Exam 6: Thermochemistry

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Given the following Δ\Delta H° values, H2(g)+  Given the following  \Delta H° values, H<sub>2</sub>(g)+   O<sub>2</sub>(g) \rarr H<sub>2</sub>O(l), \Delta H°<sub>f</sub> = -285.8 kJ/mol H<sub>2</sub>O<sub>2</sub>(l), \Delta  H<sub>2</sub>(g)+ O<sub>2</sub>(g), \Delta H°<sub>rxn</sub> = 187.6 kJ/mol calculate  \Delta H°<sub>rxn</sub> for the reaction H<sub>2</sub>O<sub>2</sub>(l) \rarr  H<sub>2</sub>O(l)+   O<sub>2</sub>(g), O2(g) →\rarr H2O(l), Δ\Delta H°f = -285.8 kJ/mol H2O2(l), Δ\Delta H2(g)+ O2(g), Δ\Delta H°rxn = 187.6 kJ/mol calculate Δ\Delta H°rxn for the reaction H2O2(l) →\rarr H2O(l)+  Given the following  \Delta H° values, H<sub>2</sub>(g)+   O<sub>2</sub>(g) \rarr H<sub>2</sub>O(l), \Delta H°<sub>f</sub> = -285.8 kJ/mol H<sub>2</sub>O<sub>2</sub>(l), \Delta  H<sub>2</sub>(g)+ O<sub>2</sub>(g), \Delta H°<sub>rxn</sub> = 187.6 kJ/mol calculate  \Delta H°<sub>rxn</sub> for the reaction H<sub>2</sub>O<sub>2</sub>(l) \rarr  H<sub>2</sub>O(l)+   O<sub>2</sub>(g), O2(g),

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Calcium oxide and water react in an exothermic reaction: CaO(s)+ H2O(l) →\rarr Ca(OH)2(s), Δ\Delta H°rxn = -64.8 kJ/mol How much heat would be liberated when 7.15 g CaO(s)is dropped into a beaker containing 152g H2O?

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Calculate the standard enthalpy change for the reaction 2C8H18(l)+ 21O2(g) →\rarr 8CO(g)+ 8CO2(g)+ 18H2O(l). Given: 2C8H18(l)+ 25O2(g) →\rarr 16CO2(g)+ 18H2O(l) →\rarr H° = -11,020 kJ/mol 2CO(g)+ O2(g) →\rarr 2CO2(g) Δ\Delta H° = -566.0 kJ/mol

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A gas is allowed to expand, at constant temperature, from a volume of 1.0 L to 10.1 L against an external pressure of 0.50 atm.If the gas absorbs 250 J of heat from the surroundings, what are the values of q, w, and Δ\Delta E?  A gas is allowed to expand, at constant temperature, from a volume of 1.0 L to 10.1 L against an external pressure of 0.50 atm.If the gas absorbs 250 J of heat from the surroundings, what are the values of q, w, and  \Delta E?

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Butane (C4H10)undergoes combustion in excess oxygen to generate gaseous carbon dioxide and water.Given Δ\Delta H°f [C4H10(g)] = -124.7 kJ/mol, Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol, Δ\Delta H°f[H2O(g)] = -241.8 kJ/mol, how much energy is released (kJ)when 8.30 g of butane is burned?

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A 100.mL sample of 0.200 M aqueous hydrochloric acid is added to 100.mL of 0.200 M aqueous ammonia in a calorimeter whose heat capacity (excluding any water)is 480.J/K.The following reaction occurs when the two solutions are mixed. HCl(aq)+ NH3(aq) →\rarr NH4Cl(aq) The temperature increase is 2.34°C.Calculate Δ\Delta H per mole of HCl and NH3 reacted.

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At 25°C, the standard enthalpy of formation of anhydrous sodium carbonate is -1130.9 kJ/mol, whereas the standard enthalpy of formation of sodium carbonate monohydrate is -1430.1 kJ/mol.Determine Δ\Delta H° at 25°C for the reaction Na2CO3(s)+ H2O(l) →\rarr Na2CO3·H2O(s). (Given: Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol)

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The heat of solution of KCl is 17.2 kJ/mol and the lattice energy of KCl(s)is 701.2 kJ/mol.Calculate the total heat of hydration of 1.00 mol of gas phase K+ ions and Cl- ions.

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Calculate the amount of work done, in joules, when 2.5 mole of H2O vaporizes at 1.0 atm and 25°C.Assume the volume of liquid H2O is negligible compared to that of vapor.(1 L·atm = 101.3 J)

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If 10.6 moles of water at 35°C absorbs 12.30 kJ, what is the final temperature of the water? The specific heat of water is 4.184 J/g·°C.

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The enthalpy of combustion of acetylene C2H2 is described by C2H2(g)+ (5/2)O2(g) →\rarr 2CO2(g)+ H2O(l), Δ\Delta H°rxn= -1299 kJ/mol Calculate the enthalpy of formation of acetylene, given the following enthalpies of formation Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol

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The enthalpy change when a strong acid is neutralized by strong base is -56.1 kJ/mol.If 135 mL of 0.450 M HI at 23.15°C is mixed with 145 mL of 0.500 M NaOH, also at 23.15°C, what will the maximum temperature reached by the resulting solution? (Assume that there is no heat loss to the container, that the specific heat of the final solution is 4.18 J/g·°C, and that the density of the final solution is that of water.)

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When an automobile engine starts, the metal parts immediately begin to absorb heat released during the combustion of gasoline.How much heat will be absorbed by a 165 kg iron engine block as the temperature rises from 15.7°C to 95.7°C? (The specific heat of iron is 0.489 J/g·°C.)

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Solid sodium peroxide (Na2O2)reacts with liquid water yielding aqueous sodium hydroxide and oxygen gas.How much heat is released when 250.0 L of oxygen gas is produced from the reaction of sodium peroxide and water if the reaction is carried out in an open container at 1.000 atm pressure and 25°C? (Given: Δ\Delta H°f[Na2O2(s)] = -510.9 kJ/mol; Δ\Delta H°f[NaOH(aq)] = -469.2 kJ/mol; Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol)

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Calculate the standard enthalpy change for the reaction 2C8H18(l)+ 17O2(g) →\rarr 16CO(g)+ 18H2O(l). Given:  Calculate the standard enthalpy change for the reaction  2C<sub>8</sub>H<sub>18</sub>(l)+ 17O<sub>2</sub>(g) \rarr 16CO(g)+ 18H<sub>2</sub>O(l). Given:

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Pentaborane B5H9(s)burns vigorously in O2 to give B2O3(s)and H2O(l).Calculate Δ\Delta Hrxn for the combustion of 5.00 mol of B5H9. Δ\Delta H°f[B2O3(s)] = -1,273.5 kJ/mol Δ\Delta H°f[B5H9(s)] = 73.2 kJ/mol Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol

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The heat absorbed by a system at constant pressure is equal to Δ\Delta E + P Δ\Delta V.

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The specific heats of water and iron are 4.184 and 0.444 J/g°C, respectively.When equal masses of water and iron both absorb the same amount of heat, the temperature increase of the water will be 5.42 times greater than that of the iron.

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