Exam 23: Biomolecules: Lipids and Their Metabolism

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Which of the following fatty acids has the highest melting point?

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Draw the product of the following reaction, which is involved in the catabolism of triacylglycerols. Draw the product of the following reaction, which is involved in the catabolism of triacylglycerols.

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Match each of the given terms to a structure from the list below. There is only one correct structure for each term, and structures may be used more than once. -Starting material for fatty acid biosynthesis.

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Draw the structure of glyceryl trimyristate and compare its melting point to that of glyceryl tristearate.

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The major lipid components of cell membranes are:

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Match each of the given terms to a structure from the list below. There is only one correct structure for each term, and structures may be used more than once. -Monoterpene precursor

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Chemically, these are triacylglycerols, triesters of glycerol with three long-chain carboxylic acids.

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Cell membranes, which form an effective barrier to the passage of ions and other components into and out of the cell, are:

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Write the saponification reaction of glyceryl distearate monooleate.

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Which of the following represents a similarity between the β-oxidation pathway and the biosynthesis of fatty acids?

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Which of the following fatty acids has the highest melting point?

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Indicate by asterisks the stereogenic centers present in each of the indicated terpenes in the following question(s). -Place asterisks: linalool Indicate by asterisks the stereogenic centers present in each of the indicated terpenes in the following question(s). -Place asterisks: linalool

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How many constitutional isomers could be written for glyceryl monolaurate monomyristate monosterate?

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Progesterone and progestin are examples of:

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Indicate by asterisks the stereogenic centers present in each of the indicated terpenes in the following question(s). -Place asterisks: lineatin Indicate by asterisks the stereogenic centers present in each of the indicated terpenes in the following question(s). -Place asterisks: lineatin

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Draw the structure of calcium oleate. Would this substance be soluble or insoluble in water?

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Indicate by asterisks the stereogenic centers present in each of the indicated terpenes in the following question(s). -Place asterisks: abietic acid Indicate by asterisks the stereogenic centers present in each of the indicated terpenes in the following question(s). -Place asterisks: abietic acid

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Which of the following is not true about cholesterol?

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Draw the structures of the major organic product(s) you would expect to obtain from reaction of androsterone with the reagents listed below. Draw the structures of the major organic product(s) you would expect to obtain from reaction of androsterone with the reagents listed below.   androsterone -Draw major product(s): NaBH<sub>4</sub>, ethanol androsterone -Draw major product(s): NaBH4, ethanol

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Draw the structure of the carbocation intermediate that results from the following step in terpene synthesis. Draw the structure of the carbocation intermediate that results from the following step in terpene synthesis.

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