Exam 15: Chemical Equilibrium
Exam 1: Chemistry: the Central Science129 Questions
Exam 2: Atoms Molecules and Ions120 Questions
Exam 3: Stoichiometry Ratios of Combination131 Questions
Exam 4: Reactions in Aqueous Solutions144 Questions
Exam 5: Thermochemistry134 Questions
Exam 6: Quantum Theory and the Electronic Structure of Atoms107 Questions
Exam 7: Electron Configuration and the Periodic Table120 Questions
Exam 8: Chemical Bonding I Basic Concepts95 Questions
Exam 9: Chemical Bonding Ii Molecular Geometry and Bonding Theories137 Questions
Exam 10: Gases131 Questions
Exam 11: Intermolecular Forces and the Physical Properties of Liquids and Solids135 Questions
Exam 12: Modern Materials108 Questions
Exam 13: Physical Properties of Solutions147 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium135 Questions
Exam 16: Acids and Bases133 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria129 Questions
Exam 18: Entropy Free Energy and Equilibrium61 Questions
Exam 19: Electrochemistry122 Questions
Exam 20: Nuclear Chemistry125 Questions
Exam 21: Environmental Chemistry131 Questions
Exam 22: Coordination Chemistry128 Questions
Exam 23: Metallurgy and the Chemistry of Metals115 Questions
Exam 24: Nonmetallic Elements and Their Compounds119 Questions
Exam 25: Organic Chemistry148 Questions
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For the endothermic reaction A2(g)
2A(g),a snapshot of an equilibrium mixture of A(g)and A2(g)at low temperature may look as follows.(Each circle represents 1.0 mol of A atoms,and the volume of the box is 1.0 L.)
If the system pressure is lowered,what might the new equilibrium system look like?
(Multiple Choice)
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Consider the reversible reaction: 2NO2(g)
N2O4(g) If the concentrations of both NO2 and N2O4 are each 0.016 M,what is the value of Qc?
(Multiple Choice)
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A container was charged with hydrogen,nitrogen,and ammonia gases at 120°C and the system was allowed to reach equilibrium.What will happen if the volume of the container is increased at constant temperature? 3H2(g)+ N2(g)
2NH3(g)
(Multiple Choice)
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Which substances are included in the equilibrium constant expression,Kc?
(Multiple Choice)
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When the concentrations of both the reactants and products remain constant because the forward and reverse reactions are occurring at the same rate then the system is ________________.
(Short Answer)
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A mixture of 0.500 mole of carbon monoxide and 0.400 mole of bromine was placed into a rigid 1.00-L container and the system was allowed to come to equilibrium.The equilibrium concentration of COBr2 was 0.233 M.What is Kc for this reaction?
CO(g)+ Br2(g)
COBr2(g)
(Multiple Choice)
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Hydrogen sulfide can be formed in the following reaction: H2(g)+ S2(g)
H2S(g); ΔH°rxn = -92 kJ/mol
The equilibrium constant,KP,is 106 at 1023 K.Estimate the value of KP at 1218 K.(R = 8.314 J/K • mol)
(Multiple Choice)
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Which is the correct equilibrium constant expression for the following reaction? 2BrCl3(g)
Br2(g)+ 3Cl2(g)
(Multiple Choice)
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At 250ºC,the equilibrium constant,KP,for the reaction PCl5(g)
PCl3(g)+ Cl2(g)is 1.80. Sufficient PCl5 is put into a reaction vessel to give an initial pressure of 2.74 atm at 250ºC.What is the partial pressure of PCl5 after the system has reached equilibrium.
(Multiple Choice)
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If the system 3H2(g)+ N2(g)
2NH3(g)is at equilibrium and more N2 is added,a net reaction that consumes some of the added N2 will occur until a new equilibrium is reached.
(True/False)
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The equilibrium constant KP at 427°C for the reaction N2(g)+ 3H2(g)
2NH3(g)is 9.4 ×10-5.What is ΔG° for the reaction under these conditions? (R = 8.314 J/K • mol)
(Multiple Choice)
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Nitric oxide and bromine were allowed to react in a sealed container.When equilibrium was reached,the following partial pressures of three gases were measured: NO: 0.526 atm; Br2 :1.59 atm; NOBr: 7.68 atm.Calculate KP for the reaction. 2NO(g)+ Br2(g)
2NOBr(g)
(Multiple Choice)
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Consider the equilibrium reaction: N2O4(g)
2NO2(g) Which of the following correctly describes the relationship between Kc and KP for the reaction?
(Multiple Choice)
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If,in a particular process,reactants are able to form products,and products are also able to form reactants,then this process may be described as
(Multiple Choice)
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Suppose 75.0 g of PCl5(g)is introduced into an evacuated 3.00-L vessel and allowed to reach equilibrium at 250ºC. PCl5(g)
PCl3(g)+ Cl2(g)
If KP = 1.80 for this reaction,what is the total pressure inside the vessel at equilibrium? (R =0.0821 atm • L/mol • K)
(Multiple Choice)
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A quantity of liquid methanol,CH3OH,is introduced into a rigid 3.00-L vessel,the vessel is sealed,and the temperature is raised to 500 K.At this temperature,the methanol vaporizes and decomposes according to the reaction CH3OH(g)
CO(g)+ 2H2(g),Kc = 6.90 ×10-2
If the concentration of H2 in the equilibrium mixture is 0.426 M,what mass of methanol was initially introduced into the vessel?
(Multiple Choice)
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The equilibrium constant,KP,has a value of 6.5 × 10-4 at 308 K for the reaction of nitrogen monoxide with chlorine. 2NO(g)+ Cl2(g)
2NOCl(g)
What is the value of Kc? (R = 0.08206 L • atm/K • mol)
(Multiple Choice)
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In the gas phase,formic acid forms a dimer,2HCOOH(g)
(HCOOH)2(g).For this reaction,ΔH° = -60.1 kJ/mol and ΔG° = -13.9 kJ/mol at 25°C.Find the equilibrium constant (KP)for this reaction at 75 °C.
(Multiple Choice)
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Suppose 50.0 g of N2O4 is introduced into an evacuated 2.00-L vessel and allowed to come to equilibrium with its decomposition product,N2O4(g)
2NO2(g).For this reaction Kc = 0.133.Once the system has reached equilibrium,5.00 g of NO2 is injected into the vessel,and the system is allowed to equilibrate once again.What is the mass of NO2 in the final equilibrium mixture?
(Multiple Choice)
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