Exam 13: Structure Determination

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Instructions: Answer the following question(s) for the compound whose 1H NMR spectra is shown below. C4H8O Instructions: Answer the following question(s) for the compound whose <sup>1</sup>H NMR spectra is shown below. C<sub>4</sub>H<sub>8</sub>O   (Spectrum obtained from: SDBSWeb: http://www.aist.go.jp/RIODB/SDBS/) -Refer to instructions. Describe each signal in terms of its integration, splitting and chemical shift. (Spectrum obtained from: SDBSWeb: http://www.aist.go.jp/RIODB/SDBS/) -Refer to instructions. Describe each signal in terms of its integration, splitting and chemical shift.

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A 3.42 *10-5 M solution of dibenzalacetone in ethanol produced an absorbance of 0.753 in a 1.00 cm cell. Based on this data, what is ε\varepsilon for this compound?

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Instructions: Predict the splitting patterns you would expect for each proton in the molecules below: -Predict: Instructions: Predict the splitting patterns you would expect for each proton in the molecules below: -Predict:

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What are the units for electromagnetic radiation used in infrared spectroscopy?

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A compound with the molecular formula C5H12O produces only two singlets in the 1H NMR spectrum. a)Propose a structure for this compound. b)How many signals would be present in the 13C NMR for this structure?

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