Exam 14: Chemical Equilibrium

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Hydrogen iodide decomposes according to the equation 2HI(g) ⇌\rightleftharpoons H2(g) + I2(g), for which Kc = 0.0156 at 400ºC. 0.550 mol HI was injected into a 2.00 L reaction vessel at 400ºC. Calculate the concentration of HI at equilibrium.

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Kp for the reaction 4CuO(s) ⇌\rightleftharpoons 2Cu2O(s) + O2(g) is 0.49 at 1024 ∘\circ C. Calculate Kc at this temperature

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Hydrogen iodide decomposes according to the equation: 2HI(g) ⇌ H2(g) + I2(g), Kc = 0.0156 at 400ºC a 0.660 mol sample of HI was injected into a 2.00 L reaction vessel held at 400ºC.Calculate the concentration of HI at equilibrium.

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1.25 moles of NOCl were placed in a 2.50 L reaction chamber at 427ºC. After equilibrium was reached, 1.10 moles of NOCl remained. Calculate the equilibrium constant, Kc, for the reaction 2NOCl(g) ⇌\rightleftharpoons 2NO(g) + Cl2(g).

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Hydrogen iodide decomposes according to the equation 2HI(g) ⇌\rightleftharpoons H2(g) + I2(g), for which Kc = 0.0156 at 400ºC. 0.550 mol HI was injected into a 2.00 L reaction vessel at 400ºC. Calculate the concentration of H2 at equilibrium.

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Consider the reaction N2(g) + 3H2(g) ⇌ 2NH3(g). When nitrogen is removed from the system at equilibrium, the hydrogen (H2) concentration will increase.

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For the reaction at equilibrium 2SO3 ⇌ 2SO2 + O2 ( Δ\Delta Hºrxn= 198 kJ/mol), increasing the reaction temperature would:

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The following data for the reaction: A(g) + 2B(s) ⇌ AB2(g) provides evidence that the reaction is exothermic. Temperature () 300 1.5\times1 600 55 900 3.4\times1

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Consider the reaction N2(g) + 3H2(g) ⇌ 2NH3(g). The production of ammonia is an exothermic reaction. When heat is added to the equilibrium system it will shift to increase the amount of ammonia produced.

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Phosgene, COCl2, a poisonous gas, decomposes according to the equation COCl2(g) ⇌\rightleftharpoons CO(g) + Cl2(g). Calculate Kp for this reaction if Kc = 0.083 at 900ºC.

(Multiple Choice)
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The equilibrium constant for the reaction Ni(s) + 4CO(g) ⇌\rightleftharpoons Ni(CO)4(g) is 5.0 * 104 at 25ºC. What is the equilibrium constant for the reaction Ni(CO)4(g) ⇌\rightleftharpoons Ni(s) + 4CO(g)

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75.0 g of PCl5(g) is introduced into a 3.00 L vessel containing 10.0 g of Cl2(g), and the system is allowed to reach equilibrium at 250ºC.PCl5(g) ⇌ PCl3(g) + Cl2(g) If Kp = 1.80 for this reaction, what is the total pressure inside the vessel at equilibrium

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For the reaction H2(g) + I2(g) ⇌ 2HI(g), KP = Kc.

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For the nitrogen fixation reaction 3H2(g) + N2(g) ⇌ 2NH3(g), Kc = 6.0 * 10-2 at 500 ∘\circ C. If 0.250 M H2 and 0.050 M NH3 are present at equilibrium, what is the equilibrium concentration of N2

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The conditions used in the Haber process to enhance the yield of ammonia are low pressure and high temperature.

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At 250ºC, the equilibrium constant Kp for the reaction PCl5(g) ⇌\rightleftharpoons PCl3(g) + Cl2(g) is 1.80. Sufficient PCl5 is put into a reaction vessel to give an initial pressure of 2.74 atm at 250ºC. Calculate the pressure of PCl5 after the system has reached equilibrium.

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Which is the correct equilibrium constant expression for the following reaction Fe2O3 (s) + 3H2 (g) ⇌\rightleftharpoons 2Fe (s) + 3H2O (g)

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Consider this reaction at equilibrium: 2SO2(g) + O2(g) ⇌ 2SO3(g), Δ\Delta Hºrxn = -198 kJ/mol If the volume of the system is compressed at constant temperature, what change will occur in the position of the equilibrium

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When the substances in the equation below are at equilibrium, at pressure P and temperature T, the equilibrium can be shifted to favor the products by CuO(s) + H2(g) ⇌ H2O(g) + Cu(s) Δ\Delta Hºrxn = -2.0 kJ/mol

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Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide as shown below.CaCO3(s) ⇌ CaO(s) + CO2(g) The KP for this reaction is 1.16 at 800 ∘\circ C. A 5.00 L vessel containing 10.0 g of CaCO3(s) was evacuated to remove the air, sealed, and then heated to 800 ∘\circ C. Ignoring the volume occupied by the solid, what will be the overall mass percent of carbon in the solid once equilibrium is reached

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