Exam 15: Chemical Equilibrium

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Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl4(g)+ ½O2(g) Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl<sub>4</sub>(g)+ ½O<sub>2</sub>(g)   COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g),K<sub>c</sub> = 4.4 × 10<sup>9</sup> at 1000 K What is K<sub>c</sub> for the following reaction? 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g) COCl2(g)+ Cl2(g),Kc = 4.4 × 109 at 1000 K What is Kc for the following reaction? 2CCl4(g)+ O2(g) Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl<sub>4</sub>(g)+ ½O<sub>2</sub>(g)   COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g),K<sub>c</sub> = 4.4 × 10<sup>9</sup> at 1000 K What is K<sub>c</sub> for the following reaction? 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g) 2COCl2(g)+ 2Cl2(g)

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Consider the following equilibria: 2SO3(g) Consider the following equilibria: 2SO<sub>3</sub>(g)   2SO<sub>2</sub>(g)+ O<sub>2</sub>(g)K<sub>c</sub> = 2.3 × 10<sup>-7</sup> 2NO<sub>3</sub>(g)   2NO<sub>2</sub>(g)+ O<sub>2</sub>(g)K<sub>c</sub> = 1.4 × 10<sup>-3</sup> Calculate the equilibrium constant for the reaction SO<sub>2</sub>(g)+ NO<sub>3</sub>(g)   SO<sub>3</sub>(g)+ NO<sub>2</sub>(g). 2SO2(g)+ O2(g)Kc = 2.3 × 10-7 2NO3(g) Consider the following equilibria: 2SO<sub>3</sub>(g)   2SO<sub>2</sub>(g)+ O<sub>2</sub>(g)K<sub>c</sub> = 2.3 × 10<sup>-7</sup> 2NO<sub>3</sub>(g)   2NO<sub>2</sub>(g)+ O<sub>2</sub>(g)K<sub>c</sub> = 1.4 × 10<sup>-3</sup> Calculate the equilibrium constant for the reaction SO<sub>2</sub>(g)+ NO<sub>3</sub>(g)   SO<sub>3</sub>(g)+ NO<sub>2</sub>(g). 2NO2(g)+ O2(g)Kc = 1.4 × 10-3 Calculate the equilibrium constant for the reaction SO2(g)+ NO3(g) Consider the following equilibria: 2SO<sub>3</sub>(g)   2SO<sub>2</sub>(g)+ O<sub>2</sub>(g)K<sub>c</sub> = 2.3 × 10<sup>-7</sup> 2NO<sub>3</sub>(g)   2NO<sub>2</sub>(g)+ O<sub>2</sub>(g)K<sub>c</sub> = 1.4 × 10<sup>-3</sup> Calculate the equilibrium constant for the reaction SO<sub>2</sub>(g)+ NO<sub>3</sub>(g)   SO<sub>3</sub>(g)+ NO<sub>2</sub>(g). SO3(g)+ NO2(g).

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For the common allotropes of carbon (graphite and diamond),C(gr) For the common allotropes of carbon (graphite and diamond),C(gr)   C(dia)with equilibrium constant K = 0.32.The molar volumes of graphite and diamond are,respectively, 5.30 cm<sup>3</sup>/mol and 3.42 cm<sup>3</sup>/mol; ΔHf of diamond is 1.90 kJ/mol.These data suggest that the formation of diamond is favored at C(dia)with equilibrium constant K = 0.32.The molar volumes of graphite and diamond are,respectively, 5.30 cm3/mol and 3.42 cm3/mol; ΔHf of diamond is 1.90 kJ/mol.These data suggest that the formation of diamond is favored at

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A(n)________________ means that the products of the reaction can react to form reactants.

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The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N2(g)+ O2(g) The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N<sub>2</sub>(g)+ O<sub>2</sub>(g)   2NO(g) At 2000.°C,the equilibrium constant,K<sub>c</sub>,has a value of 4.10 × 10<sup>-4</sup>.What is the value of K<sub>P</sub>? (R = 0.08206 L • atm/K • mol) 2NO(g) At 2000.°C,the equilibrium constant,Kc,has a value of 4.10 × 10-4.What is the value of KP? (R = 0.08206 L • atm/K • mol)

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Calculate KP for the reaction 2NOCl(g) Calculate K<sub>P</sub> for the reaction 2NOCl(g)   2NO(g)+ Cl<sub>2</sub>(g)at 400.°C if K<sub>c</sub> at 400.°C for this reaction is 2.1 × 10<sup>-2</sup>.(R = 0.08206 L • atm/K • mol) 2NO(g)+ Cl2(g)at 400.°C if Kc at 400.°C for this reaction is 2.1 × 10-2.(R = 0.08206 L • atm/K • mol)

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The following reaction is at equilibrium in a sealed container. N2(g)+ 3H2(g) The following reaction is at equilibrium in a sealed container. N<sub>2</sub>(g)+ 3H<sub>2</sub>(g)   2NH<sub>3</sub>(g); ΔH°<sub>rxn</sub> < 0 Which,if any,of the following actions will increase the value of the equilibrium constant,K<sub>c</sub>? 2NH3(g); ΔH°rxn < 0 Which,if any,of the following actions will increase the value of the equilibrium constant,Kc?

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Which is correct?

