Exam 14: Chemical Equilibrium

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The reaction A(g)+ 2B(g) The reaction A(g)+ 2B(g)   <sub> </sub> <sub> </sub>C(g)was allowed to come to equilibrium. The initial amounts of reactants placed into a 5.00 L vessel were 1.0 mol A and 1.8 mol B. After the reaction reached equilibrium, 1.0 mol of B was found. Calculate K<sub>c</sub> for this reaction. C(g)was allowed to come to equilibrium. The initial amounts of reactants placed into a 5.00 L vessel were 1.0 mol A and 1.8 mol B. After the reaction reached equilibrium, 1.0 mol of B was found. Calculate Kc for this reaction.

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On analysis, an equilibrium mixture for the reaction 2H2S(g) On analysis, an equilibrium mixture for the reaction 2H<sub>2</sub>S(g)   <sub> </sub> <sub> </sub>2H<sub>2</sub>(g)+ S<sub>2</sub>(g)was found to contain 1.0 mol H<sub>2</sub>S, 4.0 mol H<sub>2</sub>, and 0.80 mol S<sub>2</sub> in a 4.0 L vessel. Calculate the equilibrium constant, K<sub>c</sub>, for this reaction. 2H2(g)+ S2(g)was found to contain 1.0 mol H2S, 4.0 mol H2, and 0.80 mol S2 in a 4.0 L vessel. Calculate the equilibrium constant, Kc, for this reaction.

(Multiple Choice)
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Kc for the reaction CO2(g)+ H2(g) K<sub>c</sub> for the reaction CO<sub>2</sub>(g)+ H<sub>2</sub>(g)   <sub> </sub> H<sub>2</sub>O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of carbon monoxide in the final equilibrium system obtained by initially adding 1.00 mol of H<sub>2</sub>, 2.00 mol of CO<sub>2</sub>, 0.750 mol of H<sub>2</sub>O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC. H2O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of carbon monoxide in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.

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For the reaction SO2(g)+ NO2(g) For the reaction SO<sub>2</sub>(g)+ NO<sub>2</sub>(g)   <sub> </sub> SO<sub>3</sub>(g)+ NO(g), the equilibrium constant is 18.0 at 1,200ºC. If 1.0 mole of SO<sub>2</sub> and 2.0 moles of NO<sub>2</sub> are placed in a 20.L container, what concentration of SO<sub>3</sub> will be present at equilibrium? SO3(g)+ NO(g), the equilibrium constant is 18.0 at 1,200ºC. If 1.0 mole of SO2 and 2.0 moles of NO2 are placed in a 20.L container, what concentration of SO3 will be present at equilibrium?

(Multiple Choice)
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Phosgene, COCl2, a poisonous gas, decomposes according to the equation COCl2(g) Phosgene, COCl<sub>2</sub>, a poisonous gas, decomposes according to the equation COCl<sub>2</sub>(g)   <sub> </sub> <sub> </sub>CO(g)+ Cl<sub>2</sub>(g). Calculate K<sub>p</sub> for this reaction if K<sub>c</sub> = 0.083 at 900ºC. CO(g)+ Cl2(g). Calculate Kp for this reaction if Kc = 0.083 at 900ºC.

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Consider the following equilibrium, 4NH3(g)+ 3O2(g) Consider the following equilibrium, 4NH<sub>3</sub>(g)+ 3O<sub>2</sub>(g)   <sub> </sub> 2N<sub>2</sub>(g)+ 6H<sub>2</sub>O(g)+ 1531 kJ State whether the concentrations of the products would increase, decrease, or remain constant when the temperature is increased. 2N2(g)+ 6H2O(g)+ 1531 kJ State whether the concentrations of the products would increase, decrease, or remain constant when the temperature is increased.

(Short Answer)
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Consider the equilibrium equation C(s)+ H2O(g)+ 2296 J Consider the equilibrium equation C(s)+ H<sub>2</sub>O(g)+ 2296 J   <sub> </sub> CO(g)+ H<sub>2</sub>(g).If additional gaseous water is added to this reaction mixture, what will happen to the temperature of the mixture? CO(g)+ H2(g).If additional gaseous water is added to this reaction mixture, what will happen to the temperature of the mixture?

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Describe why addition of a catalyst does not affect the equilibrium constant for a reaction.

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If one starts with pure NO2(g)at a pressure of 0.500 atm, the total pressure inside the reaction vessel when 2NO2(g) If one starts with pure NO<sub>2</sub>(g)at a pressure of 0.500 atm, the total pressure inside the reaction vessel when 2NO<sub>2</sub>(g)   <sub> </sub> <sub> </sub>2NO(g)+ O<sub>2</sub>(g)reaches equilibrium is 0.674 atm. Calculate the equilibrium partial pressure of NO<sub>2</sub>. 2NO(g)+ O2(g)reaches equilibrium is 0.674 atm. Calculate the equilibrium partial pressure of NO2.

(Multiple Choice)
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Which of these statements is true about chemical equilibria in general?

