Exam 15: Chemical Equilibrium
Exam 1: Chemistry: the Central Science129 Questions
Exam 2: Atoms Molecules and Ions120 Questions
Exam 3: Stoichiometry Ratios of Combination131 Questions
Exam 4: Reactions in Aqueous Solutions144 Questions
Exam 5: Thermochemistry134 Questions
Exam 6: Quantum Theory and the Electronic Structure of Atoms107 Questions
Exam 7: Electron Configuration and the Periodic Table120 Questions
Exam 8: Chemical Bonding I Basic Concepts95 Questions
Exam 9: Chemical Bonding Ii Molecular Geometry and Bonding Theories137 Questions
Exam 10: Gases131 Questions
Exam 11: Intermolecular Forces and the Physical Properties of Liquids and Solids135 Questions
Exam 12: Modern Materials108 Questions
Exam 13: Physical Properties of Solutions147 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium135 Questions
Exam 16: Acids and Bases133 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria129 Questions
Exam 18: Entropy Free Energy and Equilibrium61 Questions
Exam 19: Electrochemistry122 Questions
Exam 20: Nuclear Chemistry125 Questions
Exam 21: Environmental Chemistry131 Questions
Exam 22: Coordination Chemistry128 Questions
Exam 23: Metallurgy and the Chemistry of Metals115 Questions
Exam 24: Nonmetallic Elements and Their Compounds119 Questions
Exam 25: Organic Chemistry148 Questions
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For the reaction PCl3(g)+ Cl2(g)
PCl5(g)at a particular temperature,Kc = 32.4.Suppose a system at that temperature is prepared with [PCl5] = 0.50 M,[Cl2] = 0.4 M,and [PCl3] = 0.10M.Which of the following is correct?
(Multiple Choice)
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When a reaction reaches _________,the concentration of the reactants and products will no longer change.
(Short Answer)
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Hydrogen iodide decomposes according to the equation 2HI(g)
H2(g)+ I2(g),for which Kc = 0.0156 at 400ºC.Suppose 0.550 mol HI is injected into a 2.00-L reaction vessel at 400ºC.What is the concentration of HI at equilibrium?
(Multiple Choice)
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In which of these gas-phase equilibria is the yield of products increased by increasing the total pressure on the reaction mixture?
(Multiple Choice)
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Hydrogen peroxide (H2O2)decomposes according to the following equation. H2O2(l)→ H2O(l)+ ½O2(g).
What is KP for this reaction at 25°C? (ΔH° = -98.2 kJ/mol,ΔS° = 70.1 J/K • mol,R = 8.314 J/K• mol)
(Multiple Choice)
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The reaction system POBr3(g)
POBr(g)+ Br2(g)is at equilibrium.Which of the following statements describes the behavior of the system if POBr is added to the container?
(Multiple Choice)
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What is defined as a fraction with product concentrations in the numerator and reactant concentrations in the denominator and with each concentration raised to a power equal to the corresponding stoichiometric coefficient in the balanced chemical equation?
(Multiple Choice)
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Changing the amount of reactant or product in an equilibrium reaction will always change the equilibrium position,regardless of the physical state of the substance involved.
(True/False)
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Hydrogen iodide decomposes according to the equation 2HI(g)
H2(g)+ I2(g),for which Kc = 0.0156 at 400ºC.Suppose 0.550 mol HI was injected into a 2.00-L reaction vessel at 400ºC.What is the concentration of H2 at equilibrium?
(Multiple Choice)
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In the gas phase,methyl isonitrile (CH3NC)isomerizes to acetonitrile (CH3CN), H3C-N≡C(g)
H3C-C≡N(g)with ΔH° = -89.5 kJ/mol and ΔG° = - 73.8 kJ/mol at 25°C.Find the equilibrium constant for this reaction at 100°C.
(Multiple Choice)
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At elevated temperatures,hydrogen iodide may decompose to form hydrogen gas and iodine gas,as follows. 2HI(g)
H2(g)+ I2(g)
In a particular experiment,the concentrations at equilibrium were measured to be [HI] = 0.85
Mol/L,[I2] = 0.60 mol/L,and [H2] = 0.27 mol/L.What is Kc for the above reaction?
(Multiple Choice)
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For the reaction H2(g)+ Br2(g)
2HBr(g),Kc = 81.4 at 385ºC.If [H2] = [Br2] = [HBr] = 2.4 × 10-4M at 385ºC,which one of the following is correct?
(Multiple Choice)
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When the following reaction is at equilibrium,which relationship is always true? 2NOCl(g)
2NO(g)+ Cl2(g)
(Multiple Choice)
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Nitric oxide is formed in automobile exhaust when nitrogen and oxygen in air react at high temperatures. N2(g)+ O2(g)
2NO(g)
The equilibrium constant KP for the reaction is 0.0025 at 2127°C.If a container is charged with
8)00 atm of nitrogen and 5.00 atm of oxygen and the mixture is allowed to reach equilibrium,
What will be the equilibrium partial pressure of nitrogen?
(Multiple Choice)
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At 500°C the equilibrium constant,KP ,is 4.00 ×10-4 for the equilibrium: 2HCN(g)
H2(g)+ C2N2(g)
What is Kp for the following reaction?
H2(g)+ C2 N2(g)
2HCN(g)
(Multiple Choice)
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Nitrosyl chloride (NOCl)decomposes at elevated temperatures according to the equation 2NOCl(g)
2NO(g)+ Cl2(g).What is KP for this reaction at 227°C?
For this reaction ΔH° = 81.2 kJ/mol and ΔS° = 128 J/K • mol.(R = 8.314 J/K • mol)
(Multiple Choice)
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The following reactions occur at 500 K.Arrange them in order of increasing tendency to proceed to completion (least completion → greatest completion). 1 2NOCl
2NO + Cl2 KP = 1.7 × 10- 2
2 N2O4
2NO2 KP = 1.5 × 103
3 2SO3
2SO2 + O2 KP = 1.3 × 10 -5
4 2NO2
2NO + O2 KP = 5.9 × 10 -5
(Multiple Choice)
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