Exam 15: Chemical Equilibrium
Exam 1: Chemistry: the Central Science129 Questions
Exam 2: Atoms Molecules and Ions120 Questions
Exam 3: Stoichiometry Ratios of Combination131 Questions
Exam 4: Reactions in Aqueous Solutions144 Questions
Exam 5: Thermochemistry134 Questions
Exam 6: Quantum Theory and the Electronic Structure of Atoms107 Questions
Exam 7: Electron Configuration and the Periodic Table120 Questions
Exam 8: Chemical Bonding I Basic Concepts95 Questions
Exam 9: Chemical Bonding Ii Molecular Geometry and Bonding Theories137 Questions
Exam 10: Gases131 Questions
Exam 11: Intermolecular Forces and the Physical Properties of Liquids and Solids135 Questions
Exam 12: Modern Materials108 Questions
Exam 13: Physical Properties of Solutions147 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium135 Questions
Exam 16: Acids and Bases133 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria129 Questions
Exam 18: Entropy Free Energy and Equilibrium61 Questions
Exam 19: Electrochemistry122 Questions
Exam 20: Nuclear Chemistry125 Questions
Exam 21: Environmental Chemistry131 Questions
Exam 22: Coordination Chemistry128 Questions
Exam 23: Metallurgy and the Chemistry of Metals115 Questions
Exam 24: Nonmetallic Elements and Their Compounds119 Questions
Exam 25: Organic Chemistry148 Questions
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Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine.
CCl4(g)+ ½O2(g)
COCl2(g)+ Cl2(g),Kc = 4.4 × 109 at 1000 K
What is Kc for the following reaction?
2CCl4(g)+ O2(g)
2COCl2(g)+ 2Cl2(g)
(Multiple Choice)
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Consider the following equilibria: 2SO3(g)
2SO2(g)+ O2(g)Kc = 2.3 × 10-7
2NO3(g)
2NO2(g)+ O2(g)Kc = 1.4 × 10-3
Calculate the equilibrium constant for the reaction
SO2(g)+ NO3(g)
SO3(g)+ NO2(g).
(Multiple Choice)
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For the common allotropes of carbon (graphite and diamond),C(gr)
C(dia)with equilibrium constant K = 0.32.The molar volumes of graphite and diamond are,respectively, 5.30 cm3/mol and 3.42 cm3/mol; ΔHf of diamond is 1.90 kJ/mol.These data suggest that the formation of diamond is favored at
(Multiple Choice)
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A(n)________________ means that the products of the reaction can react to form reactants.
(Short Answer)
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The reaction of nitrogen with oxygen to form nitrogen monoxide can be represented by the following equation. N2(g)+ O2(g)
2NO(g)
At 2000.°C,the equilibrium constant,Kc,has a value of 4.10 × 10-4.What is the value of KP?
(R = 0.08206 L • atm/K • mol)
(Multiple Choice)
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Calculate KP for the reaction 2NOCl(g)
2NO(g)+ Cl2(g)at 400.°C if Kc at 400.°C for this reaction is 2.1 × 10-2.(R = 0.08206 L • atm/K • mol)
(Multiple Choice)
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The following reaction is at equilibrium in a sealed container. N2(g)+ 3H2(g)
2NH3(g); ΔH°rxn < 0
Which,if any,of the following actions will increase the value of the equilibrium constant,Kc?
(Multiple Choice)
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For the following reaction at equilibrium in a reaction vessel,which one of these changes would cause the I2 concentration to increase? 2NOI(g)
2NO(g)+ I2(g),ΔHºrxn = 45.3 kJ/mol
(Multiple Choice)
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Hydrogen peroxide may decompose to form water and oxygen gas according to the following reaction. 2H2O2(g)
2H2O(g)+ O2(g)
In a particular experiment,1.75 moles of H2O2 were placed in a 2.5-L reaction chamber at
307ºC.After equilibrium was reached,1.20 moles of H2O2 remained.What is Kc for the reaction?
(Multiple Choice)
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The equilibrium constant for the reaction Ni(s)+ 4CO(g)
Ni(CO)4(g)is 5.0× 104 at 25ºC. What is the equilibrium constant for the following reaction?
Ni(CO)4(g)
Ni(s)+ 4CO(g)?
(Multiple Choice)
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During a chemical reaction,what defines when the concentrations of the reactants and products reach a constant level?
(Multiple Choice)
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The reaction 2H2O2(g)
2H2O(g)+ O2(g)is exothermic,ΔHºrxn = -210 kJ/mol.Which one of the following is correct?
(Multiple Choice)
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Which is the correct mass-action expression,Qc,for the following chemical reaction? Sn2+(aq)+ ½ O2(g)+ 3H2O(l)
SnO2(s)+ 2H3O+(aq)
(Multiple Choice)
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For the following reaction at 25ºC,is 3 × 1024. 2SO2(g)+ O2(g)
2SO3(g)
What is Kc at this temperature? (R = 0.08206 L • atm/K • mol)
(Multiple Choice)
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Consider this reaction at equilibrium: 2H2O2(g)
2H2O(g)+ O2(g),ΔHºrxn = -210 kJ/mol
If the volume of the system is expanded at constant temperature,what change will occur in the position of the equilibrium?
(Multiple Choice)
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Consider the equilibrium:
A(s)
B(s)+ C(g); ΔH°rxn > 0
Predict and explain how or whether the following actions would affect this equilibrium.
a.adding more solid A
b.lowering the temperature c.increasing the pressure on the system by reducing its volume d.adding helium gas to increase the total pressure a.No effect.Pure solids and liquids have constant concentration,regardless of total amount.
(Essay)
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For the reaction 2NOCl(g)
2NO(g)+ Cl2(g),Kc = 8.0 at a certain temperature.What concentration of NOCl must be put into an empty 4.00 - reaction vessel in order that the equilibrium concentration of NOCl is 1.00 M?
(Multiple Choice)
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