Exam 14: Chemical Equilibrium

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The solubility of silver chloride can be increased by dissolving it in a solution containing ammonia.AgCl (s) ⇌\rightleftharpoons Ag+ (aq) + Cl- (aq) K1 = 1.6 x 10-10 Ag+ (aq) + 2NH3 (aq) ⇌\rightleftharpoons Ag(NH3)2+ (aq) K2 = 1.5 x 107 What is the value of the equilibrium constant for the overall reaction AgCl (s) + 2NH3 (aq) ⇌\rightleftharpoons Ag(NH3)2+ (aq) + Cl- (aq) Knet =

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Consider the reaction N2(g) + 3H2(g) ⇌ 2NH3(g). When hydrogen gas is added to this system at equilibrium, the reaction will shift towards reactants.

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Consider the chemical reaction 2NH3(g) ⇌ N2(g) + 3H2(g). The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 * 10-2. Initially, 1,220 moles of NH3(g) are present. Estimate the equilibrium concentration of N2(g).

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The equilibrium constant expression for the reaction 2BrF5 (g) ⇌\rightleftharpoons Br2 (g) + 5F2 (g) is

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For the reaction at equilibrium: 3Fe(s) + 4H2O(g) ⇌ Fe3O4(s) + 4H2(g), removing some of the product, Fe3O4(s), would:

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Kp for the reaction CO2(g) + C(s) ⇌\rightleftharpoons 2CO(g) is 1.47 at 727 ∘\circ C. Calculate Kc at this temperature.

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At 700 K, the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g) has the equilibrium constant Kc = 4.3 * 106, and the following concentrations are present: [SO2] = 0.010 M; [SO3] = 10. M; [O2] = 0.010 M. Which of the following is true based on the above

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50.0 g of N2O4 is introduced into an evacuated 2.00 L vessel and allowed to come to equilibrium with its decomposition product, N2O4(g) ⇌ 2NO2(g). For this reaction Kc = 0.133. Once the system has reached equilibrium, 5.00 g of NO2 is injected into the vessel, and the system is allowed to equilibrate once again. Calculate the mass of N2O4 in the final equilibrium mixture.

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Two moles of PCl5 are placed in a 5.0 L container. Dissociation takes place according to the equation PCl5(g) ⇌ PCl3(g) + Cl2(g). At equilibrium, 0.40 mol of Cl2 are present. Calculate the equilibrium constant (Kc) for this reaction under the conditions of this experiment.

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The data below refer to the following reaction: 2NO(g) + Br2(g) ⇌ 2NOBr(g) Concentration (M) [] [] Initial 2.5 5.0 1.0 Equilibrium 2.0 - - Find the concentration of Br2 when the system reaches equilibrium.

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When the following reaction is at equilibrium, which of these relationships is always true 2 O3(g) ⇌\rightleftharpoons 3 O2(g)

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Given the following information: 2A(g) + B(g) ⇌\rightleftharpoons A2B(g) Kp1 2A(g) + C2(g) ⇌\rightleftharpoons 2AC(g) Kp2 3/2A2(g) + B(g) + C(g) ⇌\rightleftharpoons AC(g) + A2B(g) Kp3 Which relationship represents the equilibrium constant for the reaction: 3A2(g) + 3B(g) + 2C(g) ⇌\rightleftharpoons 3A2B(g) + C2(g) Knet = ?

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A solution was prepared such that the initial concentrations of Cu2+(aq) and CN-(aq) were 0.0120 M and 0.0400 M, respectively. These ions react according to the following chemical equation: Cu2+(aq) + 4CN-(aq) Kc= 1.0 x 1025 ⇌ Cu(CN)42-(aq) What will be the concentration of Cu2+(aq) at equilibrium

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A quantity of liquid methanol, CH3OH, is introduced into a rigid 3.00-L vessel, the vessel is sealed, and the temperature is raised to 500K. At this temperature, the methanol vaporizes and decomposes according to the reaction CH3OH(g) ⇌ CO(g) + 2 H2(g), Kc= 6.90*10-2.If the concentration of H2 in the equilibrium mixture is 0.426M, what mass of methanol was initially introduced into the vessel

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The Kc for the reaction CO2(g) + H2(g) ⇌ H2O(g) + CO(g) is 1.6 at about 990ºC. Calculate the number of moles of carbon dioxide in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.

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5.00 mol of ammonia are introduced into a 5.00 L reactor vessel in which it partially dissociates at high temperatures.2NH3(g) ⇌ 3H2(g) + N2(g) At equilibrium and a particular temperature, 1.00 mole of ammonia remains. Calculate Kc for the reaction.

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The Kc for the reaction CO2(g) + H2(g) ⇌ H2O(g) + CO(g) is 1.6 at about 990ºC. Calculate the number of moles of carbon monoxide in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.

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The equilibrium constants for the chemical reaction N2(g) + O2(g) ⇌ 2NO(g) are KP = 1.1 * 10-3 and 3.6 * 10-3 at 2,200 K and 2,500 K, respectively.Which one of these statements is true

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Kp for the reaction of SO2(g) with O2 to produce SO3(g) is 3 * 1024 . Calculate Kc for this equilibrium at 25ºC. (The relevant reaction is 2SO2(g) + O2(g) ⇌\rightleftharpoons 2SO3(g).)

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Equilibrium is established for the reaction 2X(s) + Y(g) ⇌\rightleftharpoons 2Z(g) at 500K, Kc = 100. Determine the concentration of Z in equilibrium with 0.2 mol X and 0.50 M Y at 500K.

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