Exam 13: Nuclear Magnetic Resonance Spectroscopy

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MATCHING The following questions pertain to the display of NMR spectra. Match a term to each description below. -The vertical axis of spectrum displays the _____ of the signal.

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Which feature in the 1H NMR spectrum provides information about the number of types of different protons in a compound?

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Which of the following is not true regarding 1H NMR spectroscopy?

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How many signals appear in the proton-decoupled 13C NMR spectrum of 1,3-dibromobenzene?

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Which of the protons in the following molecule appear at the highest δ\delta -value in the 1H NMR spectrum?  Which of the protons in the following molecule appear at the highest  \delta -value in the <sup>1</sup>H NMR spectrum?

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Which of the following is not true regarding 1H NMR spectroscopy?

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Which of the protons in the following molecule appear furthest downfield in the 1H NMR spectrum? Which of the protons in the following molecule appear furthest downfield in the <sup>1</sup>H NMR spectrum?

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How many signals appear in the proton-decoupled 13C NMR spectrum of 4-bromotoluene?

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Predict the splitting of each of the numbered hydrogen atoms in the structure below in a 1H NMR spectrum. Identify as singlet, doublet, triplet, quartet, quintet, sextet, septet, .... Place the correct splitting in the blank to the left of the number. Predict the splitting of each of the numbered hydrogen atoms in the structure below in a <sup>1</sup>H NMR spectrum. Identify as singlet, doublet, triplet, quartet, quintet, sextet, septet, .... Place the correct splitting in the blank to the left of the number.   -______ 1 -______ 1

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Identify the compound (C3H7Cl) that gives the following 1H NMR spectrum. Identify the compound (C<sub>3</sub>H<sub>7</sub>Cl) that gives the following <sup>1</sup>H NMR spectrum.

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MATCHING The following questions pertain to the display of NMR spectra. Match a term to each description below. -When looking at a NMR spectrum the right-hand part of the chart is the _____.

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The splitting of signals in the 1H NMR spectrum provides information about the number of neighboring protons of each proton in the compound.

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How many signals appear in the proton-decoupled 13C NMR spectrum of 2-bromotoluene?

(Multiple Choice)
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Identify the compound (C4H6O2) that gives the following 1H NMR spectrum. Identify the compound (C<sub>4</sub>H<sub>6</sub>O<sub>2</sub>) that gives the following <sup>1</sup>H NMR spectrum.

(Essay)
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Identify the ratio of peak areas upon integration of the 1H NMR spectrum for A, B, and C respectively. Enter the numbers separated by colons. Identify the ratio of peak areas upon integration of the <sup>1</sup>H NMR spectrum for A, B, and C respectively. Enter the numbers separated by colons.

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Which of the protons in the following molecule appear at the highest δ\delta -value in the 1H NMR spectrum?  Which of the protons in the following molecule appear at the highest  \delta -value in the <sup>1</sup>H NMR spectrum?

(Multiple Choice)
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Which of the following is true for pair of diastereotopic protons? 1)They will appear at the same chemical shift in an achiral (i.e., nonchiral environment) 2)They will appear at the same chemical shifts in a chiral environment

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Which of the protons in the following molecule appear at the highest δ\delta -value in the 1H NMR spectrum?  Which of the protons in the following molecule appear at the highest  \delta -value in the <sup>1</sup>H NMR spectrum?

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Which of the carbon atoms in the molecule appears furthest downfield in the 13C NMR spectrum? Which of the carbon atoms in the molecule appears furthest downfield in the <sup>13</sup>C NMR spectrum?

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Identify the compound (C4H8O) that gives the following 1H NMR spectrum. Identify the compound (C<sub>4</sub>H<sub>8</sub>O) that gives the following <sup>1</sup>H NMR spectrum.

(Short Answer)
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