Exam 14: Chemical Equilibrium
Exam 1: Chemistry: the Study of Change168 Questions
Exam 2: Atoms, Molecules, and Ions156 Questions
Exam 3: Mass Relationships in Chemical Reactions194 Questions
Exam 4: Reactions in Aqueous Solutions186 Questions
Exam 5: Gases121 Questions
Exam 6: Thermochemistry118 Questions
Exam 7: Quantum Theory and the Electronic Structure of Atoms136 Questions
Exam 8: Periodic Relationships Among the Elements144 Questions
Exam 9: Chemical Bonding I: Basic Concepts137 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals147 Questions
Exam 11: Intermolecular Forces and Liquids and Solids149 Questions
Exam 12: Physical Properties of Solutions122 Questions
Exam 13: Chemical Kinetics130 Questions
Exam 14: Chemical Equilibrium109 Questions
Exam 15: Acids and Bases178 Questions
Exam 16: Acid-Base Equilibria and Solubility Equilibria131 Questions
Exam 17: Entropy Free Energy and Equilibrium128 Questions
Exam 18: Electrochemistry154 Questions
Exam 19: Nuclear Chemistry133 Questions
Exam 20: Chemistry in the Atmosphere50 Questions
Exam 21: Metallurgy and the Chemistry of Metals63 Questions
Exam 22: Nonmetallic Elements and Their Compounds52 Questions
Exam 23: Transition Metal Chemistry and Coordination Compounds92 Questions
Exam 24: Organic Chemistry67 Questions
Exam 25: Synthetic and Natural Organic Polymers50 Questions
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Consider the chemical reaction 2NH3(g)
N2(g)+ 3H2(g).The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 × 10-2.Initially, 1,220 moles of NH3(g)are present.Calculate Kp for the reaction.
(Short Answer)
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The equilibrium between carbon dioxide gas and carbonic acid is very important in biology and environmental science, and is shown below.
CO2(aq)+ H2O(l)
H2CO3(aq)
Based on the equilibrium constant reported for this reaction (Kc = 1.70 × 10-3), there will be more carbon dioxide in solution than carbonic acid.
(True/False)
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Which of these situations will result if some CH4(g)is removed from the reaction CO(g)+ 3H2(g)
CH4(g)+ H2O(g)at equilibrium?
(Multiple Choice)
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For the following reaction at equilibrium, which gives a change that will shift the position of equilibrium to favor formation of more products? 2NOBr(g)
2NO(g)+ Br2(g), Hºrxn = 30 kJ/mol
(Multiple Choice)
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When the reaction 2O3(g)
3O2(g), for which Kp = 3.0 × 1026 at 773ºC, is at equilibrium, the mixture will contain very little O2 as compared to O3.
(True/False)
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Consider the reaction N2(g)+ O2(g)
2NO(g), for which Kc = 0.10 at 2,000ºC.Starting with initial concentrations of 0.040 M of N2 and 0.040 M of O2, determine the equilibrium concentration of NO.
(Multiple Choice)
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For the following reaction at equilibrium in a reaction vessel, which change will cause the Br2 concentration to decrease? 2NOBr(g)
2NO(g)+ Br2(g), Hºrxn= 30 kJ/mol
(Multiple Choice)
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Equilibrium is established for the reaction 2X(s)+ Y(g)
2Z(g)at 500K, Kc = 100.Determine the concentration of Z in equilibrium with 0.2 mol X and 0.50 M Y at 500K.
(Multiple Choice)
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The data below refer to the following reaction:
2NO(g)+ Br2(g)
2NOBr(g)
Calculate Kc.
(Short Answer)
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Calculate Kp for the reaction 2NOCl(g)
2NO(g)+ Cl2(g)at 400°C if Kc at 400°C for this reaction is 2.1 × 10-2.
(Multiple Choice)
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Consider the equilibrium C(s)+ H2O(g)
CO(g)+ H2(g), H = 2296 J.What will happen to the concentration of carbon if gaseous water is added to the system?
(Short Answer)
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At 250ºC, the equilibrium constant Kp for the reaction PCl5(g)
PCl3(g)+ Cl2(g)is 1.80.Sufficient PCl5 is put into a reaction vessel to give an initial pressure of 2.74 atm at 250ºC.Calculate the pressure of PCl5 after the system has reached equilibrium.
(Multiple Choice)
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Kp for the reaction 4CuO(s)
2Cu2O(s)+ O2(g)is 0.49 at 1024 °C.Calculate Kc at this temperature
(Multiple Choice)
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For the equilibrium reaction 2SO2(g)+ O2(g)
2SO3(g), Hºrxn = -198 kJ/mol.Which one of these factors would cause the equilibrium constant to increase?
(Multiple Choice)
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For the reaction H2(g)+ I2(g)
2HI(g), Kc = 50.2 at 445ºC.If [H2] = [I2] = [HI] = 1.75 × 10-3 M at 445ºC.Which of the following is true based on the above?
(Multiple Choice)
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For the reaction SO2(g)+ NO2(g)
SO3(g)+ NO(g), the equilibrium constant is 18.0 at 1,200ºC.If 1.0 mole of SO2 and 2.0 moles of NO2 are placed in a 20.L container, what concentration of SO3 will be present at equilibrium?
(Multiple Choice)
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Consider the following reactions and their associated equilibrium constants:
For the reaction A + 2B
D + E, having equilibrium constant Kc,
(Multiple Choice)
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Consider the chemical reaction 2NH3(g)
N2(g)+ 3H2(g).The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 × 10-2.Initially, 1,220 moles of NH3(g)are present.Estimate the equilibrium concentration of N2(g).
(Short Answer)
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The brown gas NO2 and the colorless gas N2O4 exist in equilibrium, 2NO2
N2O4.In an experiment, 0.625 mole of N2O4 was introduced into a 5.00 L vessel and was allowed to decompose until equilibrium was reached.The concentration of N2O4 at equilibrium was 0.0750 M.Calculate Kc for the reaction.
(Multiple Choice)
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A solution was prepared such that the initial concentrations of Cu2+(aq)and CN-(aq)were 0.0120 M and 0.0400 M, respectively.These ions react according to the following chemical equation
What will be the concentration of Cu2+(aq)at equilibrium?
(Short Answer)
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