Exam 15: Chemical Equilibrium
Exam 1: Chemistry: the Central Science129 Questions
Exam 2: Atoms Molecules and Ions120 Questions
Exam 3: Stoichiometry Ratios of Combination131 Questions
Exam 4: Reactions in Aqueous Solutions144 Questions
Exam 5: Thermochemistry134 Questions
Exam 6: Quantum Theory and the Electronic Structure of Atoms107 Questions
Exam 7: Electron Configuration and the Periodic Table120 Questions
Exam 8: Chemical Bonding I Basic Concepts95 Questions
Exam 9: Chemical Bonding Ii Molecular Geometry and Bonding Theories137 Questions
Exam 10: Gases131 Questions
Exam 11: Intermolecular Forces and the Physical Properties of Liquids and Solids135 Questions
Exam 12: Modern Materials108 Questions
Exam 13: Physical Properties of Solutions147 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium135 Questions
Exam 16: Acids and Bases133 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria129 Questions
Exam 18: Entropy Free Energy and Equilibrium61 Questions
Exam 19: Electrochemistry122 Questions
Exam 20: Nuclear Chemistry125 Questions
Exam 21: Environmental Chemistry131 Questions
Exam 22: Coordination Chemistry128 Questions
Exam 23: Metallurgy and the Chemistry of Metals115 Questions
Exam 24: Nonmetallic Elements and Their Compounds119 Questions
Exam 25: Organic Chemistry148 Questions
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When the substances in the equation below are at equilibrium,at pressure,P,and temperature, T,the equilibrium can be shifted to favor the products by
CuO(s)+ H2(g)
H2O(g)+ Cu(s)ΔHºrxn = -2.0 kJ/mol
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(Multiple Choice)
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Correct Answer:
C
Compounds A,B,and C react according to the following equation. 3A(g)+ 2B(g)
2C(g)
At 100°C a mixture of these gases at equilibrium showed that [A] = 0.855 M,[B] = 1.23 M,and
[C] = 1.75 M.What is the value of Kc for this reaction?
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(Multiple Choice)
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Correct Answer:
E
a.State Le Châtelier's principle.
b.The following reaction is at equilibrium in a closed container:
2Fe(OH)3(s)
Fe2O3(s)+ 3H2O(g); ΔH°rxn > 0
What effects,if any,will the following actions have on the position of equilibrium? In each case,
state the direction of any shift in equilibrium,and give your reasons in one sentence.
(i)adding more Fe(OH)3
(ii)raising the temperature
(iii)adding a more water vapor a.If a stress is applied to a system at equilibrium,the equilibrium position shifts so as to reduce that stress.
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Correct Answer:
b.(i)No effect.Pure solids and liquids have constant concentration,regardless of total amount.(ii)The equilibrium will move in the endothermic direction,i.e.,more products will form.(iii)The equilibrium will move to the left,i.e.,more reactant will form.
Phosgene,COCl2,a poisonous gas,decomposes as follows. COCl2(g)
CO(g)+ Cl2(g).
At 900.ºC,Kc = 0.083.What is KP at this temperature? (R = 0.08206 L • atm/K • mol)
(Multiple Choice)
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What is the expression for KP for the following reaction? A(g)
B(g)+ 2C(g)
(Multiple Choice)
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At 400ºC,Kc = 64 for the equilibrium H2(g)+ I2(g)
2HI(g).If 3.00 mol H2 and 3.00 mol I2 are introduced into an empty 4.0-L vessel,what is the equilibrium concentration of HI at 400ºC?
(Multiple Choice)
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Ammonium iodide dissociates reversibly to ammonia and hydrogen iodide. NH4I(s)
NH3(g)+ HI(g)
At 400°C,KP = 0.215.Calculate the partial pressure of ammonia at equilibrium when a sufficient quantity of ammonium iodide is heated to 400°C.
(Multiple Choice)
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When a reaction system reaches equilibrium,the forward and reverse reactions stop.
(True/False)
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For the reaction SO2(g)+ NO2(g)
SO3(g)+ NO(g),the equilibrium constant Kc is 18.0 at 1200ºC.If 1.0 mole of SO2 and 2.0 moles of NO2 are placed in a 20.0-L container,what concentration of SO3 will be present at equilibrium?
(Multiple Choice)
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What is used to explain the effect of a stress that has been applied to a system at equilibrium?
(Short Answer)
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Which is the correct equilibrium constant expression for the following reaction? 2C6H6(g)+ 15O2(g)
12CO2(g)+ 6H2O(g)
(Multiple Choice)
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The equilibrium constants (expressed in atm)for the chemical reaction N2(g)+ O2(g)
2NO(g)are KP = 1.1 × 10-3 and 3.6 × 10-3 at 2200 K and 2500 K,respectively.
Which statement is true?
(Multiple Choice)
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The equilibrium constant,Kc,for the reaction PCl3(g)+ Cl2(g)
PCl5(g)is 49 at 230°C.
If 0.70 mol of PCl3 is added to 0.70 mol of Cl2 in a 1.00-L reaction vessel at 230°C,what is the concentration of PCl3 when equilibrium has been established?
(Multiple Choice)
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If one starts with pure NO2(g)at a pressure of 0.500 atm,the total pressure inside the reaction vessel when 2NO2(g)
2NO(g)+ O2(g)reaches equilibrium is 0.674 atm. What is the equilibrium partial pressure of NO2?
(Multiple Choice)
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Suppose 15.00 g of solid ammonium hydrogen sulfide is introduced into a 500.-mL flask at 25°C,the flask is sealed,and the system is allowed to reach equilibrium.What is the partial pressure of ammonia in this flask if KP = 0.108 at 25°C for the following reaction?
NH4HS(s)
NH3(g)+ H2S(g)
(Multiple Choice)
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For the endothermic reaction A2(g)
2A(g),a snapshot of an equilibrium mixture of A(g)and A2(g)may look as follows.(Each circle represents 1.0 mol of A atoms,and the volume of the box is 1.0 L.)
What is the equilibrium constant KP for this reaction at 298 K? (R = 0.08206 L • atm/K • mol)
(Multiple Choice)
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Which of the following statements is incorrect regarding equilibrium?
(Multiple Choice)
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The reaction system POBr3(g)
POBr(g)+ Br2(g)is at equilibrium. Which of the following statements describes the behavior of the system if the partial pressure of bromine is reduced by 75% as equilibrium is established?
(Multiple Choice)
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