Exam 18: Electrochemistry

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Consider an electrochemical cell constructed from the following half cells, linked by a KCl salt bridge. - a Fe electrode in 1.0 M FeCl2 solution - a Sn electrode in 1.0 M Sn(NO3)2 solution When the cell is running spontaneously, which choice includes only true statements and no false ones?

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Consider a voltaic cell based on the following cell reaction: Ni(s)+ At2(s) →\rarr Ni2+(aq)+ 2At- (aq) Given that the standard cell emf is 0.55 V, what is the standard reduction potential for astatine? [E°(Ni2+/Ni)= -0.25 V]

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Which one of the following reagents is capable of oxidizing Cu(s)to Cu2+ (1 M)?

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Consider the following standard reduction potentials in acid solution: Consider the following standard reduction potentials in acid solution:   The strongest oxidizing agent among those shown above is The strongest oxidizing agent among those shown above is

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Complete and balance the following redox reaction under basic conditions: CrO42-(aq)+ SO32-(aq) →\rarr Cr(OH)3(s)+ SO42-(aq)

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Consider the reaction Pb(s)+ 2H+(aq) →\rarr Pb2+(aq)+ H2(g).If the hydrogen gas pressure is maintained at 1.00 atm and the lead(II)ion concentration is 0.025 M, find the pH at which this reaction is at equilibrium.

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What is the total number of moles (n)of electrons exchanged between the oxidizing agent and the reducing agent in the overall redox equation: 5Fe2+(aq)+ MnO4-(aq)+ 8H+(aq) →\rarr 5Fe3+(aq)+ Mn2+(aq)+ 4H2O(l)

(Short Answer)
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For the electrochemical cell, Fe(s)| Fe2+(aq)|| Cu2+(aq)| Cu+(aq)| Pt(s), determine the equilibrium constant (Keq)at 25°C for the reaction that occurs.

(Multiple Choice)
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Calculate E°cell for the following electrochemical cell: Mn(s)| Mn2+(aq)|| Ce4+(aq),Ce3+(aq)| Pt(s)

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The measured voltage of a cell in which the following reaction occurs is 0.96 V: H2(g, 1.0 atm)+ 2Ag+(aq, 1.0 M) →\rarr 2H+(aq, pH = ?)+ 2Ag(s) Calculate the pH of the H+(aq)solution.

(Multiple Choice)
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For the electrochemical cell, Cd(s)| Cd2+(aq)|| Co2+(aq)| Co(s), determine the equilibrium constant (Keq)at 25°C for the reaction that occurs.

(Multiple Choice)
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Calculate the cell emf for the following reaction at 25°C: 2Ag+(0.010 M)+ H2(1 atm) →\rarr 2Ag(s)+ 2H+(pH = 6.0)

(Short Answer)
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Predict the products of the electrolysis of aqueous aluminum bromide AlBr3(aq).(Balancing is not required.)

(Multiple Choice)
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Consider the reaction 2Fe3+(aq)+ Fe(s) Consider the reaction 2Fe<sup>3+</sup>(aq)+ Fe(s)   <sub> </sub> 3Fe<sup>2+</sup>(aq).Find the equilibrium constant for this reaction at 25°C. 3Fe2+(aq).Find the equilibrium constant for this reaction at 25°C.

(Multiple Choice)
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Complete and balance the following redox equation.What is the coefficient of H2O when the equation is balanced using the set of smallest whole-number coefficients? MnO4- + SO32- →\rarr Mn2+ + SO42- (acidic solution)

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Iron objects such as storage tanks and underground pipelines can be protected from corrosion by connecting them through a wire to a piece of

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Under standard-state conditions, which of the following half-reactions occurs at the cathode during the electrolysis of aqueous nickel sulfate at 25°C?

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How many minutes would be required to electroplate 25.0 grams of chromium by passing a constant current of 4.80 amperes through a solution containing CrCl3?

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A galvanic cell has the overall reaction: Zn(s)+ 2Eu(NO3)3(aq) →\rarr Zn(NO3)2(aq)+ 2Eu(NO3)2(aq) Which is the half reaction occurring at the anode?

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How long will it take to produce 78 g of Al metal by the reduction of Al3+ in an electrolytic cell with a current of 2.0 A?

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