Exam 6: Energy Changes, Reaction Rates, and Equilibrium

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The stronger the bond, the higher its bond dissociation energy.

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Consider the following reversible reaction at equilibrium: CO(g)+ Cl2(g) Consider the following reversible reaction at equilibrium: CO(g)+ Cl<sub>2</sub>(g)   COCl<sub>2</sub>(g). If the pressure inside the reaction vessel is increased, the equilibrium will shift to the left. COCl2(g). If the pressure inside the reaction vessel is increased, the equilibrium will shift to the left.

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Which of the following energy quantities is equivalent to 578 J?

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In an _____ reaction, the products are lower in energy than the reactants.

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When reactants can come together and form products, and products can come together to re-form reactants, the reaction is called a _____ reaction.

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Consider the following reversible reaction at equilibrium: CO(g)+ Cl2(g) Consider the following reversible reaction at equilibrium: CO(g)+ Cl<sub>2</sub>(g)   COCl<sub>2</sub>(g). If chlorine gas is added to the reaction vessel, the concentration of carbon monoxide will decrease. COCl2(g). If chlorine gas is added to the reaction vessel, the concentration of carbon monoxide will decrease.

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The rate of a chemical reaction increases with an increase in the concentration of one or more reactants. This is best explained by which statement?

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For an endothermic reaction at equilibrium, increasing the temperature

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Which bond is the strongest?

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Changes in potential energy occur in chemical reactions.

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Consider the following reversible reaction at equilibrium: CO(g)+ Cl2(g)  Consider the following reversible reaction at equilibrium: CO(g)+ Cl<sub>2</sub>(g)   COCl<sub>2</sub>(g), where  \Delta H = -108.6 kJ. When the temperature of the reaction vessel decreases, the system responds by forming more COCl<sub>2</sub>. COCl2(g), where Δ\Delta H = -108.6 kJ. When the temperature of the reaction vessel decreases, the system responds by forming more COCl2.

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Bond breaking is endothermic.

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The larger the K for a reaction, the faster the reaction.

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Consider the reaction: 2 C2H6(g)+ 7 O2(g) →\rightarrow 4 CO2(g)+ 6 H2O(g). Increasing the concentration of C2H6(g)will decrease the activation energy.

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The law of conservation of energy states that

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A manufacturing company requires 157 kJ of energy to power one of its machines for a day. The reaction shown below would be able to provide a sufficient amount of energy for this purpose. 2 HgO(s) →\rightarrow 2 Hg(l)+ O2(g) Δ\Delta H = 182 kJ

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Consider the reversible reaction: PCl3(g)+ Cl2(g) Consider the reversible reaction: PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)   PCl<sub>5</sub>(g), where K = 0.5. Since K < 1, [PCl<sub>5</sub>] must be less than 1 M. PCl5(g), where K = 0.5. Since K < 1, [PCl5] must be less than 1 M.

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Ammonia (NH3)is synthesized by the reaction of nitrogen and hydrogen in the presence of an iron catalyst according to the equation below. Removing the iron catalyst would decrease the reaction rate. Ammonia (NH<sub>3</sub>)is synthesized by the reaction of nitrogen and hydrogen in the presence of an iron catalyst according to the equation below. Removing the iron catalyst would decrease the reaction rate.

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Which of the following energy quantities is equivalent to 258 Cal?

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A chemical reaction releases 55.2 kcal. How many kilojoules does this correspond to?

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