Exam 14: Chemical Equilibrium

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For the reaction 2NOCl(g) ⇌ 2NO(g) + Cl2(g), Kc = 8.0 at a certain temperature. What concentration of NOCl must be put into an empty 4.00 L reaction vessel in order that the equilibrium concentration of NOCl be 1.00 M

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Consider this gas phase equilibrium system: PCl5(g) ⇌ PCl3(g) + Cl2(g) Δ\Delta Hºrxn = +87.8 kJ/mol.Which of these statements is false

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For the following reaction at equilibrium, which change will cause the equilibrium to shift to the left 2NOBr(g) ⇌ 2NO(g) + Br2(g), Δ\Delta Hºrxn = 30 kJ/mol

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What is the correct equilibrium constant expression for this reaction 2HI(g) ⇌ H2(g) + I2(g)

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Consider the chemical reaction 2NH3(g) ⇌ N2(g) + 3H2(g). The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 * 10-2. Initially, 1,220 moles of NH3(g) are present. Estimate the equilibrium concentration of H2(g).

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For the reaction SO2(g) + NO2(g) ⇌\rightleftharpoons SO3(g) + NO(g), the equilibrium constant is 18.0 at 1,200ºC. If 1.0 mole of SO2 and 2.0 moles of NO2 are placed in a 20. L container, what concentration of SO3 will be present at equilibrium

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For the reaction H2(g) + I2(g) ⇌ 2HI(g), Kc = 50.2 at 445ºC. If [H2] = [I2] = [HI] = 1.75 * 10-3 M at 445ºC, which of the following is true based on the above

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The common allotropes of carbon (graphite and diamond) equilibrate as follows: C(gr) ⇌ C(dia) with equilibrium constant K = 0.32. The molar volumes of graphite and diamond are, respectively, 5.30 cm3/mol and 3.42 cm3/mol; Δ\Delta Hf of diamond is 1.90 kJ/mol. This data suggests that the formation of diamond is favored at

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Consider the reaction N2(g) + O2(g) ⇌\rightleftharpoons 2NO(g), for which Kc = 0.10 at 2,000ºC. Starting with initial concentrations of 0.040 M of N2 and 0.040 M of O2, determine the equilibrium concentration of NO.

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Consider the following reactions and their associated equilibrium constants: +2\leftrightharpoons \leftrightharpoons+ For the reaction A + 2B (⇌) D + E, having equilibrium constant Kc,

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At 700 K, the reaction 2SO2(g) + O2(g) ⇌ 2SO3(g) has the equilibrium constant Kc = 4.3 * 106 , and the following concentrations are present: [SO2] = 0.10 M; [SO3] = 10. M; [O2] = 0.10 M. Which of the following is true based on the above

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The Kc for the reaction CO2(g) + H2(g) ⇌ H2O(g) + CO(g) is 1.6 at about 990ºC. Calculate the number of moles of water in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.

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For the reaction at equilibrium: CO(g) + H2O(g) ⇌ CO2(g) + H2(g), increasing the volume of the container would:

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Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine.CCl4(g) + 1/2O2(g) ⇌\rightleftharpoons COCl2(g) + Cl2(g), Kc = 4.4 * 109 at 1,000 K Calculate Kc for the reaction 2CCl4(g) + O2(g) ⇌\rightleftharpoons 2COCl2(g) + 2Cl2(g).

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For the reaction PCl3(g) + Cl2(g) ⇌ PCl5(g) at a particular temperature, Kc = 24.3. Suppose a system at that temperature is prepared with [PCl3] = 0.10 M, [Cl2] = 0.15 M, and [PCl5] = 0.60 M. Which of the following is true based on the above

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Concerning the following reaction at equilibrium: 3Fe(s) + 4H2O(g) ⇌ Fe3O4(s) + 4H2(g), increasing the volume of the container would:

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The equilibrium constant for the chemical equation 2NO(g) + O2(g) ⇌ 2NO2(g) is two times the equilibrium constant for the chemical equation NO(g) + 1/2O2(g) ⇌ NO2(g).

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Consider the reaction N2(g) + 3H2(g) ⇌ 2NH3(g). When nitrogen is added to the system at equilibrium, the reaction will shift toward the products.

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Calculate Kc for the reaction 2HI(g) ⇌\rightleftharpoons H2(g) + I2(g) given that the concentrations of each species at equilibrium are as follows: [HI] = 0.85 mol/L, [I2] = 0.60 mol/L, [H2] = 0.27 mol/L.

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Consider the following equilibrium: 4NH3(g) + 3O2(g) ⇌ 2N2(g) + 6H2O(g) + 1531 kJ The concentrations of the products will increase when the temperature is increased.

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