Exam 15: Chemical Equilibrium

arrow
  • Select Tags
search iconSearch Question
flashcardsStudy Flashcards
  • Select Tags

When the substances in the equation below are at equilibrium,at pressure,P,and temperature, T,the equilibrium can be shifted to favor the products by CuO(s)+ H2(g) When the substances in the equation below are at equilibrium,at pressure,P,and temperature, T,the equilibrium can be shifted to favor the products by CuO(s)+ H<sub>2</sub>(g)   H<sub>2</sub>O(g)+ Cu(s)ΔHº<sub>rxn</sub> = -2.0 kJ/mol H2O(g)+ Cu(s)ΔHºrxn = -2.0 kJ/mol

Free
(Multiple Choice)
4.7/5
(85)
Correct Answer:
Verified

C

Compounds A,B,and C react according to the following equation. 3A(g)+ 2B(g) Compounds A,B,and C react according to the following equation. 3A(g)+ 2B(g)   2C(g) At 100°C a mixture of these gases at equilibrium showed that [A] = 0.855 M,[B] = 1.23 M,and [C] = 1.75 M.What is the value of K<sub>c</sub> for this reaction? 2C(g) At 100°C a mixture of these gases at equilibrium showed that [A] = 0.855 M,[B] = 1.23 M,and [C] = 1.75 M.What is the value of Kc for this reaction?

Free
(Multiple Choice)
4.8/5
(88)
Correct Answer:
Verified

E

a.State Le Châtelier's principle. b.The following reaction is at equilibrium in a closed container: 2Fe(OH)3(s) a.State Le Châtelier's principle. b.The following reaction is at equilibrium in a closed container: 2Fe(OH)<sub>3</sub>(s)   Fe<sub>2</sub>O<sub>3</sub>(s)+ 3H<sub>2</sub>O(g); ΔH°<sub>rxn</sub> > 0 What effects,if any,will the following actions have on the position of equilibrium? In each case, state the direction of any shift in equilibrium,and give your reasons in one sentence. (i)adding more Fe(OH)<sub>3</sub> (ii)raising the temperature (iii)adding a more water vapor a.If a stress is applied to a system at equilibrium,the equilibrium position shifts so as to reduce that stress. Fe2O3(s)+ 3H2O(g); ΔH°rxn > 0 What effects,if any,will the following actions have on the position of equilibrium? In each case, state the direction of any shift in equilibrium,and give your reasons in one sentence. (i)adding more Fe(OH)3 (ii)raising the temperature (iii)adding a more water vapor a.If a stress is applied to a system at equilibrium,the equilibrium position shifts so as to reduce that stress.

Free
(Essay)
4.9/5
(86)
Correct Answer:
Verified

b.(i)No effect.Pure solids and liquids have constant concentration,regardless of total amount.(ii)The equilibrium will move in the endothermic direction,i.e.,more products will form.(iii)The equilibrium will move to the left,i.e.,more reactant will form.

Phosgene,COCl2,a poisonous gas,decomposes as follows. COCl2(g) Phosgene,COCl<sub>2</sub>,a poisonous gas,decomposes as follows. COCl<sub>2</sub>(g)   CO(g)+ Cl<sub>2</sub>(g). At 900.ºC,K<sub>c</sub> = 0.083.What is KP at this temperature? (R = 0.08206 L • atm/K • mol) CO(g)+ Cl2(g). At 900.ºC,Kc = 0.083.What is KP at this temperature? (R = 0.08206 L • atm/K • mol)

(Multiple Choice)
5.0/5
(79)

What is the expression for KP for the following reaction? A(g) What is the expression for K<sub>P</sub> for the following reaction? A(g)   B(g)+ 2C(g) B(g)+ 2C(g)

(Multiple Choice)
4.8/5
(81)

At 400ºC,Kc = 64 for the equilibrium H2(g)+ I2(g) At 400ºC,K<sub>c</sub> = 64 for the equilibrium H<sub>2</sub>(g)+ I<sub>2</sub>(g)   2HI(g).If 3.00 mol H<sub>2</sub> and 3.00 mol I<sub>2</sub> are introduced into an empty 4.0-L vessel,what is the equilibrium concentration of HI at 400ºC? 2HI(g).If 3.00 mol H2 and 3.00 mol I2 are introduced into an empty 4.0-L vessel,what is the equilibrium concentration of HI at 400ºC?

(Multiple Choice)
4.9/5
(94)

Consider the equilibrium equation C(s)+ O2(g)

(Essay)
4.9/5
(80)

Ammonium iodide dissociates reversibly to ammonia and hydrogen iodide. NH4I(s) Ammonium iodide dissociates reversibly to ammonia and hydrogen iodide. NH<sub>4</sub>I(s)   NH<sub>3</sub>(g)+ HI(g) At 400°C,K<sub>P</sub> = 0.215.Calculate the partial pressure of ammonia at equilibrium when a sufficient quantity of ammonium iodide is heated to 400°C. NH3(g)+ HI(g) At 400°C,KP = 0.215.Calculate the partial pressure of ammonia at equilibrium when a sufficient quantity of ammonium iodide is heated to 400°C.

(Multiple Choice)
4.8/5
(82)

When a reaction system reaches equilibrium,the forward and reverse reactions stop.

(True/False)
4.8/5
(67)

For the reaction SO2(g)+ NO2(g) For the reaction SO<sub>2</sub>(g)+ NO<sub>2</sub>(g)   SO<sub>3</sub>(g)+ NO(g),the equilibrium constant K<sub>c</sub> is 18.0 at 1200ºC.If 1.0 mole of SO<sub>2</sub> and 2.0 moles of NO<sub>2</sub> are placed in a 20.0-L container,what concentration of SO<sub>3</sub> will be present at equilibrium? SO3(g)+ NO(g),the equilibrium constant Kc is 18.0 at 1200ºC.If 1.0 mole of SO2 and 2.0 moles of NO2 are placed in a 20.0-L container,what concentration of SO3 will be present at equilibrium?

