Exam 5: Stereochemistry at Tetrahedral Centers

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Place asterisks at all the chirality centers in each molecule below. -The following atoms are commonly encountered in organic molecules. For which is it not possible to isolate enantiomers due to rapid inversion?

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Which of the following compounds is (are) achiral? A Which of the following compounds is (are) achiral? A   B   C   ​ B Which of the following compounds is (are) achiral? A   B   C   ​ C Which of the following compounds is (are) achiral? A   B   C   ​ ​

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If (+)-sucrose has a specific rotation of +66.47, what is the specific rotation of (−)-sucrose?

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Match each definition to a term from the list below. -Is an atom in a molecule that is bonded to four different atoms or groups of atoms.

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Match each definition to a term from the list below. -Are stereoisomers that are not mirror images.

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Which of the following have the S configuration? A Which of the following have the S configuration? A   B   C   ​ ​ B Which of the following have the S configuration? A   B   C   ​ ​ C Which of the following have the S configuration? A   B   C   ​ ​ ​ ​

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Match each definition to a term from the list below. -Are molecules which contain both chirality centers and a plane of symmetry.

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2.10 g of an unknown compound was dissolved in 15.00 mL of ethanol. The sample was placed in a 10.0 cm cell in a polarimeter and the angle of rotation was determined to be −18.48°. What is the specific rotation of this unknown and specify if the compound is levorotatory or dextrorotatory?

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Which of the following have the R configuration? A Which of the following have the R configuration? A   B   C   ​ B Which of the following have the R configuration? A   B   C   ​ C Which of the following have the R configuration? A   B   C   ​ ​

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Match each definition to a term from the list below. -Are designated either (±) or d,l.

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In the molecules below, assign R, S configurations to the chirality center indicated with an arrow. In the molecules below, assign R, S configurations to the chirality center indicated with an arrow.     norepinephrine alanine -Refer to instructions. The configuration of this carbon atom is _____. In the molecules below, assign R, S configurations to the chirality center indicated with an arrow.     norepinephrine alanine -Refer to instructions. The configuration of this carbon atom is _____. norepinephrine alanine -Refer to instructions. The configuration of this carbon atom is _____.

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Which of the following structures contain a plane of symmetry? A Which of the following structures contain a plane of symmetry? A   B   C   ​ B Which of the following structures contain a plane of symmetry? A   B   C   ​ C Which of the following structures contain a plane of symmetry? A   B   C   ​ ​

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Identify the indicated hydrogens in the following molecules as pro-R or pro-S. -Identify: Identify the indicated hydrogens in the following molecules as pro-R or pro-S. -Identify:   succinate succinate

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Which of the following is the definition of a meso compound?

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How many stereoisomers of 2,3-dimethylbutane exist? How many stereoisomers of 2,3-dimethylbutane exist?

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Which of the following is the definition of a pair of enantiomers?

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Place asterisks at all the chirality centers in each molecule below. -The numbers on the carbon center of the following molecule represent atomic numbers. Place asterisks at all the chirality centers in each molecule below. -The numbers on the carbon center of the following molecule represent atomic numbers.   The molecule is in The molecule is in

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Which of the following is the definition of a pair of diastereomers?

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Identify the indicated hydrogens in the following molecules as pro-R or pro-S. -Identify: Identify the indicated hydrogens in the following molecules as pro-R or pro-S. -Identify:   phenylpyruvate phenylpyruvate

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(−)-cholesterol

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