(Multiple Choice)
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When the substances in the equation below are at equilibrium, at pressure P and temperature T, the equilibrium can be shifted to favor the products by CuO(s)+ H2(g)  When the substances in the equation below are at equilibrium, at pressure P and temperature T, the equilibrium can be shifted to favor the products by CuO(s)+ H<sub>2</sub>(g)   <sub> </sub> H<sub>2</sub>O(g)+ Cu(s) \Delta Hº<sub>rxn</sub> = -2.0 kJ/mol H2O(g)+ Cu(s) Δ\Delta Hºrxn = -2.0 kJ/mol

(Multiple Choice)
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Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl4(g)+ 1/2O2(g) Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl<sub>4</sub>(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub> <sub> </sub>COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g), K<sub>c</sub> = 4.4 * 10<sup>9</sup> at 1,000 K Calculate K<sub>c</sub> for the reaction 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   <sub> </sub> <sub> </sub>2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g). COCl2(g)+ Cl2(g), Kc = 4.4 * 109 at 1,000 K Calculate Kc for the reaction 2CCl4(g)+ O2(g) Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl<sub>4</sub>(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub> <sub> </sub>COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g), K<sub>c</sub> = 4.4 * 10<sup>9</sup> at 1,000 K Calculate K<sub>c</sub> for the reaction 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   <sub> </sub> <sub> </sub>2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g). 2COCl2(g)+ 2Cl2(g).

(Multiple Choice)
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Calculate Kc for the reaction 2HI(g) Calculate K<sub>c</sub> for the reaction 2HI(g)<sub> </sub> <sub> </sub>   <sub> </sub> <sub> </sub>H<sub>2</sub>(g)+ I<sub>2</sub>(g)given that the concentrations of each species at equilibrium are as follows: [HI] = 0.85 mol/L, [I<sub>2</sub>] = 0.60 mol/L, [H<sub>2</sub>] = 0.27 mol/L. H2(g)+ I2(g)given that the concentrations of each species at equilibrium are as follows: [HI] = 0.85 mol/L, [I2] = 0.60 mol/L, [H2] = 0.27 mol/L.

(Multiple Choice)
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At 250ºC, the equilibrium constant Kp for the reaction PCl5(g) At 250ºC, the equilibrium constant K<sub>p</sub> for the reaction PCl<sub>5</sub>(g)   <sub> </sub> <sub> </sub>PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g)is 1.80.Sufficient PCl<sub>5</sub> is put into a reaction vessel to give an initial pressure of 2.74 atm at 250ºC.Calculate the pressure of PCl<sub>5</sub> after the system has reached equilibrium. PCl3(g)+ Cl2(g)is 1.80.Sufficient PCl5 is put into a reaction vessel to give an initial pressure of 2.74 atm at 250ºC.Calculate the pressure of PCl5 after the system has reached equilibrium.

(Multiple Choice)
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The equilibrium constant for the chemical equation 2NO(g)+ O2(g) The equilibrium constant for the chemical equation 2NO(g)+ O<sub>2</sub>(g)   <sub> </sub> 2NO<sub>2</sub>(g) is two times the equilibrium constant for the chemical equation NO(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub> NO<sub>2</sub>(g). 2NO2(g) is two times the equilibrium constant for the chemical equation NO(g)+ 1/2O2(g) The equilibrium constant for the chemical equation 2NO(g)+ O<sub>2</sub>(g)   <sub> </sub> 2NO<sub>2</sub>(g) is two times the equilibrium constant for the chemical equation NO(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub> NO<sub>2</sub>(g). NO2(g).

(True/False)
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The equilibrium between carbon dioxide gas and carbonic acid is very important in biology and environmental science. CO2(aq)+ H2O(l) The equilibrium between carbon dioxide gas and carbonic acid is very important in biology and environmental science. CO<sub>2</sub>(aq)+ H<sub>2</sub>O(l)   <sub> </sub> <sub> </sub>H<sub>2</sub>CO<sub>3</sub>(aq) Which one of the following is the correct equilibrium constant expression (K<sub>c</sub>)for this reaction? H2CO3(aq) Which one of the following is the correct equilibrium constant expression (Kc)for this reaction?

(Multiple Choice)
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Hydrogen iodide decomposes according to the equation: 2HI(g) Hydrogen iodide decomposes according to the equation: 2HI(g)   <sub> </sub> H<sub>2</sub>(g)+ I<sub>2</sub>(g), K<sub>c</sub> = 0.0156 at 400ºC A 0.660 mol sample of HI was injected into a 2.00 L reaction vessel held at 400ºC. Calculate the concentration of HI at equilibrium. H2(g)+ I2(g), Kc = 0.0156 at 400ºC A 0.660 mol sample of HI was injected into a 2.00 L reaction vessel held at 400ºC. Calculate the concentration of HI at equilibrium.

(Short Answer)
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Consider the following reactions and their associated equilibrium constants: Consider the following reactions and their associated equilibrium constants:    For the reaction A + 2B  D + E, having equilibrium constant K<sub>c</sub>, For the reaction A + 2B Consider the following reactions and their associated equilibrium constants:    For the reaction A + 2B  D + E, having equilibrium constant K<sub>c</sub>,D + E, having equilibrium constant Kc,

(Multiple Choice)
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For the following reaction at equilibrium in a reaction vessel, which one of these changes would cause the Br2 concentration to increase? 2NOBr(g)  For the following reaction at equilibrium in a reaction vessel, which one of these changes would cause the Br<sub>2</sub> concentration to increase? 2NOBr(g)   <sub> </sub> 2NO(g)+ Br<sub>2</sub>(g),  \Delta Hº<sub>rxn</sub>= 30 kJ/mol 2NO(g)+ Br2(g), Δ\Delta Hºrxn= 30 kJ/mol

(Multiple Choice)
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Consider the two gaseous equilibria: Consider the two gaseous equilibria:    The values of the equilibrium constants K<sub>1</sub> and K<sub>2</sub><sub> </sub>are related by The values of the equilibrium constants K1 and K2 are related by

(Multiple Choice)
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