Exam 20: Chemistry in the Atmosphere

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Which of the following reactions associated with nitrogen fixation by lightening is a disproportionation reaction I. N2(g) + O2(g) →\rarr 2NO(g) II. 2NO(g) + O2(g) →\rarr 2NO2(g) III. 2NO2(g) + H2O(l) →\rarr HNO2(aq) + HNO3(aq)

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Which statement about ozone and the ozone layer is true

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In order for a gas to be a "greenhouse gas" it must

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A

Of the following which one, if any, is not one of the primary pollutants removed from automobile exhaust by catalytic converters.

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Shown here are the four steps that show how sulfur in coal is converted to sulfuric acid in acid rain. Which step, if any, shows an unbalanced equation

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Which one of the following indoor air pollutants has adverse health effects because it is radioactive

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Which one of the following is not a greenhouse gas

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The mechanism for the decomposition of ozone in the presence of a reactive chlorine atom is shown below. Which species functions as a catalyst O3 + (UV light) →\rarr O + O2 Cl + O3 →\rarr ClO + O2 ClO + O →\rarr Cl + O2

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Which of the following would NOT help reduce the amount of CO2 introduced into the atmosphere

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The mechanism for the decomposition of ozone in the presence of a reactive chlorine atom is shown below. Which of the following species is an intermediate O3 + (UV light) →\rarr O + O2 Cl + O3 →\rarr ClO + O2 ClO + O →\rarr Cl + O2

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Which region of the atmosphere contains the ozone layer

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The steps in the mechanism of ozone destruction by chlorine atoms is shown here: Cl2(g) + O3(g) →\rarr 2ClO(g) + O2(g) ClO(g) + O(g) →\rarr O2(g) + Cl(g)

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A possible reaction leading to removal of ClO from the atmosphere is 2ClO →\rarr Cl2 + O2. Studies of this reaction have yielded an Arrhenius frequency factor (A) and activation energy of 1.0 * 10-12 cm3 molecule-1 s-1 and 13.2 kJ/mol, respectively. Calculate the rate constant for the disappearance of ClO at -30 ∘\circ C.

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An unusual atmospheric reaction leading to ozone destruction is CF3O + O3 →\rarr CF3O2 + O2, the analysis of which has yielded an Arrhenius frequency factor (A) and activation energy of 2.0 * 10-12 cm3 molecule-1 s-1 and 11.6 kJ/mol, respectively. Calculate the rate constant for this reaction at an altitude of 35 km, where the temperature is -34 ∘\circ C.

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List the following greenhouse gases in order of their overall magnitude of contribution to global warming: N2O, CFCs, CO2, CH4.

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An increase in the amount of particulate matter (dust and smoke) in the atmosphere may result in cooler world temperatures because

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Which of the following is a promising candidate as an alternative to using chlorofluorocarbons as a coolant

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The steps in the reaction scheme for nitrogen fixation by lightening are as follow: N2(g) + O2(g)      lightening     →\underrightarrow{~~~~\text { lightening }~~~~} 2NO(g) 2NO(g) + O2(g) →\rarr 2NO2(g) 2NO2(g) + H2O(l) →\rarr HNO2(aq) + HNO3(aq)

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Select all of the following that are capable of destroying stratospheric ozone through chemical means I. CF2Cl2 II. NO III. CO2

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The ozone layer in the atmosphere protects animals and plants from

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