Exam 12: Physical Properties of Solutions

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The solubility of oxygen in lakes high in the Rocky Mountains is affected by the altitude. If the solubility of O2 from the air is 2.67 * 10-4 M at sea level and 25°C, what is the solubility of O2 at an elevation of 12,000 ft where the atmospheric pressure is 0.657 atm? Assume the temperature is 25°C, and that the mole fraction of O2 in air is 0.209 at both 12,000 ft and at sea level.

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Calculate the approximate freezing point of a solution made from 21.0 g NaCl and 1.00 * 102 g of H2O. [Kf of water is 1.86°C/m.]

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Pure benzene, C6H6, freezes at 5.5° and boils at 80.1°C. What is the boiling point of a solution consisting of cyclohexane (C6H12)dissolved in benzene if the freezing point of this solution is 0.0°C? (For benzene, Kf = 5.12 °C/m, Kb = 2.53 °C/m; for cyclohexane, Kf = 20.0 °C/m, Kb = 2.79°C/m)

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The osmotic pressure of a 0.010 M MgSO4 solution at 25°C is 0.318 atm. Calculate i, the van't Hoff factor, for this MgSO4 solution.

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The solubility of oxygen in water is about 4.5 * 10-2 g/L.The water portion of an adult's total blood supply is about 5 liters.How many grams of oxygen could dissolve in 5 liters of water?

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The concentration of nitrogen in water at 25°C was determined to be 7.2 *10-6 M.Calculate the partial pressure of nitrogen at the surface of the water in mmHg. The Henry's law constant for nitrogen gas at 25°C is 6.8 *10-4 mol/L·atm?

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How many grams of propanol (C3H7OH, 60.10 g/mol)would be needed to make 750 mL of a solution with an osmotic pressure of 25 atm at 25°C? (R = 0.0821 L.atm/K.mol)

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What is the percent CdSO4 by mass in a 1.0 molal aqueous CdSO4 solution?

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Calculate the molality of 6.0 M H2SO4 solution. The density of the solution is 1.34 g/mL.

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A 100.mL sample of water is taken from the Great Salt Lake, and the water is allowed to evaporate.The salts that remain (mostly NaCl)have a mass of 31.9 g Calculate the original concentration of NaCl, in g per liter, in each water sample.

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During osmosis

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Determine the mass percent HCl in a 1.2 M solution of hydrochloric acid with a density of 1.019 g/mL?

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A solution is prepared by adding 6.24 g of benzene (C6H6, 78.11 g/mol)to 80.74 g of cyclohexane (C6H12, 84.16 g/mol).Calculate the mole fraction and molality of benzene in this solution.

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Calculate the freezing point of a solution made from 22.0 g of octane (C8H18)dissolved in 148.0 g of benzene. Benzene freezes at 5.50°C and its Kf value is 5.12°C/m.

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Which of the following aqueous solutions has the lowest freezing point?

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Oxygen gas makes up 21 % of the atmosphere by volume.What is the solubility of O2(g)in water at 25°C if the atmospheric pressure is 741 mmHg? The Henry's law constant for oxygen gas at 25°C is 1.3 * 10-3 mol/L·atm.

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When 12.1 g of the sugar sucrose (a nonelectrolyte)are dissolved in exactly 800 g of water, the solution has a freezing point of -0.082°C. What is the molar mass of sucrose? Kf of water is 1.86°C/m.

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An organic compound was prepared and purified by chromatography.A conductivity measurement showed the compound to be a nonelectrolyte.Elemental analysis gave an empirical formula of CH3O.A 0.127 g sample of the compound was dissolved in water and diluted to 100.0 mL, and the osmotic pressure of that solution was determined to 0.492 atm at 20°C. Determine the molar mass and molecular formula of the compound.(R = 0.0821 L.atm/K.mol)

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The solubility of nitrogen gas at 25°C and a nitrogen pressure of 522 mmHg is 4.7 * 10-4 mol/L. What is the value of the Henry's Law constant in mol/L·atm?

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To interconvert the concentration units molality (m)and mass percent, you must also know the density of the solution.

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