Exam 14: Chemical Equilibrium
Exam 1: Chemistry: The Study of Change175 Questions
Exam 2: Atoms Molecules and Ions156 Questions
Exam 3: Mass Relationships in Chemical Reactions194 Questions
Exam 4: Reactions in Aqueous Solutions192 Questions
Exam 5: Gases130 Questions
Exam 6: Thermochemistry119 Questions
Exam 7: Quantum Theory and the Electronic Structure of Atoms135 Questions
Exam 8: Periodic Relationships Among the Elements144 Questions
Exam 9: Chemical Bonding I: Basic Concepts136 Questions
Exam 10: Chemical Bonding II: Molecular Geometry and Hybridization of Atomic146 Questions
Exam 11: Intermolecular Forces and Liquids and Solids149 Questions
Exam 12: Physical Properties of Solutions122 Questions
Exam 13: Chemical Kinetics131 Questions
Exam 14: Chemical Equilibrium119 Questions
Exam 15: Acids and Bases178 Questions
Exam 16: Acid-Base Equilibria and Solubility Equilibria145 Questions
Exam 17: Entropy Free Energy and Equilibrium128 Questions
Exam 18: Electrochemistry154 Questions
Exam 19: Nuclear Chemistry128 Questions
Exam 20: Chemistry in the Atmosphere50 Questions
Exam 21: Metallurgy and the Chemistry of Metals63 Questions
Exam 22: Nonmetallic Elements and Their Compounds52 Questions
Exam 23: Transition Metals Chemistry and Coordination Compounds92 Questions
Exam 24: Organic Chemistry66 Questions
Exam 25: Synthetic and Natural Organic Polymers46 Questions
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Consider the following equilibria:
2SO3(g) ⇌ 2SO2(g) + O2(g) Kc = 2.3 * 10-7
2NO3(g) ⇌ 2NO2(g) + O2(g) Kc = 1.4 * 10-3
Calculate the equilibrium constant for the reaction
SO2(g) + NO3(g) ⇌ SO3(g) + NO2(g)
(Multiple Choice)
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4.21 moles of S2Cl4 are introduced into a 2.0 L vessel.S2Cl4(g) ⇌ 2SCl2(g) At equilibrium, 1.25 moles of S2Cl4 are found to remain in the container. Calculate Kc for this reaction.
(Multiple Choice)
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A solution was prepared such that the initial concentrations of Cu2+(aq) and CN-(aq) were 0.0120 M and 0.0400 M, respectively. These ions react according to the following chemical equation:
What will be the concentration of CN-(aq) at equilibrium
(Multiple Choice)
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Consider the following equilibrium:
4NH3(g) + 3O2(g) ⇌ 2N2(g) + 6H2O(g) + 1531 kJ
The concentrations of the reactants will increase when the temperature is increased.
(True/False)
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For the equilibrium reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), Hºrxn = -198 kJ/mol. Which one of these factors would cause the equilibrium constant to increase
(Multiple Choice)
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Consider the equilibrium C(s) + H2O(g) ⇌ CO(g) + H2(g), H = 2296 J. The concentration of carbon monoxide will increase if the temperature of this system is raised.
(True/False)
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Concerning the following reaction at equilibrium: 3Fe(s) + 4H2O(g) ⇌ Fe3O4(s) + 4H2(g), increasing the concentration of the Fe(s) would:
(Multiple Choice)
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In which of these gas-phase equilibria is the yield of products increased by increasing the total pressure on the reaction mixture
(Multiple Choice)
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Consider the two gaseous equilibria: ()+()\leftrightharpoons() 2()\leftrightharpoons()+() The values of the equilibrium constants K1 and K2 are related by
(Multiple Choice)
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When the reaction 2H2S(g) ⇌ 2H2(g) + S2(g) is carried out at 1065 C, Kp = 0.012. Starting with pure H2S at 1065 , what must the initial pressure of H2S be if the equilibrated mixture at this temperature is to contain 0.250 atm of H2(g)
(Multiple Choice)
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A reaction with an equilibrium constant Kc = 1.5 x 1021 would consist of which of the following at equilibrium:
(Multiple Choice)
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When the following reaction is at equilibrium, which of these relationships is always true
2NOCl(g) 2NO(g) + Cl2(g)
(Multiple Choice)
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Equilibrium constants are known for the following reactions:
S(s) + 3/2O2(g) ⇌ SO3(g) Kc = 9.2 * 1023
SO3(g) ⇌ SO2(g) + 1/2O2(g) Kc = 4.8 * 10- 4
Thus, for the reaction S(s) + O2(g) ⇌ SO2(g), Kc = 4.4 * 1020.
(True/False)
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A reaction with an equilibrium constant Kc = 1.5 x 10-25 would consist of which of the following at equilibrium:
(Multiple Choice)
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Consider the equilibrium C(s) + H2O(g) ⇌ CO(g) + H2(g), H = 2296 J. The concentration of carbon will not change if gaseous water is added to the system.
(True/False)
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Given the following data for the reaction: A(g) + 2B(s) ⇌ AB2(g) Temperature () 300 1.2\times1 600 12 900 2.2\times1 This data represents an endothermic reaction.
(True/False)
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Consider this reaction at equilibrium at a total pressure P1: 2SO2(g) + O2(g) ⇌ 2SO3(g)
Suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished. The new equilibrium total pressure will be
(Multiple Choice)
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4.2 mol of oxygen and 4.0 mol of NO are introduced to an evacuated 0.50 L reaction vessel. At a specific temperature, the equilibrium 2NO(g) + O2(g) ⇌ 2NO2(g) is reached when [NO] = 1.6 M. Calculate Kc for the reaction at this temperature.
(Multiple Choice)
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2.50 mol NOCl was placed in a 2.50 L reaction vessel at 400ºC. After equilibrium was established, it was found that 28% of the NOCl had dissociated according to the equation 2NOCl(g) 2NO(g) + Cl2(g).Calculate the equilibrium constant, Kc, for the reaction.
(Multiple Choice)
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Consider the reaction, N2(g) + 3H2(g) ⇌ 2NH3(g). Kc = 8.1 x 10-3 at 900 K.What is the value of Kc for NH3(g) ⇌ (1/2)N2(g) + 3/2H2(g)
(Multiple Choice)
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