Exam 18: Electrochemistry

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Gold can be electrochemically "plated" onto a less expensive metal by submerging the object in a solution of gold(III)and applying an electric current to drive the following half-reaction: Au3+ + 3e- →\rarr Au(s) How many grams of gold will be formed if a current of 2.37 A is applied for 71 minutes?

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A current of 0.80 A was applied to an electrolytic cell containing molten CdCl2 for 2.5 hours.Calculate the mass of cadmium metal deposited.

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Which of these metals will be oxidized in hydrochloric acid under standard conditions at 25°C?

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Which of these metals will reduce water to hydrogen in basic solution under standard conditions?

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Aluminum does not corrode as does iron, because

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Calculate the cell emf for the following reaction at 25°C: 2Ag+(0.010 M)+ H2(1 atm) →\rarr 2Ag(s)+ 2H+(pH = 10.0)

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Complete and balance the following redox equation.What is the coefficient of OH- when the equation is balanced using the set of smallest whole-number coefficients? MnO4- + I- →\rarr MnO2 + IO3- (basic solution)

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Which of these metals will not be oxidized in hydrochloric acid under standard conditions at 25°C?

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Calculate E°cell for the following electrochemical cell: Ni(s)| Ni2+(aq)|| Hg22+(aq)| Hg(l)| Pt(s)

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Given the following standard reduction potentials, Given the following standard reduction potentials,   calculate the formation constant of Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup><sub> </sub>at 25°C. calculate the formation constant of Ag(NH3)2+ at 25°C.

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Calculate Δ\Delta G° for the electrochemical cell Fe(s)| Fe2+(aq)|| Sn4+(aq)| Sn2+(aq)| Pt(s)

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Consider an electrochemical cell involving the overall reaction 2AgBr(s)+ Pb(s) →\rarr Pb2+ + 2Ag(s)+ 2Br- Each half-reaction is carried out in a separate compartment.The anion included in the lead half-cell is NO3-.The cation in the silver half-cell is K+.The two half-cells are connected by a KNO3 salt bridge.If [Pb2+] = 1.0 M, what concentration of Br- ion will produce a cell emf of 0.25 V at 298 K? Given: AgBr(s)+ e- →\rarr Ag + Br-, E° = +0.07 V.

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Consider the following reaction: 2Fe2+(aq)+ Cu2+ →\rarr 2Fe3+(aq)+ Cu. When the reaction comes to equilibrium, what is the cell voltage?

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The measured voltage of the cell Pt(s)| H2 (1.0 atm)| H+(aq)|| Ag+(1.0 M)| Ag(s)is 1.02 V at 25°C.Calculate the pH of the solution.

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Write the formula of the strongest reducing agent.given the following standard reduction potentials in acid solution Write the formula of the strongest reducing agent.given the following standard reduction potentials in acid solution

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A current of 2.50 A was passed through an electrolytic cell containing molten CaCl2 for 4.50 hours.How many moles of calcium metal should be deposited?

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For the electrochemical cell Pt(s)| H2(1 atm)| H+(1 M)|| Cu2+(1 M)| Cu(s), which one of the following changes will cause an increase in the cell voltage?

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Which of the following is true concerning a galvanic cell?

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Using a table of standard electrode potentials, decide which of the following statements is completely true.

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Consider an electrochemical cell based on the following cell diagram: Pt | Pu3+(aq), Pu4+(aq)|| Cl2(g), Cl- (aq)| Pt Given that the standard cell emf is 0.35 V and that the standard reduction potential of chlorine is 1.36 V, what is the standard reduction potential E°(Pu4+/Pu3+)?

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