Exam 16: Additional Aqueous Equilibria: Chemistry and the Oceans

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A solution of sulfuric acid (H2SO4, 25.00 mL) was titrated to completion with 34.55 mL of 0.1020 M sodium hydroxide. What was the concentration of the sulfuric acid?

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Which of the following species is a Lewis base?

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Calculate the solubility of MgF2 in water if the Ksp for the compound is 6.40 109.

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Determine the molar concentration of Ag(aq) ions in a 1.00 M solution of AgCl2 with no excess chloride. Given: Kf 2.50 105 for AgCl2.

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Define the term Lewis base and provide an example.

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A solution of formic acid (0.15 M, 15.00 mL), a monoprotic acid, was titrated with 18.50 mL of 0.10 M sodium hydroxide (Ka of formic acid 1.80 104). What is the final pH of this solution?

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Hydrated transition metal ions produce solutions that are ________

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The pKa of a weak acid was determined to be 3.39 by measuring the pH of a solution containing the weak acid at 0.20 M and its conjugate base. The measured pH was 3.27. What was the concentration of the conjugate base?

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Which of the following represents the correct Ksp expression for the reaction shown below? Al2(SO4)3(s) Which of the following represents the correct K<sub>sp </sub>expression for the reaction shown below? Al<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub>(s)   2Al<sup>3</sup><font face=symbol><sup></sup></font>(aq) <font face=symbol></font> 3SO<sub>4</sub><sup>2</sup><font face=symbol><sup></sup></font>(aq) 2Al3(aq) 3SO42(aq)

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What is the equilibrium concentration of Cu(aq) in a solution that is 0.0200 M solution in CuNO3 and 0.450 M HCl(aq)? Given: Cu(aq) 3Cl(aq) What is the equilibrium concentration of Cu<font face=symbol><sup></sup></font>(aq) in a solution that is 0.0200 M solution in CuNO<sub>3</sub> and 0.450 M HCl(aq)? Given: Cu<font face=symbol><sup></sup></font>(aq) <font face=symbol></font> 3Cl<font face=symbol><sup></sup></font>(aq)   CuCl<sub>3</sub><sup>2</sup><font face=symbol><sup></sup></font> K<sub>f</sub> <font face=symbol></font> 5 <font face=symbol></font> 10<sup>5</sup>. CuCl32 Kf 5 105.

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What is the solubility of barium sulfate in a solution containing 0.050 M sodium sulfate? The Ksp value for barium sulfate is 1.1 1010.

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Which statement A-D regarding acids and bases is not correct?

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The Yucca Mountain repository in Nevada, which is intended for the long-term storage of nuclear waste, has long been mired in controversy. One ongoing concern is whether the stainless steel alloy containers could be corroded by salts such as calcium fluoride. If the calcium ion concentration in water inside Yucca Mountain is 1.25 103 M, what is the maximum possible concentration of fluoride ion in this water? Assume calcium fluoride Ksp 2.2 1010 at the temperatures inside the nuclear waste depository.

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Which of the following species is least likely to function as a ligand in a transition metal complex ion?

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Vitamin C is a monoprotic weak acid, which also is called ascorbic acid (C6H8O6, 176 g/mol). A vitamin C tablet weighing 0.75 g was dissolved in 50.0 mL of water and titrated with 0.250 M sodium hydroxide. It took 12.5 mL of the NaOH solution to reach the end point. What is the percentage of vitamin C in the tablet? Only the vitamin C reacted with the NaOH.

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Which of the following cannot be mixed together in water to produce a buffer solution?

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The solubility product for an insoluble salt with the formula MX4 is written as ________, where s is the molar solubility.

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Which of the following compounds contains a coordinate covalent bond?

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What is indicated by the shape of the titration curve? What is indicated by the shape of the titration curve?

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One of the following solutions is acidic. Identify which, explain why, and write an appropriate reaction equation showing the production of hydronium ion. CaCl2, CrCl2, MgCl2, NaCl

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