Exam 16: Acid-Base Equilibria and Solubility Equilibria

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An environmental chemist obtained a 200. mL sample of lake water believed to be contaminated with a single monoprotic strong acid. Titrating this sample with a 0.0050 M NaOH(aq) required 7.3 mL of the NaOH solution to reach the endpoint. If the size of the lake can be approximated as 1.1 km long by 2.3 km wide, and has an average depth of 10. m, estimate how many moles of the strong acid are present in the lake

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35.0 mL of a 0.250 M solution of KOH is titrated with 0.150 M HCl. After 35.0 mL of the HCl has been added, the resultant solution is:

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The Ksp for silver(I) phosphate is 1.8 * 10-18. Determine the silver ion concentration in a saturated solution of silver(I) phosphate.

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A saturated sodium carbonate solution at 0 ∘\circ C contains 7.1 g of dissolved sodium carbonate per 100. mL of solution. The solubility product constant for sodium carbonate at this temperature is

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Calculate the pH of a solution that is 0.15 M CH3COOH and 0.75 M CH3COONa.

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Which of the following yields a buffer solution when equal volumes of the two solutions are mixed

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Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 9.2-9.3

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Calculate the molar solubility of Fe(OH)2 in a solution with pH = 13.15.(Ksp Fe(OH)2 = 1.6 x 10-14)

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550. mL of a 0.40M solution of NaOH is titrated with 0.25 M HCl. Calculate the pH of the solution after 1.10 L of HCl has been added.

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The solubility of lead(II) iodide is 0.064 g/100 mL at 20ºC. What is the solubility product for lead(II) iodide

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Solid sodium iodide is slowly added to a solution that is 0.0050 M Pb2+ and 0.0050 M Ag+. [Ksp (PbI2) = 1.4 * 10-8; Ksp (AgI) = 8.3 * 10-17] What percent of Ag+ remains in solution at this point

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40.0 ml of an acetic acid of unknown concentration is titrated with 0.100 M NaOH. After 20.0 mL of the base solution has been added, the pH in the titration flask is 5.10. What was the concentration of the original acetic acid solution? [Ka(CH3COOH) = 1.8 * 10-5]

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25.0 mL of a hydrofluoric acid solution of unknown concentration is titrated with 0.200 M NaOH. After 20.0 mL of the base solution has been added, the pH in the titration flask is 3.00. What was the concentration of the original hydrofluoric acid solution. [Ka(HF) = 7.1 * 10-4]

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The solubility product for barium sulfate is 1.1 * 10-10. Calculate the molar solubility of barium sulfate.

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Which one of the following is a buffer solution

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The equation shown here is the net reaction that occurs when a strong acid is added to a CO32-/HCO3- buffer solution (for carbonic acid, Ka1 = 4.2 * 10-7, Ka2 = 2.4 * 10-8): CO32- + H+ →\rarr HCO3- and HCO3- + H+ →\rarr H2CO3

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50.00 mL of 0.10 M HNO2 (nitrous acid, Ka = 4.5 * 10-4) is titrated with a 0.10 M KOH solution. After 25.00 mL of the KOH solution is added, the pH in the titration flask will be

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The molar solubility of manganese(II) carbonate is 4.2 * 10-6 M. What is Ksp for this compound

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Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 * 10-10) solution.

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The net ionic equation for the reaction occurring when a small amount of sodium hydroxide solution is added to a buffer solution containing NH4Cl and NH3 is correctly shown here: NaOH + NH4+ →\rarr NH3 + H2O + Na+

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