Exam 16: Acid-Base Equilibria and Solubility Equilibria

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Solid sodium iodide is slowly added to a solution that is 0.0050 M Pb2+ and 0.0050 M Ag+. [Ksp (PbI2) = 1.4 *10-8; Ksp (AgI) = 8.3 *10-17] Calculate the Ag+ concentration when PbI2 just begins to precipitate.

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The equation shown here is the net reaction that occurs when a strong base is added to a CO32-/HCO3- buffer solution (for carbonic acid, Ka1 = 4.2 * 10-7, Ka2 = 2.4 * 10-8): HCO3- + OH- →\rarr CO32- + H2O

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At 25 ∘\circ C, the base ionization constant for NH3 is 1.8 * 10-5. If 0.0800 mole of solid magnesium chloride is dissolved in a solution prepared by adding 0.0500 mol of solid ammonium chloride to 100. ml of 0.150 M ammonia, a precipitate of magnesium hydroxide will form. (Assume the volume of the solution is unchanged. The solubility product constant for magnesium hydroxide is 1.5 * 10-11.)

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The net ionic equation for the reaction that occurs when a small amount of nitric acid is added to a NaNO2/HNO2 buffer is correctly shown here: H+ + NO2- →\rarr HNO2

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There will be no Fe(OH)3 precipitate in a buffer solution that is 0.60 M CH3COOH and 0.10 M CH3COONa, if the solution is also made to be 0.001 M in Fe3+. For Fe(OH)3, Ksp = 6.8 * 10-36.

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The solubility product for calcium phosphate is Ksp = 1.3 * 10-26. What is the molar solubility of calcium phosphate

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Calculate the pH at the equivalence point for the titration of 0.20 M HCl with 0.20 M NH3 (Kb = 1.8 * 10-5).

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550. mL of a 0.40M solution of NaOH is titrated with 0.25 M HCl. Calculate the pH of the solution after 650. mL of the HCl has been added.

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Calculate the molar solubility of Mg(OH)2 in a solution with pH = 12.20.(Ksp (Mg(OH)2 = 1.2 x 10-11)

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500. mL of a solution containing 1.5 M NH4Cl(aq) is mixed with 500. mL of a solution containing 0.50M of NaOH(aq). What is the pH of the final solution (Kb(NH3) = 1.8 x 10-5)

(Multiple Choice)
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The net ionic equation for the reaction occurring when a small amount of sodium hydroxide is added to a NaNO2/HNO2 buffer is correctly shown here: OH- + HNO2 →\rarr NO2- + H2O

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Will a precipitate of magnesium fluoride form when 200. mL of 1.9 * 10-3 M MgCl2 are added to 300. mL of 1.4 * 10-2 M NaF? [Ksp (MgF2) = 6.9 * 10-9]

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What is the optimum pH of a sodium formate/formic acid buffer? (For formic acid, Ka = 1.7 * 10-4.)

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Will a precipitate (ppt) form when 20.0 mL of 1.1 * 10-3 M Ba(NO3)2 are added to 80.0 mL of 8.4 * 10-4 M Na2CO3

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Calculate the percent ionization of formic acid in a solution that is 0.010 M HCOOH and 0.005 M HCOONa. (Ka = 1.7 * 10-4)

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Will a precipitate (ppt) form when 300. mL of 2.0 * 10-5 M AgNO3 are added to 200. mL of 2.5 * 10-9 M NaI? Answer yes or no, and identify the precipitate if there is one.

(Multiple Choice)
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At 25 ∘\circ C, the base ionization constant for NH3 is 1.8 * 10-5. Determine the percentage ionization of a 0.150 M solution of ammonia at 25 ∘\circ C.

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You are asked to go into the lab and prepare an acetic acid - sodium acetate buffer solution with a pH of 4.00 ±\pm 0.02. What molar ratio of CH3COOH to CH3COONa should be used

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Which of the following would decrease the Ksp for PbI2

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35.00 mL of a 0.30 M HCl solution is titrated with 0.35 M NaOH. What is the pH of the solution after 40.00 mL of the NaOH has been added

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