Exam 14: Chemical Equilibrium
Exam 1: Chemistry: The Study of Change153 Questions
Exam 2: Atoms, Molecules, and Ions141 Questions
Exam 3: Mass Relationships in Chemical Reactions168 Questions
Exam 4: Reactions in Aqueous Solution161 Questions
Exam 5: Gases109 Questions
Exam 6: Thermo-Chemistry111 Questions
Exam 7: Quantum Theory and the Electronic Structure of Atoms115 Questions
Exam 8: Periodic Relationships Among the Elements119 Questions
Exam 9: Chemical Bonding I: Basic Concepts118 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals122 Questions
Exam 11: Intermolecular Forces and Liquids and Solids140 Questions
Exam 12: Physical Properties of Solutions109 Questions
Exam 13: Chemical Kinetics114 Questions
Exam 14: Chemical Equilibrium100 Questions
Exam 15: Acids and Bases163 Questions
Exam 16: Acid-Base Equilibria and Solubility Equilibria110 Questions
Exam 17: Chemistry in the Atmosphere41 Questions
Exam 18: Entropy, Free Energy, and Equilibrium112 Questions
Exam 19: Electrochemistry138 Questions
Exam 20: Metallurgy and the Chemistry of Metals58 Questions
Exam 21: Nonmetallic Elements and Their Compounds41 Questions
Exam 22: Transition Metal Chemistry and Coordination Compounds80 Questions
Exam 23: Nuclear Chemistry112 Questions
Exam 24: Organic Chemistry57 Questions
Exam 25: Synthetic and Natural Organic Polymers42 Questions
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The reaction 2NO(g)
N2(g)+ O2(g)is exothermic, Hºrxn = -180 kJ/mol.Which one of these statements is true?
(Multiple Choice)
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Consider this reaction at equilibrium at a total pressure P1: 2SO2(g)+ O2(g)
2SO3(g)
Suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished. The new equilibrium total pressure will be
(Multiple Choice)
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At 35ºC, the equilibrium constant for the reaction 2NOCl(g)
2NO(g)+ Cl2(g)is Kc = 1.6 * 10-5. An equilibrium mixture was found to have the following concentrations of Cl2 and NOCl: [Cl2] = 1.2 * 10-2 M; [NOCl] = 2.8 * 10-1 M. Calculate the concentration of NO(g)at equilibrium.
(Multiple Choice)
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When the reaction 2O3(g)
3O2(g), for which Kp = 3.0 * 1026 at 773ºC, is at equilibrium, the mixture will contain very little O2 as compared to O3.
(True/False)
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Consider the reaction N2(g)+ 3H2(g)
2NH3(g). The production of ammonia is an endothermic reaction.Will heating the equilibrium system increase or decrease the amount of ammonia produced?
(Essay)
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Consider the reaction N2(g)+ O2(g)
2NO(g), for which Kc = 0.10 at 2,000ºC.Starting with initial concentrations of 0.040 M of N2 and 0.040 M of O2, determine the equilibrium concentration of NO.
(Multiple Choice)
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What is the correct equilibrium constant expression for this reaction?
2HI(g)
H2(g)+ I2(g)
(Essay)
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Consider the chemical reaction 2NH3(g)
N2(g)+ 3H2(g).The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 * 10-2. Initially, 1,220 moles of NH3(g)are present.Calculate Kp for the reaction.
(Short Answer)
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For the reaction H2(g)+ I2(g)
2HI(g), Kc = 50.2 at 445ºC.If [H2] = [I2] = [HI] = 1.75 * 10-3 M at 445ºC, which one of these statements is true?
(Multiple Choice)
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Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide.
CaCO3(s)
CaO(s)+ CO2(g)
KP for this reaction is 1.16 at 800°C.A 5.00 L vessel containing 10.0 g of CaCO3(s)was evacuated to remove the air, sealed, and then heated to 800°C.Ignoring the volume occupied by the solid, what will be the mass of the solid in the vessel once equilibrium is reached?
(Short Answer)
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Two moles of PCl5 are placed in a 5.0 L container.Dissociation takes place according to the equation PCl5(g)
PCl3(g)+ Cl2(g).At equilibrium, 0.40 mol of Cl2 are present.Calculate the equilibrium constant (Kc)for this reaction under the conditions of this experiment.
(Short Answer)
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Consider the reaction N2(g)+ 3H2(g)
2NH3(g). If nitrogen is removed from the system at equilibrium, what will happen to the hydrogen (H2)concentration?
(Short Answer)
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Consider the equilibrium equation C(s)+ H2O(g)+ 2296 J
CO(g)+ H2(g).Which way will the reaction shift if the pressure on the system is increased?
(Short Answer)
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In which of these gas-phase equilibria is the yield of products increased by increasing the total pressure on the reaction mixture?
(Multiple Choice)
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Consider the following equilibrium,
4NH3(g)+ 3O2(g)
2N2(g)+ 6H2O(g)+ 1531 kJ
State whether the concentrations the products would increase, decrease, or remain constant after ammonia was added to the system.
(Short Answer)
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For the following reaction at equilibrium in a reaction vessel, which one of these changes would cause the Br2 concentration to decrease? 2NOBr(g)
2NO(g)+ Br2(g), Hºrxn= 30 kJ/mol
(Multiple Choice)
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The equilibrium constant for the reaction Ni(s)+ 4CO(g)
Ni(CO)4(g)is 5.0 * 104 at 25ºC. What is the equilibrium constant for the reaction Ni(CO)4(g)
Ni(s)+ 4CO(g)?
(Multiple Choice)
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Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide.
CaCO3(s)
CaO(s)+ CO2(g)
KP for this reaction is 1.16 at 800°C.A 5.00 L vessel containing 10.0 g of CaCO3(s)was evacuated to remove the air, sealed, and then heated to 800°C.Ignoring the volume occupied by the solid, what will be the overall mass percent of carbon in the solid once equilibrium is reached?
(Short Answer)
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The equilibrium constant expression for the reaction
CuO(s)+ H2(g)
Cu(s)+ H2O(g)is Kc = [H2]/[H2O].
(True/False)
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