Exam 17: Acid-Base Equilibria and Solubility Equilibria

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A 10.0-mL sample of 0.75 M CH3CH2COOH is titrated with 0.30 M NaOH.What is the pH of the solution after 22.0 mL of NaOH have been added to the acid? [Ka(CH3CH2COOH)= 1.3 × 10-5]

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What is the effect on the equilibrium when sodium formate is added to a solution of formic acid? HCOOH(aq) What is the effect on the equilibrium when sodium formate is added to a solution of formic acid? HCOOH(aq)   H<sup>+</sup>(aq)+ HCOO<sup>-</sup>(aq) H+(aq)+ HCOO-(aq)

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When a strong acid is titrated with a strong base,the pH at the equivalence point

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Which is the best acid to prepare a buffer with the lowest pH?

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If the pH of a buffer solution is greater than the pKa value of the buffer acid,the buffer will have more capacity to neutralize added base than added acid.

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A 50.0-mL sample of 0.50 M HCl is titrated with 0.50 M NaOH.What is the pH of the solution after 28.0 mL of NaOH have been added to the acid?

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The ____________________ is the point in a titration where the color of the indicator changes.

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Methyl red is a common acid-base indicator.It has a Ka equal to 6.3 × 10-6.Its un-ionized form is red and its anionic form is yellow.What color would a methyl red solution have at pH = 7.8?

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Calculate the solubility of zinc hydroxide,Zn(OH)2,in 1.00 M NaOH.Ksp = 3.0 × 10-16 for Zn(OH)2,Kf = 3.0 × 1015 for Zn(OH)42-

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Calculate the solubility of silver oxalate,Ag2C2 O4,in pure water. [Ksp(Ag2C2O4)= 1.0 × 10-11]

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Increasing the concentrations of the components of a buffer solution will increase the buffer range.

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Which of the following is correct for the equivalence point in an acid-base titration?

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Which of the following acids is the best acid to prepare a buffer with the highest pH?

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What is the pH of a solution prepared by mixing 500.mL of 0.10 M NaOCl and 500.mL of 0.20 M HOCl? [Ka(HOCl)= 3.2 × 10-8]

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When an acid,HA,is titrated with 0.1 M NaOH,the pH at the half equivalence point of the titration is 4.5.What is the Ka of the acid?

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Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III)fluoride.[Ksp(CrF3)= 6.6 × 10-11]

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Indicators are weak acids that are one color in acidic solution and another color in basic solution.

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What molar ratio of CH3COOH to CH3COONa should be used in order to prepare an acetic acid / sodium acetate buffer solution with a pH of 4.00 ± 0.02? [Ka(CH3COOH)= 1.8 × 10-5]

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Which will precipitate first when AgNO3 is added to a solution containing equal concentrations of Br-,Cl-, and I- ions?

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The molar solubility of tin(II)iodide is 1.28 × 10-2 mol/L.What is Ksp for this compound?

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