Exam 6: Energy Changes, Reaction Rates, and Equilibrium

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Consider the reaction: PCl3(g)+ Cl2(g) Consider the reaction: PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)   PCl<sub>5</sub>(g). If [PCl<sub>3</sub>] = 0.78 M, [Cl<sub>2</sub>] = 0.44 M, and [PCl<sub>5</sub>] = 0.88 at equilibrium, what is the value of K? PCl5(g). If [PCl3] = 0.78 M, [Cl2] = 0.44 M, and [PCl5] = 0.88 at equilibrium, what is the value of K?

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A reversible reaction in which K = 9.65 × 10-14 contains a negligible amount of reactants at equilibrium.

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Walking at a brisk pace burns off about 280 Cal/h. How long would you have to walk to burn off the Calories obtained from eating a candy bar that contained 3 g of protein, 12 g of fat, and 28 g of carbohydrates?

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Kinetic energy is the energy associated with movement; potential energy is the energy inherent in an object due to its position or composition.

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In the energy diagram shown below, C labels the _____. In the energy diagram shown below, C labels the _____.

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The Δ\Delta H for the reaction depicted by the energy diagram below is ____.  The \Delta H for the reaction depicted by the energy diagram below is ____.

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One step in the metabolism of glucose is depicted below. Which statement best describes how the equilibrium system would respond if the amount of dihydroxyacetone phosphate is decreased? One step in the metabolism of glucose is depicted below. Which statement best describes how the equilibrium system would respond if the amount of dihydroxyacetone phosphate is decreased?

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Bond dissociation energies are always positive numbers.

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Once equilibrium is reached in a chemical reaction, reactants stop forming products.

(True/False)
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Consider the reaction, C2H4(g)+ H2(g) →\rightarrow C2H6(g), where Δ\Delta H = -137 kJ. How many kilojoules are released when 55.3 g of C2H4 reacts?

(Multiple Choice)
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The expression for the equilibrium constant, K, for the general reaction: a A + b B The expression for the equilibrium constant, K, for the general reaction: a A + b B   c C + d D is   . c C + d D is The expression for the equilibrium constant, K, for the general reaction: a A + b B   c C + d D is   . .

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When heat is added to an exothermic equilibrium reaction, the reaction shifts to form more ____.

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Which term correctly describes a reaction in which the energy of the products is higher than the energy of the reactants?

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Which statement concerning the reversible reaction 2 NO2(g) Which statement concerning the reversible reaction 2 NO<sub>2</sub>(g)   N<sub>2</sub>O<sub>4</sub>(g)is true? N2O4(g)is true?

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An equilibrium constant with a value of 8.0 × 106 indicates that at equilibrium

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Which of the following is NOT a reasonable assumption about the chemical reaction whose energy diagram is depicted below? Which of the following is NOT a reasonable assumption about the chemical reaction whose energy diagram is depicted below?

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Consider the reaction: N2(g)+ O2(g) Consider the reaction: N<sub>2</sub>(g)+ O<sub>2</sub>(g)   2 NO(g). If [N<sub>2</sub>] = 0.520 M, [O<sub>2</sub>] = 0.0662 M, and [NO] = 0.00956 at equilibrium, what is the value of K? 2 NO(g). If [N2] = 0.520 M, [O2] = 0.0662 M, and [NO] = 0.00956 at equilibrium, what is the value of K?

(Multiple Choice)
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Increasing the temperature of a reaction mixture usually results in a decrease in the reaction rate.

(True/False)
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Le Châtelier's principle is a general rule used to explain the effect of a change in reaction conditions on equilibrium.

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Exothermic reactions involve the formation of products having lower energy than the reactants.

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