Exam 15: Chemical Equilibrium

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For the reaction PCl3(g)+ Cl2(g) For the reaction PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)   PCl<sub>5</sub>(g)at a particular temperature,K<sub>c</sub> = 32.4.Suppose a system at that temperature is prepared with [PCl<sub>5</sub>] = 0.50 M,[Cl<sub>2</sub>] = 0.4 M,and [PCl<sub>3</sub>] = 0.10M.Which of the following is correct? PCl5(g)at a particular temperature,Kc = 32.4.Suppose a system at that temperature is prepared with [PCl5] = 0.50 M,[Cl2] = 0.4 M,and [PCl3] = 0.10M.Which of the following is correct?

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When a reaction reaches _________,the concentration of the reactants and products will no longer change.

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Hydrogen iodide decomposes according to the equation 2HI(g) Hydrogen iodide decomposes according to the equation 2HI(g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g),for which K<sub>c</sub> = 0.0156 at 400ºC.Suppose 0.550 mol HI is injected into a 2.00-L reaction vessel at 400ºC.What is the concentration of HI at equilibrium? H2(g)+ I2(g),for which Kc = 0.0156 at 400ºC.Suppose 0.550 mol HI is injected into a 2.00-L reaction vessel at 400ºC.What is the concentration of HI at equilibrium?

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In which of these gas-phase equilibria is the yield of products increased by increasing the total pressure on the reaction mixture?

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Hydrogen peroxide (H2O2)decomposes according to the following equation. H2O2(l)→ H2O(l)+ ½O2(g). What is KP for this reaction at 25°C? (ΔH° = -98.2 kJ/mol,ΔS° = 70.1 J/K • mol,R = 8.314 J/K• mol)

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The reaction system POBr3(g) The reaction system POBr<sub>3</sub>(g)   POBr(g)+ Br<sub>2</sub>(g)is at equilibrium.Which of the following statements describes the behavior of the system if POBr is added to the container? POBr(g)+ Br2(g)is at equilibrium.Which of the following statements describes the behavior of the system if POBr is added to the container?

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What is defined as a fraction with product concentrations in the numerator and reactant concentrations in the denominator and with each concentration raised to a power equal to the corresponding stoichiometric coefficient in the balanced chemical equation?

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Changing the amount of reactant or product in an equilibrium reaction will always change the equilibrium position,regardless of the physical state of the substance involved.

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Hydrogen iodide decomposes according to the equation 2HI(g) Hydrogen iodide decomposes according to the equation 2HI(g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g),for which K<sub>c</sub> = 0.0156 at 400ºC.Suppose 0.550 mol HI was injected into a 2.00-L reaction vessel at 400ºC.What is the concentration of H<sub>2</sub> at equilibrium? H2(g)+ I2(g),for which Kc = 0.0156 at 400ºC.Suppose 0.550 mol HI was injected into a 2.00-L reaction vessel at 400ºC.What is the concentration of H2 at equilibrium?

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In the gas phase,methyl isonitrile (CH3NC)isomerizes to acetonitrile (CH3CN), H3C-N≡C(g) In the gas phase,methyl isonitrile (CH<sub>3</sub>NC)isomerizes to acetonitrile (CH<sub>3</sub>CN), H<sub>3</sub>C-N≡C(g)   H<sub>3</sub>C-C≡N(g)with ΔH° = -89.5 kJ/mol and ΔG° = - 73.8 kJ/mol at 25°C.Find the equilibrium constant for this reaction at 100°C. H3C-C≡N(g)with ΔH° = -89.5 kJ/mol and ΔG° = - 73.8 kJ/mol at 25°C.Find the equilibrium constant for this reaction at 100°C.

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There are guidelines to help write equilibrium constants.

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At elevated temperatures,hydrogen iodide may decompose to form hydrogen gas and iodine gas,as follows. 2HI(g) At elevated temperatures,hydrogen iodide may decompose to form hydrogen gas and iodine gas,as follows. 2HI(g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g) In a particular experiment,the concentrations at equilibrium were measured to be [HI] = 0.85 Mol/L,[I<sub>2</sub>] = 0.60 mol/L,and [H<sub>2</sub>] = 0.27 mol/L.What is K<sub>c</sub> for the above reaction? H2(g)+ I2(g) In a particular experiment,the concentrations at equilibrium were measured to be [HI] = 0.85 Mol/L,[I2] = 0.60 mol/L,and [H2] = 0.27 mol/L.What is Kc for the above reaction?

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For the reaction H2(g)+ Br2(g) For the reaction H<sub>2</sub>(g)+ Br<sub>2</sub>(g)   2HBr(g),K<sub>c</sub> = 81.4 at 385ºC.If [H<sub>2</sub>] = [Br<sub>2</sub>] = [HBr] = 2.4 × 10<sup>-4</sup>M at 385ºC,which one of the following is correct? 2HBr(g),Kc = 81.4 at 385ºC.If [H2] = [Br2] = [HBr] = 2.4 × 10-4M at 385ºC,which one of the following is correct?

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When the following reaction is at equilibrium,which relationship is always true? 2NOCl(g) When the following reaction is at equilibrium,which relationship is always true? 2NOCl(g)   2NO(g)+ Cl<sub>2</sub>(g) 2NO(g)+ Cl2(g)

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Nitric oxide is formed in automobile exhaust when nitrogen and oxygen in air react at high temperatures. N2(g)+ O2(g) Nitric oxide is formed in automobile exhaust when nitrogen and oxygen in air react at high temperatures. N<sub>2</sub>(g)+ O<sub>2</sub>(g)   2NO(g) The equilibrium constant K<sub>P</sub> for the reaction is 0.0025 at 2127°C.If a container is charged with 8)00 atm of nitrogen and 5.00 atm of oxygen and the mixture is allowed to reach equilibrium, What will be the equilibrium partial pressure of nitrogen? 2NO(g) The equilibrium constant KP for the reaction is 0.0025 at 2127°C.If a container is charged with 8)00 atm of nitrogen and 5.00 atm of oxygen and the mixture is allowed to reach equilibrium, What will be the equilibrium partial pressure of nitrogen?

