Exam 13: Nuclear Magnetic Resonance Spectroscopy

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The coupling constant, J, between the protons of chloroethane is 7 Hz when the spectrum is obtained at 250 MHz. What is the coupling constant between these protons when the spectrum is acquired at 500 MHz?

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Which of the protons in the following molecule appear furthest downfield in the 1H NMR spectrum? Which of the protons in the following molecule appear furthest downfield in the <sup>1</sup>H NMR spectrum?

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Which of the following is true for pair of enantiotopic protons? 1)They will appear at the same chemical shift in an achiral (i.e., nonchiral environment) 2)They will appear at the same chemical shifts in a chiral environment

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Which C9H10O compound gives the following 1H NMR spectrum? Which C<sub>9</sub>H<sub>10</sub>O compound gives the following <sup>1</sup>H NMR spectrum?

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Which C4H9Br compound gives a triplet at approximately 3.5 ppm in the 1H NMR spectrum? Which C<sub>4</sub>H<sub>9</sub>Br compound gives a triplet at approximately 3.5 ppm in the <sup>1</sup>H NMR spectrum?

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Consider the compound shown below. Consider the compound shown below.   The above compound would produce a signal further downfield in a <sup>13</sup>C NMR spectrum than  The above compound would produce a signal further downfield in a 13C NMR spectrum than Consider the compound shown below.   The above compound would produce a signal further downfield in a <sup>13</sup>C NMR spectrum than

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Which of the following combinations of peaks appears in the 1H NMR spectrum of 1,2-dimethyoxyethane, CH3OCH2CH2OCH3?

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What is the hydrogen deficiency index for a compound with a molecular formula of C6H11N?

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For each of the compounds below tell how many signals you would expect the molecule to have in its normal, broadband hydrogen-decoupled 13C NMR spectra. Enter the numerical value in the blank provided to the left of the structure. -_______ For each of the compounds below tell how many signals you would expect the molecule to have in its normal, broadband hydrogen-decoupled <sup>13</sup>C NMR spectra. Enter the numerical value in the blank provided to the left of the structure. -_______

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Which of the following compounds gives a 1H NMR spectrum consisting of only a singlet, triplet and quintet?

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Which C6H12O2 compound gives the following 1H NMR spectrum? Which C<sub>6</sub>H<sub>12</sub>O<sub>2</sub> compound gives the following <sup>1</sup>H NMR spectrum?

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How many signals appear in the proton-decoupled 13C NMR spectrum of 1,4-dibromobenzene?

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What is the hydrogen deficiency index for a compound with a molecular formula of C10H16O2?

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Which of the protons in the following molecule appear furthest downfield in the 1H NMR spectrum? Which of the protons in the following molecule appear furthest downfield in the <sup>1</sup>H NMR spectrum?

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Which of the following combinations of peaks appears in the 1H NMR spectrum of 1,4-dimethyoxyethane, CH3OCH2CH2CH2CH2OCH3?

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Identify the compound (C8H10O2) that gives the following 1H NMR spectrum. Identify the compound (C<sub>8</sub>H<sub>10</sub>O<sub>2</sub>) that gives the following <sup>1</sup>H NMR spectrum.

(Essay)
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For each of the compounds below tell how many signals you would expect the molecule to have in its normal, broadband hydrogen-decoupled 13C NMR spectra. Enter the numerical value in the blank provided to the left of the structure. -_______ For each of the compounds below tell how many signals you would expect the molecule to have in its normal, broadband hydrogen-decoupled <sup>13</sup>C NMR spectra. Enter the numerical value in the blank provided to the left of the structure. -_______

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Which of the following combinations of peaks appears in the 1H NMR spectrum of 2-methylpropane?

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How many sets of equivalent protons are there in 2-methylhexane?

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What is the hydrogen deficiency index for a compound with a molecular formula of C6H6Br2?

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