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For the following reaction at equilibrium in a reaction vessel,which one of these changes would cause the I2 concentration to increase? 2NOI(g) For the following reaction at equilibrium in a reaction vessel,which one of these changes would cause the I<sub>2</sub> concentration to increase? 2NOI(g)   2NO(g)+ I<sub>2</sub>(g),ΔHº<sub>rxn</sub> = 45.3 kJ/mol 2NO(g)+ I2(g),ΔHºrxn = 45.3 kJ/mol

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Hydrogen peroxide may decompose to form water and oxygen gas according to the following reaction. 2H2O2(g) Hydrogen peroxide may decompose to form water and oxygen gas according to the following reaction. 2H<sub>2</sub>O<sub>2</sub>(g)   2H<sub>2</sub>O(g)+ O<sub>2</sub>(g) In a particular experiment,1.75 moles of H<sub>2</sub>O<sub>2</sub> were placed in a 2.5-L reaction chamber at 307ºC.After equilibrium was reached,1.20 moles of H<sub>2</sub>O<sub>2</sub> remained.What is K<sub>c</sub> for the reaction? 2H2O(g)+ O2(g) In a particular experiment,1.75 moles of H2O2 were placed in a 2.5-L reaction chamber at 307ºC.After equilibrium was reached,1.20 moles of H2O2 remained.What is Kc for the reaction?

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The equilibrium constant for the reaction Ni(s)+ 4CO(g) The equilibrium constant for the reaction Ni(s)+ 4CO(g)   Ni(CO)<sub>4</sub>(g)is 5.0× 10<sup>4</sup> at 25ºC. What is the equilibrium constant for the following reaction? Ni(CO)<sub>4</sub>(g)   Ni(s)+ 4CO(g)? Ni(CO)4(g)is 5.0× 104 at 25ºC. What is the equilibrium constant for the following reaction? Ni(CO)4(g) The equilibrium constant for the reaction Ni(s)+ 4CO(g)   Ni(CO)<sub>4</sub>(g)is 5.0× 10<sup>4</sup> at 25ºC. What is the equilibrium constant for the following reaction? Ni(CO)<sub>4</sub>(g)   Ni(s)+ 4CO(g)? Ni(s)+ 4CO(g)?

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During a chemical reaction,what defines when the concentrations of the reactants and products reach a constant level?

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What is the name for Qc?

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The reaction 2H2O2(g) The reaction 2H<sub>2</sub>O<sub>2</sub>(g)   2H<sub>2</sub>O(g)+ O<sub>2</sub>(g)is exothermic,ΔHº<sub>rxn</sub> = -210 kJ/mol.Which one of the following is correct? 2H2O(g)+ O2(g)is exothermic,ΔHºrxn = -210 kJ/mol.Which one of the following is correct?

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Which is the correct mass-action expression,Qc,for the following chemical reaction? Sn2+(aq)+ ½ O2(g)+ 3H2O(l) Which is the correct mass-action expression,Qc,for the following chemical reaction? Sn<sup>2+</sup>(aq)+ ½ O<sub>2</sub>(g)+ 3H<sub>2</sub>O(l)   SnO<sub>2</sub>(s)+ 2H<sub>3</sub>O<sup>+</sup>(aq) SnO2(s)+ 2H3O+(aq)

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For the following reaction at 25ºC,is 3 × 1024. 2SO2(g)+ O2(g) For the following reaction at 25ºC,is 3 × 10<sup>24</sup>. 2SO<sub>2</sub>(g)+ O<sub>2</sub>(g)   2SO<sub>3</sub>(g) What is K<sub>c</sub> at this temperature? (R = 0.08206 L • atm/K • mol) 2SO3(g) What is Kc at this temperature? (R = 0.08206 L • atm/K • mol)

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Consider this reaction at equilibrium: 2H2O2(g) Consider this reaction at equilibrium: 2H<sub>2</sub>O<sub>2</sub>(g)   2H<sub>2</sub>O(g)+ O<sub>2</sub>(g),ΔHº<sub>rxn</sub> = -210 kJ/mol If the volume of the system is expanded at constant temperature,what change will occur in the position of the equilibrium? 2H2O(g)+ O2(g),ΔHºrxn = -210 kJ/mol If the volume of the system is expanded at constant temperature,what change will occur in the position of the equilibrium?

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Consider the equilibrium: A(s) Consider the equilibrium: A(s)   B(s)+ C(g); ΔH°<sub>rxn</sub> > 0 Predict and explain how or whether the following actions would affect this equilibrium. a.adding more solid A b.lowering the temperature c.increasing the pressure on the system by reducing its volume d.adding helium gas to increase the total pressure a.No effect.Pure solids and liquids have constant concentration,regardless of total amount. B(s)+ C(g); ΔH°rxn > 0 Predict and explain how or whether the following actions would affect this equilibrium. a.adding more solid A b.lowering the temperature c.increasing the pressure on the system by reducing its volume d.adding helium gas to increase the total pressure a.No effect.Pure solids and liquids have constant concentration,regardless of total amount.

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For the reaction 2NOCl(g) For the reaction 2NOCl(g)   2NO(g)+ Cl<sub>2</sub>(g),K<sub>c</sub> = 8.0 at a certain temperature.What concentration of NOCl must be put into an empty 4.00 - reaction vessel in order that the equilibrium concentration of NOCl is 1.00 M? 2NO(g)+ Cl2(g),Kc = 8.0 at a certain temperature.What concentration of NOCl must be put into an empty 4.00 - reaction vessel in order that the equilibrium concentration of NOCl is 1.00 M?

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Which equation is correct?

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