Exam 5: Thermochemistry

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The value of ΔH° for the reaction below is -336 kJ. Calculate the heat (kJ)released to the surroundings when 23.0 g of HCl is formed. CH4 (g) + 3Cl2 (g) → CHCl3 (l) + 3HCl (g)

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In the reaction below, ΔH°f is zero for ________. Ni (s) + 2CO (g) + 2PF3 (g) → Ni(CO)2(PF3)2 (l)

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The ΔE of a system that releases 12.4 J of heat and does 4.2 J of work on the surroundings is ________ J.

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For a given process at constant pressure, w is positive. This means that the process involves ________.

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The value of ΔH° for the reaction below is -126 kJ. ________ kj are released when 2.00 mol of NaOH is formed in the reaction? 2Na2O2 (s) + 2H2O (l) → 4NaOH (s) + O2 (g)

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The temperature of a 11.8 g sample of calcium carbonate [CaCO3 (s)] increases from 24.8 °C to 38.0 °C. If the specific heat of calcium carbonate is 0.82 J/g-K, how many joules of heat are absorbed?

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Given the following reactions N2 (g) + O2 (g) → 2NO (g)ΔH = +180.7 kJ 2NO( g) + O2 (g) → 2NO2 (g)ΔH = -113.1 kJ The enthalpy for the decomposition of nitrogen dioxide into molecular nitrogen and oxygen 2NO2 (g) → N2 (g) + 2O2 (g) Is ________ kJ.

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For which one of the following reactions is the value of ΔH°rxn equal to ΔH°f for the product?

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One joule equals 1 kg-m2/s2.

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When work is done on a system, w will be a ________ value.

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Which of the following is a statement of the first law of thermodynamics?

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The specific heat capacity of solid copper metal is 0.385 J/g-K. How many joules of heat are needed to raise the temperature of a 2.12-kg block of copper from 25.0 °C to 99.9 °C?

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In the presence of excess oxygen, methane gas burns in a constant-pressure system to yield carbon dioxide and water: CH4 (g) + 2O2 (g) → CO2 (g) + 2H2O (l)△H = -890.0 kJ Calculate the value of q (kJ)in this exothermic reaction when 1.80 g of methane is combusted at constant pressure.

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The ΔH for the solution process when solid sodium hydroxide dissolves in water is 44.4 kJ/mol. When a 12.6-g sample of NaOH dissolves in 250.0 g of water in a coffee-cup calorimeter, the temperature increases from 23.0 °C to ________°C. Assume that the solution has the same specific heat as liquid water, i.e., 4.18 J/g-K.

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Given the data in the table below, ΔH°rxn for the reaction 3NO2 (g) + H2O (l) → 2HNO3 (aq) + NO (g) Is ________ kJ. Given the data in the table below, ΔH°<sub>rxn</sub> for the reaction 3NO<sub>2</sub> (g) + H<sub>2</sub>O (l) → 2HNO<sub>3</sub> (aq) + NO (g) Is ________ kJ.

(Multiple Choice)
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Given the data in the table below, ΔH°rxn for the reaction Ca(OH)2 + 2H3AsO4 → Ca(H2AsO4)2 + 2H2O Is ________ kJ. Given the data in the table below, ΔH°<sub>rxn</sub> for the reaction Ca(OH)<sub>2</sub> + 2H<sub>3</sub>AsO<sub>4</sub> → Ca(H<sub>2</sub>AsO<sub>4</sub>)<sub>2</sub> + 2H<sub>2</sub>O Is ________ kJ.

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The kinetic energy of a 23.2-g object moving at a speed of 81.9 km/hr is ________ kcal.

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Calculate the work (kJ)done during a reaction in which the internal volume expands from 14 L to 50 L against a vacuum (an outside pressure of 0 atm).

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The energy released by combustion of 1 g of a substance is called the ________ of the substance.

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The standard enthalpy change of a reaction is the enthalpy change when all reactants and products are at ________ pressure and a specific temperature.

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