Exam 25: The Chemistry of Metabolism

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Of the following compounds, which are consumed in any step of the glycolytic conversion of glucose to pyruvate: ATP, ADP, NAD+, NADH, FAD, FADH2, Acetyl-CoA.

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Causing a burning sensation in the muscles, what compound builds up in muscle cells when glycolysis occurs under anaerobic conditions?

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Identify the seventh step of the citric acid cycle.

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Under anaerobic conditions, what compound in mammalian cells is used to oxidize NADH back to NAD+ so that glycolysis can continue?

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What explains the kinetic stability of ATP in aqueous media at biological pH?

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A phosphoanhydride bond is known as a ________ bond.

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How does production of pyrophosphate as the byproduct in a phosphorylation mechanism result in irreversibility of the transfer?

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Draw the structure of a fatty acyl-CoA.

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Each round of the citric acid cycle forms ________ molecule(s)of NADH.

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What class of enzyme puts a phosphoryl group on its substrate?

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In which stage of catabolism is the citric acid cycle found?

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How many isoprene units are in β-carotene? How many isoprene units are in β-carotene?

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Give the product(s)for the following reaction. Give the product(s)for the following reaction.

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What coenzymes are required for the b-oxidation pathway?

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Give the number of ATP molecules formed from NADH in the fourth stage of catabolism.

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Propose a mechanism for the reaction, of dimethylallyl pyrophosphate with isopentenyl pyrophosphate to form geranyl pyrophosphate. Propose a mechanism for the reaction, of dimethylallyl pyrophosphate with isopentenyl pyrophosphate to form geranyl pyrophosphate.

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Each round of the citric acid cycle forms ________ molecule(s)of FADH2.

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Which of the following terms best describes the compound below? Which of the following terms best describes the compound below?

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At biological pH, ADP has ________ negative charges per molecule.

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________ is the only non-citric acid cycle intermediate that can enter the cycle.

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