(Multiple Choice)
4.9/5
(70)

What is used to explain the effect of a stress that has been applied to a system at equilibrium?

(Short Answer)
4.8/5
(75)

Which is the correct equilibrium constant expression for the following reaction? 2C6H6(g)+ 15O2(g) Which is the correct equilibrium constant expression for the following reaction? 2C<sub>6</sub>H<sub>6</sub>(g)+ 15O<sub>2</sub>(g)   12CO<sub>2</sub>(g)+ 6H<sub>2</sub>O(g) 12CO2(g)+ 6H2O(g)

(Multiple Choice)
4.7/5
(81)

The equilibrium constants (expressed in atm)for the chemical reaction N2(g)+ O2(g) The equilibrium constants (expressed in atm)for the chemical reaction N<sub>2</sub>(g)+ O<sub>2</sub>(g)   2NO(g)are K<sub>P</sub> = 1.1 × 10<sup>-3</sup> and 3.6 × 10<sup>-3</sup> at 2200 K and 2500 K,respectively. Which statement is true? 2NO(g)are KP = 1.1 × 10-3 and 3.6 × 10-3 at 2200 K and 2500 K,respectively. Which statement is true?

(Multiple Choice)
4.7/5
(78)

The equilibrium constant,Kc,for the reaction PCl3(g)+ Cl2(g) The equilibrium constant,K<sub>c</sub>,for the reaction PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)   PCl<sub>5</sub>(g)is 49 at 230°C. If 0.70 mol of PCl<sub>3</sub> is added to 0.70 mol of Cl<sub>2</sub> in a 1.00-L reaction vessel at 230°C,what is the concentration of PCl<sub>3</sub> when equilibrium has been established? PCl5(g)is 49 at 230°C. If 0.70 mol of PCl3 is added to 0.70 mol of Cl2 in a 1.00-L reaction vessel at 230°C,what is the concentration of PCl3 when equilibrium has been established?

(Multiple Choice)
4.7/5
(83)

If one starts with pure NO2(g)at a pressure of 0.500 atm,the total pressure inside the reaction vessel when 2NO2(g) If one starts with pure NO<sub>2</sub>(g)at a pressure of 0.500 atm,the total pressure inside the reaction vessel when 2NO<sub>2</sub>(g)   2NO(g)+ O<sub>2</sub>(g)reaches equilibrium is 0.674 atm. What is the equilibrium partial pressure of NO<sub>2</sub>? 2NO(g)+ O2(g)reaches equilibrium is 0.674 atm. What is the equilibrium partial pressure of NO2?

(Multiple Choice)
5.0/5
(74)

Suppose 15.00 g of solid ammonium hydrogen sulfide is introduced into a 500.-mL flask at 25°C,the flask is sealed,and the system is allowed to reach equilibrium.What is the partial pressure of ammonia in this flask if KP = 0.108 at 25°C for the following reaction? NH4HS(s) Suppose 15.00 g of solid ammonium hydrogen sulfide is introduced into a 500.-mL flask at 25°C,the flask is sealed,and the system is allowed to reach equilibrium.What is the partial pressure of ammonia in this flask if K<sub>P</sub> = 0.108 at 25°C for the following reaction? NH<sub>4</sub>HS(s)   NH<sub>3</sub>(g)+ H<sub>2</sub>S(g) NH3(g)+ H2S(g)

(Multiple Choice)
4.8/5
(69)

Which statement is correct?

(Multiple Choice)
4.7/5
(68)

For the endothermic reaction A2(g) For the endothermic reaction A<sub>2</sub>(g)   2A(g),a snapshot of an equilibrium mixture of A(g)and A<sub>2</sub>(g)may look as follows.(Each circle represents 1.0 mol of A atoms,and the volume of the box is 1.0 L.)   What is the equilibrium constant K<sub>P</sub> for this reaction at 298 K? (R = 0.08206 L • atm/K • mol) 2A(g),a snapshot of an equilibrium mixture of A(g)and A2(g)may look as follows.(Each circle represents 1.0 mol of A atoms,and the volume of the box is 1.0 L.) For the endothermic reaction A<sub>2</sub>(g)   2A(g),a snapshot of an equilibrium mixture of A(g)and A<sub>2</sub>(g)may look as follows.(Each circle represents 1.0 mol of A atoms,and the volume of the box is 1.0 L.)   What is the equilibrium constant K<sub>P</sub> for this reaction at 298 K? (R = 0.08206 L • atm/K • mol) What is the equilibrium constant KP for this reaction at 298 K? (R = 0.08206 L • atm/K • mol)

(Multiple Choice)
4.9/5
(83)

Which of the following statements is incorrect regarding equilibrium?

(Multiple Choice)
4.8/5
(66)

The reaction system POBr3(g) The reaction system POBr<sub>3</sub>(g)   POBr(g)+ Br<sub>2</sub>(g)is at equilibrium. Which of the following statements describes the behavior of the system if the partial pressure of bromine is reduced by 75% as equilibrium is established? POBr(g)+ Br2(g)is at equilibrium. Which of the following statements describes the behavior of the system if the partial pressure of bromine is reduced by 75% as equilibrium is established?

(Multiple Choice)
4.8/5
(84)
Showing 1 - 20 of 135
close modal

Filters

  • Essay(0)
  • Multiple Choice(0)
  • Short Answer(0)
  • True False(0)
  • Matching(0)