Exam 16: Acid-Base Equilibria and Solubility Equilibria

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Calculate the equilibrium constant Kc for the net reaction shown below.AgI(s) + 2NH3(aq) ⇋\leftrightharpoons Ag(NH3)2+(aq) + I-(aq) For AgI, Ksp = 8.3 * 10-17; for Ag(NH3)2+, Kf = 1.5 * 107.

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Consider a buffer solution prepared from HOCl and NaOCl. Which is the net ionic equation for the reaction that occurs when NaOH is added to this buffer

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You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH) and 0.30 M sodium acetate (CH3COONa). What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution [Ka = 1.8 * 10-5]

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Calculate the molar solubility of CaF2 in a 0.25 M solution of NaF(aq). (Ksp (CaF2) = 4.0 x 10-11)

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The solubility product for chromium(III) fluoride is Ksp = 6.6 * 10-11. What is the molar solubility of chromium(III) fluoride

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You have 500.0 mL of a buffer solution containing 0.30 M acetic acid (CH3COOH) and 0.20 M sodium acetate (CH3COONa). What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution [Ka = 1.8 * 10-5]

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An environmental chemist obtained a 200. mL sample of lake water believed to be contaminated with a single monoprotic strong acid. Titrating this sample with a 0.0050 M NaOH(aq) required 7.3 mL of the NaOH solution to reach the endpoint. What is the pH of the lake

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How many moles of NaF must be dissolved in 1.00 liter of a saturated solution of PbF2 at 25 ∘\circ C to reduce the [Pb2+] to 1.0 * 10-6 M The Ksp for PbF2 at 25 ∘\circ C is 4.0 * 10-8.

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Solid sodium iodide is slowly added to a solution that is 0.0050 M Pb2+ and 0.0050 M Ag+. [Ksp (PbI2) = 1.4 * 10-8; Ksp (AgI) = 8.3 * 10-17] AgI will precipitate first.

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The Ksp value for lead(II) chloride is 2.4 * 10-4. What is the molar solubility of lead(II) chloride

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Calculate the pH of the solution resulting from the addition of 75.0 mL of 0.15 M KOH to 35.0 mL of 0.20 M HCN (Ka (HCN) = 4.9 * 10-10).

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Calculate the pH of the solution resulting from the addition of 25.0 mL of 0.20 M HCl to 50.0 mL of 0.10 M aniline (C6H5NH2). Kb (C6H5NH2) = 3.8 x 10-10

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Calculate the molar solubility of BaCO3 in a 0.10 M solution of Na2CO3(aq). (Ksp (BaCO3) = 8.1 x 10-9)

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NaCl is added slowly to a solution that is 0.010 M each in Cu+, Ag+, and Au+. The Ksp's for CuCl, AgCl, and AuCl are 1.9 * 10-7, 1.8 * 10-10, and 2.0 * 10-13, respectively. Which compound will precipitate first

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Calculate the percent ionization of formic acid in a 0.010 M HCOOH solution.(Ka = 1.7 * 10-4)

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For which type of titration will the pH be basic at the equivalence point

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What volume of 0.200 M potassium hydroxide should be added to 300. mL of 0.150 M propanoic acid (C2H5COOH) to obtain a solution with a pH of 5.25? [Ka(C2H5COOH) = 1.34 * 10-5]

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Which of the following compounds is more soluble in acidic solution than in pure neutral water

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Starting with 0.250L of a buffer solution containing 0.250 M benzoic acid (C6H5COOH) and 0.20 M sodium benzoate (C6H5COONa), what will the pH of the solution be after the addition of 25.0 mL of 0.100M HCl (Ka (C6H5COOH) = 6.5 x 10-5)

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Calculate the pH of a buffer solution that contains 0.25 M benzoic acid (C6H5CO2H) and 0.15M sodium benzoate (C6H5COONa). [Ka = 6.5 * 10-5 for benzoic acid]

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