Exam 6: Thermo-Chemistry

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A 0.1946 g piece of magnesium metal is burned in a constant-volume calorimeter that has a heat capacity of 1349 J/°C. The calorimeter contains 500.g of water and the temperature rise is 1.40°C. Calculate the heat of combustion of magnesium metal in kJ/g, given that the specific heat of water = 4.184 J/g·°C.

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Calculate the standard enthalpy change for the reaction 2C8H18(l)+ 17O2(g) →\rarr 16CO(g)+ 18H2O(l). Given: 2C8H18(l)+ 25O2(g) →\rarr 16CO2(g)+ 18H2O(l) Δ\Delta H° = -11,020 kJ/mol 2CO(g)+ O2(g) →\rarr 2CO2(g) Δ\Delta H° = -566.0 kJ/mol

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Glycine, C2H5O2N, is important for biological energy. The combustion reaction of glycine is given by the equation 4C2H5O2N(s)+ 9O2(g) →\rarr 8CO2(g)+ 10H2O(l)+ 2N2(g) Δ\Delta H°rxn = -3857 kJ/mol Given that Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol and Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, calculate the enthalpy of formation of glycine.

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The heat of solution of ammonium chloride is 15.2 kJ/mol. If a 6.134 g sample of NH4Cl is added to 65.0 mL of water in a calorimeter at 24.5°C, what is the minimum temperature reached by the solution? (The specific heat of water = 4.18 J/g·°C; the heat capacity of the calorimeter = 365.J/°C.)

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Radiant energy is

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Given the following Δ\Delta H° values, H2(g)+  Given the following  \Delta H° values, H<sub>2</sub>(g)+   O<sub>2</sub>(g) \rarr H<sub>2</sub>O(l) \Delta H°<sub>f</sub> = -285.8 kJ/mol H<sub>2</sub>O<sub>2</sub>(l) \rarr H<sub>2</sub>(g)+ O<sub>2</sub>(g) \Delta H°<sub>rxn</sub> = 187.6 kJ/mol calculate  \Delta H°<sub>rxn</sub> for the reaction H<sub>2</sub>O<sub>2</sub>(l) \rarr  H<sub>2</sub>O(l)+   O<sub>2</sub>(g), O2(g) →\rarr H2O(l) Δ\Delta H°f = -285.8 kJ/mol H2O2(l) →\rarr H2(g)+ O2(g) Δ\Delta H°rxn = 187.6 kJ/mol calculate Δ\Delta H°rxn for the reaction H2O2(l) →\rarr H2O(l)+  Given the following  \Delta H° values, H<sub>2</sub>(g)+   O<sub>2</sub>(g) \rarr H<sub>2</sub>O(l) \Delta H°<sub>f</sub> = -285.8 kJ/mol H<sub>2</sub>O<sub>2</sub>(l) \rarr H<sub>2</sub>(g)+ O<sub>2</sub>(g) \Delta H°<sub>rxn</sub> = 187.6 kJ/mol calculate  \Delta H°<sub>rxn</sub> for the reaction H<sub>2</sub>O<sub>2</sub>(l) \rarr  H<sub>2</sub>O(l)+   O<sub>2</sub>(g), O2(g),

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An exothermic reaction causes the surroundings to

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The total heat of hydration of 1 mol of gas phase Li+ ions and Cl - ions is -865 kJ. The lattice energy of LiCl(s)is 828 kJ/mol. Calculate the heat of solution of LiCl.

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Calculate the amount of work done against an atmospheric pressure of 1.00 atm when 500.0 g of zinc dissolves in excess acid at 30.0°C. Zn(s)+ 2H+(aq) →\rarr Zn2+(aq)+ H2(g)

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Ozone (O3)in the atmosphere can be converted to oxygen gas by reaction with nitric oxide (NO). Nitrogen dioxide is also produced in the reaction. What is the enthalpy change when 8.50L of ozone at a pressure of 1.00 atm and 25°C reacts with 12.00 L of nitric oxide at the same initial pressure and temperature? [ Δ\Delta H°f(NO)= 90.4 kJ/mol; Δ\Delta H°f(NO2)= 33.85 kJ/mol; Δ\Delta H°f(O3)= 142.2 kJ/mol]

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Calculate the standard enthalpy change for the reaction 2C8H18(l)+ 21O2(g) →\rarr 8CO(g)+ 8CO2(g)+ 18H2O(l). Given: 2C8H18(l)+ 25O2(g) →\rarr 16CO2(g)+ 18H2O(l) Δ\Delta H° = -11,020 kJ/mol 2CO(g)+ O2(g) →\rarr 2CO2(g) Δ\Delta H° = -566.0 kJ/mol

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In an endothermic process, heat is absorbed by the system.

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A 26.2 g piece of copper metal is heated from 21.5°C to 201.6°C. Calculate the amount of heat absorbed by the metal. The specific heat of Cu is 0.385 J/g·°C.

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How many grams of ethylene (C2H4)would have to be burned to produce 450 kJ of heat? C2H4(g)+ 3O2(g) →\rarr 2CO2(g)+ H2O(l) Δ\Delta H°rxn = -1411 kJ/mol

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Suppose a 50.0 g block of silver (specific heat = 0.2350 J/g·°C)at 100°C is placed in contact with a 50.0 g block of iron (specific heat = 0.4494 J/g·°C)at 0°C, and the two blocks are insulated from the rest of the universe. The final temperature of the two blocks

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A gas is compressed in a cylinder from a volume of 20.0 L to 2.0 L by a constant pressure of 10.0 atm.Calculate the amount of work done on the system.

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If 325 g of water at 4.2°C absorbs 12.28 kJ, what is the final temperature of the water? The specific heat of water is 4.184 J/g·°C.

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Octane (C8H18)undergoes combustion according to the following thermochemical equation: 2C8H18(l)+ 25O2(g) →\rarr 16CO2(g)+ 18H2O(l) Δ\Delta H°rxn = -11,020 kJ/mol. Given that Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol and Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, calculate the standard enthalpy of formation of octane.

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Styrene, C8H8, is one of the substances used in the production of synthetic rubber. When styrene burns in oxygen to form carbon dioxide and liquid water under standard-state conditions at 25°C, 42.62 kJ are released per gram of styrene. Find the standard enthalpy of formation of styrene at 25°C. (Given: Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol, Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, Δ\Delta H°f[H2O(g)] = -241.8 kJ/mol)

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When an automobile engine starts, the metal parts immediately begin to absorb heat released during the combustion of gasoline. How much heat will be absorbed by a 165 kg iron engine block as the temperature rises from 15.7°C to 95.7°C? (The specific heat of iron is 0.489 J/g·°C.)

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