Exam 6: Thermo-Chemistry
Exam 1: Chemistry: The Study of Change153 Questions
Exam 2: Atoms, Molecules, and Ions141 Questions
Exam 3: Mass Relationships in Chemical Reactions168 Questions
Exam 4: Reactions in Aqueous Solution161 Questions
Exam 5: Gases109 Questions
Exam 6: Thermo-Chemistry111 Questions
Exam 7: Quantum Theory and the Electronic Structure of Atoms115 Questions
Exam 8: Periodic Relationships Among the Elements119 Questions
Exam 9: Chemical Bonding I: Basic Concepts118 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals122 Questions
Exam 11: Intermolecular Forces and Liquids and Solids140 Questions
Exam 12: Physical Properties of Solutions109 Questions
Exam 13: Chemical Kinetics114 Questions
Exam 14: Chemical Equilibrium100 Questions
Exam 15: Acids and Bases163 Questions
Exam 16: Acid-Base Equilibria and Solubility Equilibria110 Questions
Exam 17: Chemistry in the Atmosphere41 Questions
Exam 18: Entropy, Free Energy, and Equilibrium112 Questions
Exam 19: Electrochemistry138 Questions
Exam 20: Metallurgy and the Chemistry of Metals58 Questions
Exam 21: Nonmetallic Elements and Their Compounds41 Questions
Exam 22: Transition Metal Chemistry and Coordination Compounds80 Questions
Exam 23: Nuclear Chemistry112 Questions
Exam 24: Organic Chemistry57 Questions
Exam 25: Synthetic and Natural Organic Polymers42 Questions
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A 0.1946 g piece of magnesium metal is burned in a constant-volume calorimeter that has a heat capacity of 1349 J/°C. The calorimeter contains 500.g of water and the temperature rise is 1.40°C. Calculate the heat of combustion of magnesium metal in kJ/g, given that the specific heat of water = 4.184 J/g·°C.
(Short Answer)
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Calculate the standard enthalpy change for the reaction 2C8H18(l)+ 17O2(g) 16CO(g)+ 18H2O(l).
Given:
2C8H18(l)+ 25O2(g) 16CO2(g)+ 18H2O(l) H° = -11,020 kJ/mol
2CO(g)+ O2(g) 2CO2(g) H° = -566.0 kJ/mol
(Multiple Choice)
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Glycine, C2H5O2N, is important for biological energy. The combustion reaction of glycine is given by the equation 4C2H5O2N(s)+ 9O2(g) 8CO2(g)+ 10H2O(l)+ 2N2(g) H°rxn = -3857 kJ/mol
Given that H°f[CO2(g)] = -393.5 kJ/mol and H°f[H2O(l)] = -285.8 kJ/mol, calculate the enthalpy of formation of glycine.
(Multiple Choice)
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The heat of solution of ammonium chloride is 15.2 kJ/mol. If a 6.134 g sample of NH4Cl is added to 65.0 mL of water in a calorimeter at 24.5°C, what is the minimum temperature reached by the solution? (The specific heat of water = 4.18 J/g·°C; the heat capacity of the calorimeter = 365.J/°C.)
(Multiple Choice)
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Given the following H° values,
H2(g)+
O2(g) H2O(l) H°f = -285.8 kJ/mol
H2O2(l) H2(g)+ O2(g) H°rxn = 187.6 kJ/mol
calculate H°rxn for the reaction H2O2(l) H2O(l)+
O2(g),
(Short Answer)
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The total heat of hydration of 1 mol of gas phase Li+ ions and Cl - ions is -865 kJ. The lattice energy of LiCl(s)is 828 kJ/mol. Calculate the heat of solution of LiCl.
(Multiple Choice)
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Calculate the amount of work done against an atmospheric pressure of 1.00 atm when 500.0 g of zinc dissolves in excess acid at 30.0°C. Zn(s)+ 2H+(aq) Zn2+(aq)+ H2(g)
(Multiple Choice)
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Ozone (O3)in the atmosphere can be converted to oxygen gas by reaction with nitric oxide (NO). Nitrogen dioxide is also produced in the reaction. What is the enthalpy change when 8.50L of ozone at a pressure of 1.00 atm and 25°C reacts with 12.00 L of nitric oxide at the same initial pressure and temperature? [ H°f(NO)= 90.4 kJ/mol; H°f(NO2)= 33.85 kJ/mol; H°f(O3)= 142.2 kJ/mol]
(Multiple Choice)
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Calculate the standard enthalpy change for the reaction 2C8H18(l)+ 21O2(g) 8CO(g)+ 8CO2(g)+ 18H2O(l).
Given:
2C8H18(l)+ 25O2(g) 16CO2(g)+ 18H2O(l) H° = -11,020 kJ/mol
2CO(g)+ O2(g) 2CO2(g) H° = -566.0 kJ/mol
(Multiple Choice)
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A 26.2 g piece of copper metal is heated from 21.5°C to 201.6°C. Calculate the amount of heat absorbed by the metal. The specific heat of Cu is 0.385 J/g·°C.
(Short Answer)
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How many grams of ethylene (C2H4)would have to be burned to produce 450 kJ of heat?
C2H4(g)+ 3O2(g) 2CO2(g)+ H2O(l) H°rxn = -1411 kJ/mol
(Short Answer)
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Suppose a 50.0 g block of silver (specific heat = 0.2350 J/g·°C)at 100°C is placed in contact with a 50.0 g block of iron (specific heat = 0.4494 J/g·°C)at 0°C, and the two blocks are insulated from the rest of the universe. The final temperature of the two blocks
(Multiple Choice)
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A gas is compressed in a cylinder from a volume of 20.0 L to 2.0 L by a constant pressure of 10.0 atm.Calculate the amount of work done on the system.
(Multiple Choice)
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If 325 g of water at 4.2°C absorbs 12.28 kJ, what is the final temperature of the water? The specific heat of water is 4.184 J/g·°C.
(Multiple Choice)
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Octane (C8H18)undergoes combustion according to the following thermochemical equation: 2C8H18(l)+ 25O2(g) 16CO2(g)+ 18H2O(l) H°rxn = -11,020 kJ/mol.
Given that H°f[CO2(g)] = -393.5 kJ/mol and H°f[H2O(l)] = -285.8 kJ/mol, calculate the standard enthalpy of formation of octane.
(Multiple Choice)
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Styrene, C8H8, is one of the substances used in the production of synthetic rubber. When styrene burns in oxygen to form carbon dioxide and liquid water under standard-state conditions at 25°C, 42.62 kJ are released per gram of styrene. Find the standard enthalpy of formation of styrene at 25°C. (Given: H°f[CO2(g)] = -393.5 kJ/mol, H°f[H2O(l)] = -285.8 kJ/mol, H°f[H2O(g)] = -241.8 kJ/mol)
(Multiple Choice)
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When an automobile engine starts, the metal parts immediately begin to absorb heat released during the combustion of gasoline. How much heat will be absorbed by a 165 kg iron engine block as the temperature rises from 15.7°C to 95.7°C? (The specific heat of iron is 0.489 J/g·°C.)
(Short Answer)
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