Exam 6: Thermochemistry
Exam 1: Chemistry: The Study of Change175 Questions
Exam 2: Atoms Molecules and Ions156 Questions
Exam 3: Mass Relationships in Chemical Reactions194 Questions
Exam 4: Reactions in Aqueous Solutions192 Questions
Exam 5: Gases130 Questions
Exam 6: Thermochemistry119 Questions
Exam 7: Quantum Theory and the Electronic Structure of Atoms135 Questions
Exam 8: Periodic Relationships Among the Elements144 Questions
Exam 9: Chemical Bonding I: Basic Concepts136 Questions
Exam 10: Chemical Bonding II: Molecular Geometry and Hybridization of Atomic146 Questions
Exam 11: Intermolecular Forces and Liquids and Solids149 Questions
Exam 12: Physical Properties of Solutions122 Questions
Exam 13: Chemical Kinetics131 Questions
Exam 14: Chemical Equilibrium119 Questions
Exam 15: Acids and Bases178 Questions
Exam 16: Acid-Base Equilibria and Solubility Equilibria145 Questions
Exam 17: Entropy Free Energy and Equilibrium128 Questions
Exam 18: Electrochemistry154 Questions
Exam 19: Nuclear Chemistry128 Questions
Exam 20: Chemistry in the Atmosphere50 Questions
Exam 21: Metallurgy and the Chemistry of Metals63 Questions
Exam 22: Nonmetallic Elements and Their Compounds52 Questions
Exam 23: Transition Metals Chemistry and Coordination Compounds92 Questions
Exam 24: Organic Chemistry66 Questions
Exam 25: Synthetic and Natural Organic Polymers46 Questions
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The enthalpy change when a strong acid is neutralized by strong base is -56.1 kJ/mol. If 135 mL of 0.450 M HI at 23.15 C is mixed with 145 mL of 0.500 M NaOH, also at 23.15 C, what is the maximum temperature reached by the resulting solution (Assume that there is no heat loss to the container, that the specific heat of the final solution is 4.18 J/g· C, and that the density of the final solution is that of water.)
(Multiple Choice)
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Calculate the amount of work done, in joules, when 2.5 mole of H2O vaporizes at 1.0 atm and 25 C. Assume the volume of liquid H2O is negligible compared to that of vapor. (1 L·atm = 101.3 J)
(Multiple Choice)
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Find the standard enthalpy of formation of ethylene, C2H4(g), given the following data: heat of combustion of C2H4(g)= -1411 kJ/mol; H f[CO2(g)] = -393.5 kJ/mol; H f[H2O(l)] = -285.8 kJ/mol.
(Multiple Choice)
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Find H rxn for the reaction
2Ag2S(s) + 2H2O(l) 4Ag(s) + 2H2S(g) + O2(g).[ H f (Ag2S(s)) = -32.6 kJ/mol; H f (H2S(g)) = -20.5 kJ/mol; H f (H2O(l)) = -285.5 kJ/mol]
(Multiple Choice)
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Ethanol (C2H5OH) burns according to the equation C2H5OH(l) + 3O2(g) 2CO2(g) + 3H2O(l), H rxn = -1367 kJ/mol.How much heat is released when 35.0 g of ethanol is burned
(Multiple Choice)
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The bond enthalpy of the Br-Cl bond is equal to E for the reaction BrCl(g) Br(g) + Cl(g).Use the following data to find the bond enthalpy of the Br-Cl bond. ()\rightarrow() \Delta=30.91/ ()\rightarrow2() \Delta=192.9/ ()\rightarrow2() \Delta=243.4/ ()+()\rightarrow2() \Delta=29.2/
(Multiple Choice)
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Calculate the enthalpy of reaction for H2(g) + C2H4(g) C2H6(g).[ H f(C2H4(g)) = 52.3 kJ/mol; H f(C2H6(g)) = -84.7 kJ/mol]
(Multiple Choice)
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A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter. The temperature of the calorimeter and the 1.000 kg of water contained therein rose from 20.22 C to 22.82 C. The heat capacity of the calorimeter is 2.21 kJ/ C. The heat capacity of water = 4.184 J/g· C. How much heat was given off during combustion of the sample of pentane
(Multiple Choice)
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The combustion of pentane produces heat according to the equation C5H12(l) + 8O2(g) 5CO2(g) + 6H2O(l), H rxn= -3,510 kJ/mol.How many grams of CO2 are produced per 2.50 * 103 kJ of heat released
(Multiple Choice)
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Aluminum oxide can be reduced to aluminum metal using carbon, the other reaction product being carbon monoxide. Determine the enthalpy change when 12.5 g of aluminum is produced by this method. [ H f(carbon monoxide) = -110.5 kJ/mol; H f(aluminum oxide) = -1669.8 kJ/mol]
(Multiple Choice)
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At 25 C, the standard enthalpy of formation of anhydrous sodium carbonate is -1130.9 kJ/mol, whereas the standard enthalpy of formation of sodium carbonate monohydrate is -1430.1 kJ/mol. Determine H at 25 C for the reaction Na2CO3(s) + H2O(l) Na2CO3·H2O(s).(Given: H f[H2O(l)] = -285.8 kJ/mol)
(Multiple Choice)
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The heat of solution of ammonium nitrate is 26.2 kJ/mol. If a 5.368 g sample of NH4NO3 is added to 40.0 mL of water in a calorimeter at 23.5 C, what is the minimum temperature reached by the solution (The specific heat of water = 4.18 J/g· C; the heat capacity of the calorimeter = 650. J/ C.)
(Multiple Choice)
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A 26.2 g piece of copper metal is heated from 21.5 C to 201.6 C. Calculate the amount of heat absorbed by the metal. The specific heat of Cu is 0.385 J/g· C.
(Multiple Choice)
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When 0.7521 g of benzoic acid was burned in a calorimeter containing 1,000. g of water, a temperature rise of 3.60 C was observed. What is the heat capacity of the bomb calorimeter, excluding the water The heat of combustion of benzoic acid is -26.42 kJ/g.
(Multiple Choice)
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Naphthalene combustion can be used to calibrate the heat capacity of a bomb calorimeter. The heat of combustion of naphthalene is -40.1 kJ/g. When 0.8210 g of naphthalene was burned in a calorimeter containing 1,000. g of water, a temperature rise of 4.21 C was observed. What is the heat capacity of the bomb calorimeter excluding the water
(Multiple Choice)
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For which of these reactions will the difference between H and E be the greatest
(Multiple Choice)
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Calculate the standard enthalpy change for the reaction 2A + 2A2 + 4AB + B 5A2B
Given: 2+\rightarrow \Delta=-25.0/ 2\rightarrow2+ \Delta=35.0/
(Multiple Choice)
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Calculate the heat released (kJ) in the reaction of 2.20 g of sulfur dioxide gas and excess oxygen gas to form sulfur trioxide gas: 2SO2(g) + O2(g) 2SO3(g)
Given:
S(s) + O2(g) SO2(g) H = -299 kJ/mol
S(s) + 3/2O2(g) SO3(g) H = -395 kJ/mol
(Multiple Choice)
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The heat of solution of LiCl is -37.1 kJ/mol, and the lattice energy of LiCl(s) is 828 kJ/mol. Calculate the total heat of hydration of 1.00 mol of gas phase Li+ ions and Cl- ions.
(Multiple Choice)
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