Exam 6: Energy Changes, Reaction Rates, and Equilibrium

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The difference in energy between the reactants and the transition state is called the energy of activation, symbolized by Ea.

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Chemical reactions are considered favorable if the products have a higher energy than the reactants.

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When the equilibrium constant for a reaction is much less than one (K < 1), the concentration of the products is larger than the concentration of the reactants.

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In the energy diagram shown below, the Δ\Delta H of the reaction is labeled by D.  In the energy diagram shown below, the  \Delta H of the reaction is labeled by D.

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Consider the reversible reaction: CO(g)+ Cl2(g)  Consider the reversible reaction: CO(g)+ Cl<sub>2</sub>(g)   COCl<sub>2</sub>(g). The reverse reaction is COCl<sub>2</sub>(g) \rightarrow  CO(g)+ Cl<sub>2</sub>(g). COCl2(g). The reverse reaction is COCl2(g) →\rightarrow CO(g)+ Cl2(g).

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An enzyme contains a region called its _____ that binds a reactant, which then undergoes a very specific reaction with an enhanced rate.

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When the pressure of a reaction at equilibrium decreases, in which direction does the equilibrium shift?

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Consider the reaction, C2H4(g)+ H2(g) →\rightarrow C2H6(g), where Δ\Delta H = -137 kJ. How many kilojoules are released when 3.5 mol of C2H4 reacts?

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Which of the following energy quantities is equivalent to 11.9 kcal?

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A reversible reaction has reached equilibrium when which condition is established?

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Activation energy is the minimum amount of energy necessary for a reaction to occur.

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In the reaction: 2 C2H6(g)+ 7 O2(g) →\rightarrow 4 CO2(g)+ 6 H2O(g), increasing the concentration of C2H6(g)will

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The molecular art depicts the following reversible reaction at equilibrium: CO(g)+ Cl2(g) The molecular art depicts the following reversible reaction at equilibrium: CO(g)+ Cl<sub>2</sub>(g)   COCl<sub>2</sub>(g). What can be inferred about the equilibrium constant, K, for this reaction?  COCl2(g). What can be inferred about the equilibrium constant, K, for this reaction? The molecular art depicts the following reversible reaction at equilibrium: CO(g)+ Cl<sub>2</sub>(g)   COCl<sub>2</sub>(g). What can be inferred about the equilibrium constant, K, for this reaction?

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Consider the reversible reaction at equilibrium: N2(g)+ O2(g) Consider the reversible reaction at equilibrium: N<sub>2</sub>(g)+ O<sub>2</sub>(g)   2 NO(g). What is the effect of removing some N<sub>2</sub>(g)from the equilibrium system? 2 NO(g). What is the effect of removing some N2(g)from the equilibrium system?

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A chemical reaction requires 31.39 kJ. How many kilocalories does this correspond to?

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As a general rule, a reaction rate _____ for each 10 °C the temperature is raised.

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Enzymes are proteins that act as biological catalysts.

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Increasing the concentration of the reactants in a chemical reaction increases the number of collisions, and the reaction rate increases.

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Reactions with high Ea are generally fast reactions.

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When Δ\Delta H is negative, the bonds formed in the products are _____ than the bonds broken in the reactants.

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