Exam 14: Chemical Equilibrium

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Consider the following equilibria: 2SO3(g) ⇌ 2SO2(g) + O2(g) Kc = 2.3 * 10-7 2NO3(g) ⇌ 2NO2(g) + O2(g) Kc = 1.4 * 10-3 Calculate the equilibrium constant for the reaction SO2(g) + NO3(g) ⇌ SO3(g) + NO2(g)

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4.21 moles of S2Cl4 are introduced into a 2.0 L vessel.S2Cl4(g) ⇌ 2SCl2(g) At equilibrium, 1.25 moles of S2Cl4 are found to remain in the container. Calculate Kc for this reaction.

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A solution was prepared such that the initial concentrations of Cu2+(aq) and CN-(aq) were 0.0120 M and 0.0400 M, respectively. These ions react according to the following chemical equation: Cu2+(aq)+4CN−(aq)⇌Cd(CN)42−(aq)\mathrm{Cu}^{2+}(a q)+4 \mathrm{CN}^{-}(a q) \rightleftharpoons \mathrm{Cd}(\mathrm{CN})_{4}^{2-}(a q) Kc=1.0×1025\mathrm{K}_{\mathrm{c}}=1.0 \times 10^{25} What will be the concentration of CN-(aq) at equilibrium

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Consider the following equilibrium: 4NH3(g) + 3O2(g) ⇌ 2N2(g) + 6H2O(g) + 1531 kJ The concentrations of the reactants will increase when the temperature is increased.

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For the equilibrium reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), Δ\Delta Hºrxn = -198 kJ/mol. Which one of these factors would cause the equilibrium constant to increase

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Consider the equilibrium C(s) + H2O(g) ⇌ CO(g) + H2(g), Δ\Delta H = 2296 J. The concentration of carbon monoxide will increase if the temperature of this system is raised.

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Concerning the following reaction at equilibrium: 3Fe(s) + 4H2O(g) ⇌ Fe3O4(s) + 4H2(g), increasing the concentration of the Fe(s) would:

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In which of these gas-phase equilibria is the yield of products increased by increasing the total pressure on the reaction mixture

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Consider the two gaseous equilibria: ()+()\leftrightharpoons() 2()\leftrightharpoons()+() The values of the equilibrium constants K1 and K2 are related by

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When the reaction 2H2S(g) ⇌ 2H2(g) + S2(g) is carried out at 1065 ∘\circ C, Kp = 0.012. Starting with pure H2S at 1065 ∘\circ , what must the initial pressure of H2S be if the equilibrated mixture at this temperature is to contain 0.250 atm of H2(g)

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A reaction with an equilibrium constant Kc = 1.5 x 1021 would consist of which of the following at equilibrium:

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When the following reaction is at equilibrium, which of these relationships is always true 2NOCl(g) ⇌\rightleftharpoons 2NO(g) + Cl2(g)

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Equilibrium constants are known for the following reactions: S(s) + 3/2O2(g) ⇌ SO3(g) Kc = 9.2 * 1023 SO3(g) ⇌ SO2(g) + 1/2O2(g) Kc = 4.8 * 10- 4 Thus, for the reaction S(s) + O2(g) ⇌ SO2(g), Kc = 4.4 * 1020.

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A reaction with an equilibrium constant Kc = 1.5 x 10-25 would consist of which of the following at equilibrium:

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Consider the equilibrium C(s) + H2O(g) ⇌ CO(g) + H2(g), Δ\Delta H = 2296 J. The concentration of carbon will not change if gaseous water is added to the system.

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Given the following data for the reaction: A(g) + 2B(s) ⇌ AB2(g) Temperature () 300 1.2\times1 600 12 900 2.2\times1 This data represents an endothermic reaction.

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Consider this reaction at equilibrium at a total pressure P1: 2SO2(g) + O2(g) ⇌ 2SO3(g) Suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished. The new equilibrium total pressure will be

(Multiple Choice)
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4.2 mol of oxygen and 4.0 mol of NO are introduced to an evacuated 0.50 L reaction vessel. At a specific temperature, the equilibrium 2NO(g) + O2(g) ⇌ 2NO2(g) is reached when [NO] = 1.6 M. Calculate Kc for the reaction at this temperature.

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2.50 mol NOCl was placed in a 2.50 L reaction vessel at 400ºC. After equilibrium was established, it was found that 28% of the NOCl had dissociated according to the equation 2NOCl(g) ⇌\rightleftharpoons 2NO(g) + Cl2(g).Calculate the equilibrium constant, Kc, for the reaction.

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Consider the reaction, N2(g) + 3H2(g) ⇌ 2NH3(g). Kc = 8.1 x 10-3 at 900 K.What is the value of Kc for NH3(g) ⇌ (1/2)N2(g) + 3/2H2(g)

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