Exam 17: The Organic Chemistry of Metabolic Pathways

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The reaction of fructose 1,6-bisphosphate to give glyceraldehyde-3-phosphate and dihydroxyacetone phosphate is an example of

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A

Which group of small molecules best fit the boxes associated with the reaction shown? Which group of small molecules best fit the boxes associated with the reaction shown?

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D

Consider the following reaction. Consider the following reaction.   Which of the following describes this reaction? Which of the following describes this reaction?

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C

Which group of small molecules best fit the boxes associated with the reaction shown? Which group of small molecules best fit the boxes associated with the reaction shown?

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Which group of small molecules best fit the boxes associated with the reaction shown? Which group of small molecules best fit the boxes associated with the reaction shown?

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Instructions: Consider the reaction below to answer the following questions: Instructions:  Consider the reaction below to answer the following questions:   -Refer to instructions. This reaction is an example of: -Refer to instructions. This reaction is an example of:

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Which enzyme catalyzes the reaction shown? Which enzyme catalyzes the reaction shown?

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What product would be obtained from enzymatic transamination of 3-hydroxy-2-ketopropanoic acid? What product would be obtained from enzymatic transamination of 3-hydroxy-2-ketopropanoic acid?

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Instructions: Match a term or structure from the list below to each of the following definitions or names. -Acetyl groups are oxidized to yield carbon dioxide and water.

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Many biological reactions are endergonic. Explain how it is possible that these reactions occur spontaneously.

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How many passages through the β\beta -oxidation pathway are required to completely degrade the following fatty acid? CH3(CH2)12CO2H

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Instructions: Match a term or structure from the list below to each of the following definitions or names. -The "energy currency" of the cell.

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When acetyl-CoA reacts with oxaloacetate to form citrate

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Instructions: Consider the reaction below to answer the following question(s). Instructions: Consider the reaction below to answer the following question(s).   -Refer to instructions. Write the mechanism for this isomerization. -Refer to instructions. Write the mechanism for this isomerization.

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The formation of amino acids from proteins

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All of the following are byproducts of β\beta -oxidation, except:

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Instructions: Match a term or structure from the list below to each of the following definitions or names. -Coenzyme NAD+ required in the β\beta -oxidation of fatty acids, glycolysis, and the citric acid cycle.

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Instructions: Consider the reaction below to answer the following question(s). Instructions: Consider the reaction below to answer the following question(s).   -Refer to instructions. This reaction proceeds through a common enol structure. Draw the structure of the glucose/fructose enol. -Refer to instructions. This reaction proceeds through a common enol structure. Draw the structure of the glucose/fructose enol.

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Draw the structure of the ultimate organic glycolysis product of α\alpha -glucose.  Draw the structure of the ultimate organic glycolysis product of  \alpha -glucose.

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Instructions: Consider the reaction below to answer the following question(s). Instructions: Consider the reaction below to answer the following question(s).   -Refer to instructions. The isomerization of glucose 6-phosphate to fructose 6-phosphate is an example of: -Refer to instructions. The isomerization of glucose 6-phosphate to fructose 6-phosphate is an example of:

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