Exam 14: Chemical Equilibrium
Exam 1: Chemistry: The Study of Change153 Questions
Exam 2: Atoms, Molecules, and Ions141 Questions
Exam 3: Mass Relationships in Chemical Reactions168 Questions
Exam 4: Reactions in Aqueous Solution161 Questions
Exam 5: Gases109 Questions
Exam 6: Thermo-Chemistry111 Questions
Exam 7: Quantum Theory and the Electronic Structure of Atoms115 Questions
Exam 8: Periodic Relationships Among the Elements119 Questions
Exam 9: Chemical Bonding I: Basic Concepts118 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals122 Questions
Exam 11: Intermolecular Forces and Liquids and Solids140 Questions
Exam 12: Physical Properties of Solutions109 Questions
Exam 13: Chemical Kinetics114 Questions
Exam 14: Chemical Equilibrium100 Questions
Exam 15: Acids and Bases163 Questions
Exam 16: Acid-Base Equilibria and Solubility Equilibria110 Questions
Exam 17: Chemistry in the Atmosphere41 Questions
Exam 18: Entropy, Free Energy, and Equilibrium112 Questions
Exam 19: Electrochemistry138 Questions
Exam 20: Metallurgy and the Chemistry of Metals58 Questions
Exam 21: Nonmetallic Elements and Their Compounds41 Questions
Exam 22: Transition Metal Chemistry and Coordination Compounds80 Questions
Exam 23: Nuclear Chemistry112 Questions
Exam 24: Organic Chemistry57 Questions
Exam 25: Synthetic and Natural Organic Polymers42 Questions
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The reaction A(g)+ 2B(g)
C(g)was allowed to come to equilibrium. The initial amounts of reactants placed into a 5.00 L vessel were 1.0 mol A and 1.8 mol B. After the reaction reached equilibrium, 1.0 mol of B was found. Calculate Kc for this reaction.
(Multiple Choice)
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On analysis, an equilibrium mixture for the reaction 2H2S(g)
2H2(g)+ S2(g)was found to contain 1.0 mol H2S, 4.0 mol H2, and 0.80 mol S2 in a 4.0 L vessel. Calculate the equilibrium constant, Kc, for this reaction.
(Multiple Choice)
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Kc for the reaction CO2(g)+ H2(g)
H2O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of carbon monoxide in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.
(Short Answer)
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For the reaction SO2(g)+ NO2(g)
SO3(g)+ NO(g), the equilibrium constant is 18.0 at 1,200ºC. If 1.0 mole of SO2 and 2.0 moles of NO2 are placed in a 20.L container, what concentration of SO3 will be present at equilibrium?
(Multiple Choice)
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Phosgene, COCl2, a poisonous gas, decomposes according to the equation COCl2(g)
CO(g)+ Cl2(g). Calculate Kp for this reaction if Kc = 0.083 at 900ºC.
(Multiple Choice)
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Consider the following equilibrium,
4NH3(g)+ 3O2(g)
2N2(g)+ 6H2O(g)+ 1531 kJ
State whether the concentrations of the products would increase, decrease, or remain constant when the temperature is increased.
(Short Answer)
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Consider the equilibrium equation C(s)+ H2O(g)+ 2296 J
CO(g)+ H2(g).If additional gaseous water is added to this reaction mixture, what will happen to the temperature of the mixture?
(Short Answer)
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Describe why addition of a catalyst does not affect the equilibrium constant for a reaction.
(Essay)
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If one starts with pure NO2(g)at a pressure of 0.500 atm, the total pressure inside the reaction vessel when 2NO2(g)
2NO(g)+ O2(g)reaches equilibrium is 0.674 atm. Calculate the equilibrium partial pressure of NO2.
(Multiple Choice)
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Which of these statements is true about chemical equilibria in general?
(Multiple Choice)
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When the substances in the equation below are at equilibrium, at pressure P and temperature T, the equilibrium can be shifted to favor the products by CuO(s)+ H2(g)
H2O(g)+ Cu(s) Hºrxn = -2.0 kJ/mol
(Multiple Choice)
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Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl4(g)+ 1/2O2(g)
COCl2(g)+ Cl2(g), Kc = 4.4 * 109 at 1,000 K
Calculate Kc for the reaction 2CCl4(g)+ O2(g)
2COCl2(g)+ 2Cl2(g).
(Multiple Choice)
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Calculate Kc for the reaction 2HI(g)
H2(g)+ I2(g)given that the concentrations of each species at equilibrium are as follows: [HI] = 0.85 mol/L, [I2] = 0.60 mol/L, [H2] = 0.27 mol/L.
(Multiple Choice)
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At 250ºC, the equilibrium constant Kp for the reaction PCl5(g)
PCl3(g)+ Cl2(g)is 1.80.Sufficient PCl5 is put into a reaction vessel to give an initial pressure of 2.74 atm at 250ºC.Calculate the pressure of PCl5 after the system has reached equilibrium.
(Multiple Choice)
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The equilibrium constant for the chemical equation
2NO(g)+ O2(g)
2NO2(g)
is two times the equilibrium constant for the chemical equation
NO(g)+ 1/2O2(g)
NO2(g).
(True/False)
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The equilibrium between carbon dioxide gas and carbonic acid is very important in biology and environmental science. CO2(aq)+ H2O(l)
H2CO3(aq)
Which one of the following is the correct equilibrium constant expression (Kc)for this reaction?
(Multiple Choice)
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Hydrogen iodide decomposes according to the equation:
2HI(g)
H2(g)+ I2(g), Kc = 0.0156 at 400ºC
A 0.660 mol sample of HI was injected into a 2.00 L reaction vessel held at 400ºC.
Calculate the concentration of HI at equilibrium.
(Short Answer)
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Consider the following reactions and their associated equilibrium constants:
For the reaction A + 2B
D + E, having equilibrium constant Kc,
(Multiple Choice)
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For the following reaction at equilibrium in a reaction vessel, which one of these changes would cause the Br2 concentration to increase? 2NOBr(g)
2NO(g)+ Br2(g), Hºrxn= 30 kJ/mol
(Multiple Choice)
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Consider the two gaseous equilibria:
The values of the equilibrium constants K1 and K2 are related by
(Multiple Choice)
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