Exam 6: Thermochemistry

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The enthalpy change when a strong acid is neutralized by strong base is -56.1 kJ/mol. If 135 mL of 0.450 M HI at 23.15 ∘\circ C is mixed with 145 mL of 0.500 M NaOH, also at 23.15 ∘\circ C, what is the maximum temperature reached by the resulting solution (Assume that there is no heat loss to the container, that the specific heat of the final solution is 4.18 J/g· ∘\circ C, and that the density of the final solution is that of water.)

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Calculate the amount of work done, in joules, when 2.5 mole of H2O vaporizes at 1.0 atm and 25 ∘\circ C. Assume the volume of liquid H2O is negligible compared to that of vapor. (1 L·atm = 101.3 J)

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Find the standard enthalpy of formation of ethylene, C2H4(g), given the following data: heat of combustion of C2H4(g)= -1411 kJ/mol; Δ\Delta H ∘\circ f[CO2(g)] = -393.5 kJ/mol; Δ\Delta H ∘\circ f[H2O(l)] = -285.8 kJ/mol.

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Find Δ\Delta H ∘\circ rxn for the reaction 2Na(s)+2H2O(l)→2NaOH(aq)+2H2( g) 2 \mathrm{Na}(\mathrm{s})+2 \mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \rightarrow 2 \mathrm{NaOH}(\mathrm{aq})+2 \mathrm{H}_{2}(\mathrm{~g}) . [ΔH∘f(NaOH(aq))=−426.8 kJ/mol;ΔH∘f(H2O(l))=−285.5 kJ/mol] \left[\Delta \mathrm{H}^{\circ}{ }_{\mathrm{f}}(\mathrm{NaOH}(\mathrm{aq}))=-426.8 \mathrm{~kJ} / \mathrm{mol} ; \Delta \mathrm{H}^{\circ}{ }_{\mathrm{f}}\left(\mathrm{H}_{2} \mathrm{O}(\mathrm{l})\right)=-285.5 \mathrm{~kJ} / \mathrm{mol}\right]

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Find Δ\Delta H ∘\circ rxn for the reaction 2Ag2S(s) + 2H2O(l) →\rarr 4Ag(s) + 2H2S(g) + O2(g).[ Δ\Delta H ∘\circ f (Ag2S(s)) = -32.6 kJ/mol; Δ\Delta H ∘\circ f (H2S(g)) = -20.5 kJ/mol; Δ\Delta H ∘\circ f (H2O(l)) = -285.5 kJ/mol]

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Ethanol (C2H5OH) burns according to the equation C2H5OH(l) + 3O2(g) →\rarr 2CO2(g) + 3H2O(l), Δ\Delta H ∘\circ rxn = -1367 kJ/mol.How much heat is released when 35.0 g of ethanol is burned

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The bond enthalpy of the Br-Cl bond is equal to Δ\Delta E ∘\circ for the reaction BrCl(g) →\rarr Br(g) + Cl(g).Use the following data to find the bond enthalpy of the Br-Cl bond. ()\rightarrow() \Delta=30.91/ ()\rightarrow2() \Delta=192.9/ ()\rightarrow2() \Delta=243.4/ ()+()\rightarrow2() \Delta=29.2/

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Calculate the enthalpy of reaction for H2(g) + C2H4(g) →\rarr C2H6(g).[ Δ\Delta H ∘\circ f(C2H4(g)) = 52.3 kJ/mol; Δ\Delta H ∘\circ f(C2H6(g)) = -84.7 kJ/mol]

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A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter. The temperature of the calorimeter and the 1.000 kg of water contained therein rose from 20.22 ∘\circ C to 22.82 ∘\circ C. The heat capacity of the calorimeter is 2.21 kJ/ ∘\circ C. The heat capacity of water = 4.184 J/g· ∘\circ C. How much heat was given off during combustion of the sample of pentane

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The combustion of pentane produces heat according to the equation C5H12(l) + 8O2(g) →\rarr 5CO2(g) + 6H2O(l), Δ\Delta H ∘\circ rxn= -3,510 kJ/mol.How many grams of CO2 are produced per 2.50 * 103 kJ of heat released

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Aluminum oxide can be reduced to aluminum metal using carbon, the other reaction product being carbon monoxide. Determine the enthalpy change when 12.5 g of aluminum is produced by this method. [ Δ\Delta H ∘\circ f(carbon monoxide) = -110.5 kJ/mol; Δ\Delta H ∘\circ f(aluminum oxide) = -1669.8 kJ/mol]

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At 25 ∘\circ C, the standard enthalpy of formation of anhydrous sodium carbonate is -1130.9 kJ/mol, whereas the standard enthalpy of formation of sodium carbonate monohydrate is -1430.1 kJ/mol. Determine Δ\Delta H ∘\circ at 25 ∘\circ C for the reaction Na2CO3(s) + H2O(l) →\rarr Na2CO3·H2O(s).(Given: Δ\Delta H ∘\circ f[H2O(l)] = -285.8 kJ/mol)

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The heat of solution of ammonium nitrate is 26.2 kJ/mol. If a 5.368 g sample of NH4NO3 is added to 40.0 mL of water in a calorimeter at 23.5 ∘\circ C, what is the minimum temperature reached by the solution (The specific heat of water = 4.18 J/g· ∘\circ C; the heat capacity of the calorimeter = 650. J/ ∘\circ C.)

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A 26.2 g piece of copper metal is heated from 21.5 ∘\circ C to 201.6 ∘\circ C. Calculate the amount of heat absorbed by the metal. The specific heat of Cu is 0.385 J/g· ∘\circ C.

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When 0.7521 g of benzoic acid was burned in a calorimeter containing 1,000. g of water, a temperature rise of 3.60 ∘\circ C was observed. What is the heat capacity of the bomb calorimeter, excluding the water The heat of combustion of benzoic acid is -26.42 kJ/g.

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Naphthalene combustion can be used to calibrate the heat capacity of a bomb calorimeter. The heat of combustion of naphthalene is -40.1 kJ/g. When 0.8210 g of naphthalene was burned in a calorimeter containing 1,000. g of water, a temperature rise of 4.21 ∘\circ C was observed. What is the heat capacity of the bomb calorimeter excluding the water

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For which of these reactions will the difference between Δ\Delta H ∘\circ and Δ\Delta E ∘\circ be the greatest

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Calculate the standard enthalpy change for the reaction 2A + 2A2 + 4AB + B →\rarr 5A2B Given: 2+\rightarrow \Delta=-25.0/ 2\rightarrow2+ \Delta=35.0/

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Calculate the heat released (kJ) in the reaction of 2.20 g of sulfur dioxide gas and excess oxygen gas to form sulfur trioxide gas: 2SO2(g) + O2(g) →\rarr 2SO3(g) Given: S(s) + O2(g) →\rarr SO2(g) Δ\Delta H = -299 kJ/mol S(s) + 3/2O2(g) →\rarr SO3(g) Δ\Delta H = -395 kJ/mol

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The heat of solution of LiCl is -37.1 kJ/mol, and the lattice energy of LiCl(s) is 828 kJ/mol. Calculate the total heat of hydration of 1.00 mol of gas phase Li+ ions and Cl- ions.

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