Exam 9: Chemical Bonding I: Basic Concepts

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Use the Born-Haber cycle to calculate the lattice energy of NaBr(s) given the following data: Δ\Delta H(sublimation) Na = 109 kJ/mol I1 (Na) = 496 kJ/mol Bond energy (Br-Br) = 192 kJ/mol EA (Br) = 324 kJ/mol Δ\Delta Hf (NaBr(s)) = -361 kJ/mol

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Arrange the elements F, P, and Cl in order of increasing electronegativity.

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BeF42- is called the fluoberyllate ion. The formal charge on the beryllium atom in this ion is

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List all types of bonding present in the molecule S8. I. ionic bond II. polar covalent bond III. nonpolar covalent bond

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Calculate the energy change for the reaction K(g) + I(g) →\rarr K+(g) + I - (g) Given the following ionization energy (IE) and electron affinity (EA) values. IE EA K: 419/ 48/ I: 1,010/ 295/

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The Lewis structure reveals an unpaired electron (free radical) in which of the following species

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Use the Born-Haber cycle to calculate the standard enthalpy of formation ( ΔHf∘\Delta{H}^{\circ}_f ) for LiCl(s) given the following data: Δ\Delta H(sublimation) Li = 155.2 kJ/mol I1 (Li) = 520 kJ/mol Bond energy (Cl-Cl) = 242.7 kJ/mol EA (Cl) = 349 kJ/mol Lattice energy (LiCl(s)) = 828 kJ/mol

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The Lewis dot symbol for the chloride ion is

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The polarity of covalent bonds increases as the percent ionic character increases.

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Which of the elements listed below would most likely form an ionic bond when bonded to oxygen

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Which response includes all the molecules below that do not follow the octet rule (1) H2S (2) BCl3 (3) PH3 (4) SF4

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Classify the Ca - Cl bond in CaCl2 as ionic, polar covalent, or nonpolar covalent.

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The Si - Cl bond has less ionic character than the C - Cl bond.

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The Lewis structure reveals only single bonds in which of the following species

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The Lewis structure for the nitrate ion, NO3-, showing all non-zero formal charges is shown here. The Lewis structure for the nitrate ion, NO<sub>3</sub><sup>-</sup>, showing all non-zero formal charges is shown here.    This structure shows a violation of the octet rule. This structure shows a violation of the octet rule.

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Which one of the following compounds utilizes both ionic and covalent bonding

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A Lewis structure for SO3 that obeys the octet rule, showing all non-zero formal charges, is shown here. How many resonance structures for SO3 that obey the octet rule, are possible A Lewis structure for SO<sub>3</sub> that obeys the octet rule, showing all non-zero formal charges, is shown here. How many resonance structures for SO<sub>3</sub> that obey the octet rule, are possible

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Calculate the energy change for the reaction K(g) + Br(g) →\rarr K+(g) + Br- (g) Given the following ionization energy (IE) and electron affinity (EA) values. IE EA K: :419/ 48/ :1140/ 324/

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Shown here is a Lewis structure for the chlorate ion, ClO3-, that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s). What is the formal charge on Cl Shown here is a Lewis structure for the chlorate ion, ClO<sub>3</sub><sup>-</sup>, that expands the octet to minimize formal charge and if necessary places negative formal charges on the most electronegative atom(s). What is the formal charge on Cl

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A polar covalent bond would form in which one of the following pairs of atoms

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