Exam 9: Chemical Bonding I: Basic Concepts

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Write a Lewis structure for the phosphate ion, PO43-, that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for PO43- that obey the octet rule.

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The total number of lone pairs in NCl3 is

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The formal charge on the sulfur atom in the resonance structure of sulfur dioxide which has one single bond and one double bond is

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Which one of the following is most likely to be a covalent compound?

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Which of the bonds below would have the greatest polarity (i.e., highest percent ionic character)?

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Write a Lewis structure for the nitrate ion, NO3-, showing all non-zero formal charges.

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Each of the three resonance structures of NO3- has how many lone pairs of electrons?

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Write a Lewis structure for the chlorite ion, ClO2-, that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for ClO2- that obey the octet rule.

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Which one of the following compounds utilizes both ionic and covalent bonding?

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For which of these species does the best Lewis structure have two or more equivalent resonance structures?

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Use the bond enthalpy data given to estimate the heat released when 6.50 g of nitrogen gas reacts with excess hydrogen gas to form ammonia at 25°C. BE(N ≡\equiv N)= 941.4 kJ/mol BE(H-H)= 436.4 kJ/mol BE(N-H)= 393 kJ/mol

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What is total number of lone pairs in the best Lewis structure for SOF4 that exceeds the octet rule (S is the central atom)?

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The total number of valence electrons in the ion NH4+ is

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Dichloromethane, CH2Cl2, is an important solvent in synthetic chemistry.Write a Lewis structure for CH2Cl2.

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Write a Lewis structure for the chlorate ion, ClO3-, that obeys the octet rule, showing all non-zero formal charges, and give the total number of resonance structures for ClO3- that obey the octet rule.

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Which one of the following molecules has an atom with an expanded octet?

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Use the Born-Haber cycle to calculate the standard enthalpy of formation ( Δ\Delta H  Use the Born-Haber cycle to calculate the standard enthalpy of formation ( \Delta H   <sub> </sub> )for LiCl(s)given the following data:  \Delta H(sublimation)Li = 155.2 kJ/mol I<sub>1</sub> (Li)= 520 kJ/mol Bond energy (Cl-Cl)= 242.7 kJ/mol EA (Cl)= 349 kJ/mol Lattice energy (LiCl(s))= 828 kJ/mol )for LiCl(s)given the following data: Δ\Delta H(sublimation)Li = 155.2 kJ/mol I1 (Li)= 520 kJ/mol Bond energy (Cl-Cl)= 242.7 kJ/mol EA (Cl)= 349 kJ/mol Lattice energy (LiCl(s))= 828 kJ/mol

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Classify the Ca - Cl bond in CaCl2 as ionic, polar covalent, or nonpolar covalent.

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Use the bond enthalpy data given to estimate the heat released when 25.0 g of acetylene gas, C2H2, burns in excess oxygen to yield carbon dioxide and water vapor at 25°C. BE(C-C)= 347 kJ/mol BE(C=C)= 812 kJ/mol BE(C=O in CO2)= 799 kJ/mol BE(C-H)= 414 kJ/mol BE(O-H)= 460 kJ/mol BE(O=O)= 498.7 kJ/mol

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Write the Lewis structure for the product that forms when boron trifluoride combines with ammonia.

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