rxn = 187.6 kJ/mol
calculate H°rxn for the reaction H2O2(l) H2O(l)+
O2(g),
(Short Answer)
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Calcium oxide and water react in an exothermic reaction: CaO(s)+ H2O(l) Ca(OH)2(s), H°rxn = -64.8 kJ/mol
How much heat would be liberated when 7.15 g CaO(s)is dropped into a beaker containing 152g H2O?
(Multiple Choice)
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Calculate the standard enthalpy change for the reaction
2C8H18(l)+ 21O2(g) 8CO(g)+ 8CO2(g)+ 18H2O(l).
Given:
2C8H18(l)+ 25O2(g) 16CO2(g)+ 18H2O(l) H° = -11,020 kJ/mol
2CO(g)+ O2(g) 2CO2(g) H° = -566.0 kJ/mol
(Multiple Choice)
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A gas is allowed to expand, at constant temperature, from a volume of 1.0 L to 10.1 L against an external pressure of 0.50 atm.If the gas absorbs 250 J of heat from the surroundings, what are the values of q, w, and E?
(Multiple Choice)
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Butane (C4H10)undergoes combustion in excess oxygen to generate gaseous carbon dioxide and water.Given H°f [C4H10(g)] = -124.7 kJ/mol, H°f[CO2(g)] = -393.5 kJ/mol, H°f[H2O(g)] = -241.8 kJ/mol, how much energy is released (kJ)when 8.30 g of butane is burned?
(Multiple Choice)
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A 100.mL sample of 0.200 M aqueous hydrochloric acid is added to 100.mL of 0.200 M aqueous ammonia in a calorimeter whose heat capacity (excluding any water)is 480.J/K.The following reaction occurs when the two solutions are mixed. HCl(aq)+ NH3(aq) NH4Cl(aq)
The temperature increase is 2.34°C.Calculate H per mole of HCl and NH3 reacted.
(Multiple Choice)
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At 25°C, the standard enthalpy of formation of anhydrous sodium carbonate is -1130.9 kJ/mol, whereas the standard enthalpy of formation of sodium carbonate monohydrate is -1430.1 kJ/mol.Determine H° at 25°C for the reaction Na2CO3(s)+ H2O(l) Na2CO3·H2O(s).
(Given: H°f[H2O(l)] = -285.8 kJ/mol)
(Multiple Choice)
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The heat of solution of KCl is 17.2 kJ/mol and the lattice energy of KCl(s)is 701.2 kJ/mol.Calculate the total heat of hydration of 1.00 mol of gas phase K+ ions and Cl- ions.
(Multiple Choice)
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Calculate the amount of work done, in joules, when 2.5 mole of H2O vaporizes at 1.0 atm and 25°C.Assume the volume of liquid H2O is negligible compared to that of vapor.(1 L·atm = 101.3 J)
(Multiple Choice)
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If 10.6 moles of water at 35°C absorbs 12.30 kJ, what is the final temperature of the water? The specific heat of water is 4.184 J/g·°C.
(Multiple Choice)
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The enthalpy of combustion of acetylene C2H2 is described by
C2H2(g)+ (5/2)O2(g) 2CO2(g)+ H2O(l), H°rxn= -1299 kJ/mol
Calculate the enthalpy of formation of acetylene, given the following enthalpies of formation
H°f[CO2(g)] = -393.5 kJ/mol
H°f[H2O(l)] = -285.8 kJ/mol
(Short Answer)
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The enthalpy change when a strong acid is neutralized by strong base is -56.1 kJ/mol.If 135 mL of 0.450 M HI at 23.15°C is mixed with 145 mL of 0.500 M NaOH, also at 23.15°C, what will the maximum temperature reached by the resulting solution? (Assume that there is no heat loss to the container, that the specific heat of the final solution is 4.18 J/g·°C, and that the density of the final solution is that of water.)
(Multiple Choice)
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When an automobile engine starts, the metal parts immediately begin to absorb heat released during the combustion of gasoline.How much heat will be absorbed by a 165 kg iron engine block as the temperature rises from 15.7°C to 95.7°C? (The specific heat of iron is 0.489 J/g·°C.)
(Short Answer)
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Solid sodium peroxide (Na2O2)reacts with liquid water yielding aqueous sodium hydroxide and oxygen gas.How much heat is released when 250.0 L of oxygen gas is produced from the reaction of sodium peroxide and water if the reaction is carried out in an open container at 1.000 atm pressure and 25°C? (Given: H°f[Na2O2(s)] = -510.9 kJ/mol; H°f[NaOH(aq)] = -469.2 kJ/mol; H°f[H2O(l)] = -285.8 kJ/mol)
(Multiple Choice)
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Calculate the standard enthalpy change for the reaction
2C8H18(l)+ 17O2(g) 16CO(g)+ 18H2O(l).
Given:
(Multiple Choice)
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Pentaborane B5H9(s)burns vigorously in O2 to give B2O3(s)and H2O(l).Calculate Hrxn for the combustion of 5.00 mol of B5H9.
H°f[B2O3(s)] = -1,273.5 kJ/mol
H°f[B5H9(s)] = 73.2 kJ/mol
H°f[H2O(l)] = -285.8 kJ/mol
(Multiple Choice)
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The heat absorbed by a system at constant pressure is equal to E + P V.
(True/False)
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The specific heats of water and iron are 4.184 and 0.444 J/g°C, respectively.When equal masses of water and iron both absorb the same amount of heat, the temperature increase of the water will be 5.42 times greater than that of the iron.
(True/False)
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