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At 500°C the equilibrium constant,KP ,is 4.00 ×10-4 for the equilibrium: 2HCN(g) At 500°C the equilibrium constant,K<sub>P</sub> ,is 4.00 ×10<sup>-4</sup> for the equilibrium: 2HCN(g)   H<sub>2</sub>(g)+ C<sub>2</sub>N<sub>2</sub>(g) What is K<sub>p</sub> for the following reaction? H<sub>2</sub>(g)+ C<sub>2</sub> N<sub>2</sub>(g)   2HCN(g) H2(g)+ C2N2(g) What is Kp for the following reaction? H2(g)+ C2 N2(g) At 500°C the equilibrium constant,K<sub>P</sub> ,is 4.00 ×10<sup>-4</sup> for the equilibrium: 2HCN(g)   H<sub>2</sub>(g)+ C<sub>2</sub>N<sub>2</sub>(g) What is K<sub>p</sub> for the following reaction? H<sub>2</sub>(g)+ C<sub>2</sub> N<sub>2</sub>(g)   2HCN(g) 2HCN(g)

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Nitrosyl chloride (NOCl)decomposes at elevated temperatures according to the equation 2NOCl(g) Nitrosyl chloride (NOCl)decomposes at elevated temperatures according to the equation 2NOCl(g)   2NO(g)+ Cl<sub>2</sub>(g).What is K<sub>P</sub> for this reaction at 227°C? For this reaction ΔH° = 81.2 kJ/mol and ΔS° = 128 J/K • mol.(R = 8.314 J/K • mol) 2NO(g)+ Cl2(g).What is KP for this reaction at 227°C? For this reaction ΔH° = 81.2 kJ/mol and ΔS° = 128 J/K • mol.(R = 8.314 J/K • mol)

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The following reactions occur at 500 K.Arrange them in order of increasing tendency to proceed to completion (least completion → greatest completion). 1 2NOCl The following reactions occur at 500 K.Arrange them in order of increasing tendency to proceed to completion (least completion → greatest completion). 1 2NOCl   2NO + Cl<sub>2</sub> K<sub>P</sub> = 1.7 × 10<sup>- 2</sup> 2 N2O<sub>4</sub>   2NO<sub>2</sub> K<sub>P</sub> = 1.5 × 10<sup>3</sup> 3 2SO<sub>3</sub>   2SO<sub>2</sub> + O<sub>2</sub> K<sub>P</sub> = 1.3 × 10<sup> -5</sup> 4 2NO<sub>2</sub>   2NO + O<sub>2</sub> K<sub>P</sub> = 5.9 × 10<sup> -5</sup> 2NO + Cl2 KP = 1.7 × 10- 2 2 N2O4 The following reactions occur at 500 K.Arrange them in order of increasing tendency to proceed to completion (least completion → greatest completion). 1 2NOCl   2NO + Cl<sub>2</sub> K<sub>P</sub> = 1.7 × 10<sup>- 2</sup> 2 N2O<sub>4</sub>   2NO<sub>2</sub> K<sub>P</sub> = 1.5 × 10<sup>3</sup> 3 2SO<sub>3</sub>   2SO<sub>2</sub> + O<sub>2</sub> K<sub>P</sub> = 1.3 × 10<sup> -5</sup> 4 2NO<sub>2</sub>   2NO + O<sub>2</sub> K<sub>P</sub> = 5.9 × 10<sup> -5</sup> 2NO2 KP = 1.5 × 103 3 2SO3 The following reactions occur at 500 K.Arrange them in order of increasing tendency to proceed to completion (least completion → greatest completion). 1 2NOCl   2NO + Cl<sub>2</sub> K<sub>P</sub> = 1.7 × 10<sup>- 2</sup> 2 N2O<sub>4</sub>   2NO<sub>2</sub> K<sub>P</sub> = 1.5 × 10<sup>3</sup> 3 2SO<sub>3</sub>   2SO<sub>2</sub> + O<sub>2</sub> K<sub>P</sub> = 1.3 × 10<sup> -5</sup> 4 2NO<sub>2</sub>   2NO + O<sub>2</sub> K<sub>P</sub> = 5.9 × 10<sup> -5</sup> 2SO2 + O2 KP = 1.3 × 10 -5 4 2NO2 The following reactions occur at 500 K.Arrange them in order of increasing tendency to proceed to completion (least completion → greatest completion). 1 2NOCl   2NO + Cl<sub>2</sub> K<sub>P</sub> = 1.7 × 10<sup>- 2</sup> 2 N2O<sub>4</sub>   2NO<sub>2</sub> K<sub>P</sub> = 1.5 × 10<sup>3</sup> 3 2SO<sub>3</sub>   2SO<sub>2</sub> + O<sub>2</sub> K<sub>P</sub> = 1.3 × 10<sup> -5</sup> 4 2NO<sub>2</sub>   2NO + O<sub>2</sub> K<sub>P</sub> = 5.9 × 10<sup> -5</sup> 2NO + O2 KP = 5.9 × 10 -5

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Which equation is correct?

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For _______-________ reactions KP = Kc (RT)Δn gas.

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