Exam 6: Thermochemistry

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Calculate the standard enthalpy of formation of liquid methanol, CH3OH(l), using the following information: (graph) +\rightarrow() \Delta=-393.5/ ()+(1/2)\rightarrow() \Delta=-285.8/ ()+(3/2)()\rightarrow()+2() \Delta=-726.4/

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B

Given 2Al(s) + (3/2)O2(g) →\rarr Al2O3(s), Δ\Delta H ∘\circ f = -1,670 kJ/mol for Al2O3 (s).Determine Δ\Delta H ∘\circ for the reaction 2Al2O3(s) →\rarr 4Al(s) + 3O2(g).

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E

The enthalpy change when a strong acid is neutralized by strong base is -56.1 kJ/mol. If 12.0 mL of 6.00 M HBr at 21.30 ∘\circ C is mixed with 300. mL of 0.250 M NaOH, also at 21.30 ∘\circ C, what is the maximum temperature reached by the resulting solution (Assume that there is no heat loss to the container, that the specific heat of the final solution is 4.18 J/g· ∘\circ C, and that the density of the final solution is that of water.)

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Given the following Δ\Delta H ∘\circ values, H2(g) + (1/2)O2(g) →\rarr H2O(l) Δ\Delta H ∘\circ f = -285.8 kJ/mol H2O2(l) →\rarr H2(g) + O2(g) Δ\Delta H ∘\circ rxn = 187.6 kJ/mol Calculate Δ\Delta H ∘\circ rxn for the reaction H2O2(l) →\rarr H2O(l) + (1/2)O2(g).

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Which of the following processes is exothermic

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A beaker contains 115 g of ethanol at 18.2 ∘\circ C. If the ethanol absorbs 1125 J of heat without losing heat to the surroundings, what will be the final temperature of the ethanol The specific heat of ethanol is 2.46 J/g* ∘\circ C.

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If 2Mg(s) + O2(g) →\rarr 2MgO(s), Δ\Delta H ∘\circ = -1203.6 kJ/mol, then for Mg(s) + (1/2)O2(g) →\rarr MgO(s), the enthalpy change is ∘\circ H = -601.8 kJ/mol.

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Calculate the amount of work done against an atmospheric pressure of 1.00 atm when 500.0 g of zinc dissolves in excess acid at 30.0 ∘\circ C.Zn(s) + 2H+(aq) →\rarr Zn2+(aq) + H2(g)

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Calculate the standard enthalpy change for the reaction 2C8H18(l) + 17O2(g) →\rarr 16CO(g) + 18H2O(l).Given 2()+25()\rightarrow16()+18() \Delta=-11,020/ 2()+()\rightarrow2() \Delta=-566.0/

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Calculate the heat required when 2.50 mol of A reacts with excess B and A2B according to the reaction: 2A + B + A2B →\rarr 2AB + A2 Given: 2+\rightarrow \Delta=-25.0/ 2\rightarrow2+ \Delta=35.0/

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Ozone (O3) in the atmosphere can be converted to oxygen gas by reaction with nitric oxide (NO). Nitrogen dioxide is also produced in the reaction. What is the enthalpy change when 8.50L of ozone at a pressure of 1.00 atm and 25 ∘\circ C reacts with 12.00 L of nitric oxide at the same initial pressure and temperature [ Δ\Delta H ∘\circ f(NO) = 90.4 kJ/mol; Δ\Delta H ∘\circ f(NO2) = 33.85 kJ/mol; Δ\Delta H ∘\circ f(O3) = 142.2 kJ/mol]

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Acetylene (C2H2) undergoes combustion in excess oxygen to generate gaseous carbon dioxide and water. Given Δ\Delta H ∘\circ f[CO2(g)] = -393.5 kJ/mol, Δ\Delta H ∘\circ f[H2O(g)] = -241.8 kJ/mol, and Δ\Delta H ∘\circ f[C2H2(g)] = 226.6 kJ/mol, how much energy is released (kJ) when 10.5 moles of acetylene is burned

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Chemical reactions in a bomb calorimeter occur at constant pressure.

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According to the first law of thermodynamics:

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Find the heat absorbed from the surroundings when 15 g of O2 reacts according to the equation O + O2 →\rarr O3, Δ\Delta H ∘\circ rxn= -103 kJ/mol.

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The total heat of hydration of 1.00 mol of gas phase Li+ ions and Cl - ions is -865 kJ. The lattice energy of LiCl(s) is 828 kJ/mol. Calculate the heat of solution of LiCl.

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Ethanol undergoes combustion in oxygen to produce carbon dioxide gas and liquid water. The standard heat of combustion of ethanol, C2H5OH(l), is -1366.8 kJ/mol. Given that Δ\Delta H ∘\circ f[CO2(g)] = -393.5 kJ/mol and Δ\Delta H ∘\circ f[H2O(l)] = -285.8 kJ/mol, what is the standard enthalpy of formation of ethanol

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Potential energy is

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Which of the following has a Δ\Delta H ∘\circ f= 0 kJ/mol

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A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter. The temperature of the calorimeter and the 1.000 kg of water contained therein rose from 20.22 ∘\circ C to 22.82 ∘\circ C. The heat capacity of the calorimeter is 2.21 kJ/ ∘\circ C. The heat capacity of water = 4.184 J/g· ∘\circ C. What is the heat of combustion, in kilojoules, per gram of pentane

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