Exam 8: Basic Concepts of Chemical Bonding

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Using the table of bond dissociation energies, the ΔH for the following gas-phase reaction is ________ kJ. Using the table of bond dissociation energies, the ΔH for the following gas-phase reaction is ________ kJ.    Using the table of bond dissociation energies, the ΔH for the following gas-phase reaction is ________ kJ.

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C

Ni2+ ions are represented by the electron configuration ________.

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A

Of the bonds C-C, C Of the bonds C-C, C   C, and C≡C, the C-C bond is ________. C, and C≡C, the C-C bond is ________.

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C

Atoms surrounded by eight valence electrons tend to lose electrons.

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Based on the octet rule, magnesium most likely forms a ________ ion.

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The Lewis structure of AsH3 shows ________ nonbonding electron pair(s)on As.

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In ionic bond formation, the lattice energy of ions ________ as the magnitude of the ion charges _______ and the radii ________.

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The Lewis structure of HCN (H bonded toC)shows that ________ has ________ nonbonding electron pair(s).

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Which of the following does not have eight valence electrons?

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There are ________ valence electrons in the Lewis structure of CH3Cl.

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The strength of a covalent bond is measured by its ________.

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The bond length in an HI molecule is 1.61 Å and the measured dipole moment is 0.44 D. What is the magnitude (in units of e)of the negative charge on I in HI? (1 debye = 3.34 × 10-30 coulomb-meters; e = 1.6 × 10-19 coulombs)

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Benzene is a(n)________ compound with ________ equivalent Lewis structures.

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How many hydrogen atoms must bond to silicon to give it an octet of valence electrons?

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Give the electron configuration of Cu2+.

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The reaction below is used to produce methanol: CO (g) + 2H2 (g) → CH3OH (l)△Hrxn = -128 kJ (a) Calculate the C-H bond energy given the following data: The reaction below is used to produce methanol: CO (g) + 2H<sub>2</sub> (g) → CH<sub>3</sub>OH (l)△H<sub>rxn </sub>= -128 kJ (a) Calculate the C-H bond energy given the following data:   (b) The tabulated value of the (C-H)bond energy is 413 kJ/mol. Explain why there is a difference between the number you have calculated in (a)and the tabulated value. (b) The tabulated value of the (C-H)bond energy is 413 kJ/mol. Explain why there is a difference between the number you have calculated in (a)and the tabulated value.

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The Lewis structure of PF3 shows that the central phosphorus atom has ________ nonbonding and ________ bonding electron pair(s).

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A valid Lewis structure of ________ cannot be drawn without violating the octet rule.

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Using the table of bond dissociation energies, the ΔH for the following reaction is ________ kJ. 2HCl (g) + F2 (g) → 2HF (g) + Cl2 (g) Using the table of bond dissociation energies, the ΔH for the following reaction is ________ kJ. 2HCl (g) + F<sub>2</sub> (g) → 2HF (g) + Cl<sub>2</sub> (g)

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What is the maximum number of double bonds that a carbon atom can form?

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