Exam 19: Chemical Thermodynamics

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The quantity of energy gained by a system equals the quantity of energy gained by its surroundings.

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Calculate ΔG° for the autoionization of water at 25 °C. Kw = 1.0 × 10-14

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The value of ΔG° at 25 °C for the formation of calcium chloride from its constituent elements, Ca (s) + Cl2 (g) → CaCl2 (s) Is ________ kJ/mol.

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In the Haber process, ammonia is synthesized from nitrogen and hydrogen: N2 (g) + 3H2 (g) → 2NH3 (g) ΔG° at 298 K for this reaction is -33.3 kJ/mol. The value of ΔG at 298 K for a reaction mixture that consists of 1.9 atm N2, 2.3 atm H2, and 0.85 atm NH3 is ________.

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For an isothermal process, ΔS = ________.

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