Exam 16: Acid-Base Equilibria and Solubility Equilibria

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The solubility of Ba(NO3)2 is 130.5 g/L at 0ºC. How many moles of dissolved salt are present in 4.0 L of a saturated solution of Ba(NO3)2 at 0ºC

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B

A saturated sodium carbonate solution at 100 ∘\circ C contains 45.5 g of dissolved sodium carbonate per 100. mL of solution. The solubility product constant for sodium carbonate at this temperature is

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E

A titration of an acid and base to the equivalence point results in a noticeably acidic solution. It is likely this titration involves

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A

Calculate the pH of the solution resulting from the addition of 85.0 mL of 0.35 M HCl to 30.0 mL of 0.40 M aniline (C6H5NH2). Kb (C6H5NH2) = 3.8 x 10-10

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40.0 mL of a 0.65 M solution of HF is titrated with 0.100 M NaOH. After 0.400 L of the NaOH solution has been added, the resultant solution is:

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Calculate the minimum concentration of Mg2+ that must be added to 0.10 M NaF in order to initiate a precipitate of magnesium fluoride. (For MgF2 , Ksp = 6.9 * 10-9.)

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Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 4.6-4.8

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24.00 mL of a 0.25 M NaOH solution is titrated with 0.10M HCl. What is the pH of the solution after 24.00 mL of the HCl has been added

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The solubility of strontium carbonate is 0.0011 g/100 mL at 20ºC. Calculate the Ksp value for this compound.

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Find the concentration of Pb2+ ions in a solution made by adding 5.00 g of lead(II) iodide to 500. mL of 0.150 M KI. [For PbI2, Ksp = 1.39 * 10-8.]

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Will a precipitate of magnesium fluoride form when 300. mL of 1.1 * 10-3 M MgCl2 are added to 500. mL of 1.2 *10-3 M NaF? [Ksp (MgF2) = 6.9 *10-9]

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Bromothymol blue is a common acid-base indicator. It has a Ka equal to 1.6 * 10-7. Its un-ionized form is yellow and its conjugate base is blue. At a pH of 5.8 the color in the solution would be yellow.

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A mixture made from 10 mL of 1 M HCl and 20 mL of 1 M CH3COONa would be classified as a buffer solution.

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25.0 mL of a 0.100 M solution of NH3 is titrated with 0.250M HCl. After 10.0 mL of the HCl has been added, the resultant solution is:

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The net ionic equation for the reaction that occurs when a small amount of hydrochloric acid is added to a buffer solution containing NH4Cl and NH3 is correctly shown here: H+ + H2O + NH3 →\rarr NH4+

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25.0 mL of a 0.100 M solution of NH3 is titrated with 0.250M HCl. After 25.0 mL of the HCl has been added, the resultant solution is:

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Calculate the molar solubility of AgCl in a 0.15 M solution of NH3(aq).(Ksp (AgCl) = 1.6 x 10-10; Kf (Ag(NH3)2+) = 1.5 x 107)

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Calculate the percent ionization of formic acid in a solution that is 0.010 M HCOOH and 0.050 M HCOONa. (Ka = 1.7 * 10-4)

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Calculate the concentration of chloride ions in a saturated lead(II) chloride (Ksp = 2.4 * 10-4) solution.

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Will a precipitate form (yes or no) when 50.0 mL of 1.2 * 10-3 M Pb(NO3)2 are added to 50.0 mL of 2.0 * 10-4 M Na2S If so, identify the precipitate.

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