Exam 15: Chemical Equilibrium
Exam 1: Introduction153 Questions
Exam 2: Atoms, Molecules, and Ions141 Questions
Exam 3: Stoichiometry168 Questions
Exam 4: Reactions in Aqueous Solution156 Questions
Exam 5: Gases109 Questions
Exam 6: Energy Relationships in Chemical Reactions105 Questions
Exam 7: The Electronic Structure of Atoms115 Questions
Exam 8: The Periodic Table119 Questions
Exam 9: Chemical Bonding I: the Covalent Bond118 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals120 Questions
Exam 11: Introduction to Organic Chemistry57 Questions
Exam 12: Intermolecular Forces and Liquids and Solids138 Questions
Exam 13: Physical Properties of Solutions109 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium99 Questions
Exam 16: Acids and Bases163 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria92 Questions
Exam 18: Thermodynamics112 Questions
Exam 19: Redox Reactions and Electrochemistry138 Questions
Exam 20: The Chemistry of Coordination Compounds76 Questions
Exam 21: Nuclear Chemistry112 Questions
Exam 22: Organic Polymerssynthetic and Natural42 Questions
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Consider the following equilibrium,
4NH3(g)+ 3O2(g)
2N2(g)+ 6H2O(g)+ 1531 kJ
State whether the concentrations of the products would increase, decrease, or remain constant after ammonia was added to the system.
(Short Answer)
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Consider the following reactions and their associated equilibrium constants: A + 2B
C K1
C 11ec7153_74a6_4277_88eb_656263c228fc_TB3244_11 D + E K2
For the reaction A + 2B D + E, having equilibrium constant Kc,
(Multiple Choice)
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When the reaction 2H2S(g)
2H2(g)+ S2(g)is carried out at 1065°C, Kp = 0.012. Starting with pure H2S at 1065°, what must the initial pressure of H2S be if the equilibrated mixture at this temperature is to contain 0.250 atm of H2(g)?
(Multiple Choice)
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Ethanol and acetic acid react to form ethyl acetate and water according to the following chemical equation:
C2H5OH(l)+ CH3COOH(l)
CH3COOC2H5(l)+ H2O(l)
When two moles each of ethanol and acetic acid are combined, equilibrium is reached when two-thirds of a mole of each of the reactants remains. Calculate the equilibrium constant for this reaction assuming total volume does not change during the course of the reaction. (Note: since water is not the solvent, but rather a product of the reaction, [H2O] changes during the course of the reaction, so it should be included in the equilibrium constant expression.)
(Short Answer)
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The equilibrium constant for the chemical equation
2NO(g)+ O2(g)
2NO2(g)
is two times the equilibrium constant for the chemical equation
NO(g)+ 1/2O2(g)
NO2(g).
(True/False)
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If one starts with pure NO2(g)at a pressure of 0.500 atm, the total pressure inside the reaction vessel when 2NO2(g)
2NO(g)+ O2(g)reaches equilibrium is 0.674 atm. Calculate the equilibrium partial pressure of NO2.
(Multiple Choice)
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For the nitrogen fixation reaction 3H2(g)+ N2(g)
2NH3(g), Kc = 6.0 * 10-2 at 500°C. If 0.250 M H2 and 0.050 M NH3 are present at equilibrium, what is the equilibrium concentration of N2?
(Multiple Choice)
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At 700 K, the reaction 2SO2(g)+ O2(g)
2SO3(g)has the equilibrium constant Kc = 4.3 * 106 , and the following concentrations are present: [SO2] = 0.10 M; [SO3] = 10. M; [O2] = 0.10 M. Is the mixture at equilibrium? If not at equilibrium, in which direction (as the equation is written), left to right or right to left, will the reaction proceed to reach equilibrium?
(Multiple Choice)
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Consider the following equilibria: 2SO3(g)
2SO2(g)+ O2(g)Kc = 2.3 * 10-7
2NO3(g) 11ec7153_74a6_4277_88eb_656263c228fc_TB3244_11 2NO2(g)+ O2(g)Kc = 1.4 * 10-3
Calculate the equilibrium constant for the reaction
SO2(g)+ NO3(g) SO3(g)+ NO2(g)
(Multiple Choice)
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Consider the following equilibrium,
4NH3(g)+ 3O2(g)
2N2(g)+ 6H2O(g)+ 1531 kJ
State whether the concentrations of the reactants would increase, decrease, or remain constant after ammonia was added to the system.
(Short Answer)
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At 250ºC, the equilibrium constant Kp for the reaction PCl5(g)
PCl3(g)+ Cl2(g)is 1.80. Sufficient PCl5 is put into a reaction vessel to give an initial pressure of 2.74 atm at 250ºC. Calculate the pressure of PCl5 after the system has reached equilibrium.
(Multiple Choice)
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Kp for the reaction of SO2(g)with O2 to produce SO3(g)is 3 * 1024 . Calculate Kc for this equilibrium at 25ºC. (The relevant reaction is 2SO2(g)+ O2(g)
2SO3(g).)
(Multiple Choice)
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The data below refer to the following reaction:
2NO(g)+ Br2(g)
2NOBr(g)
Find the concentration of NOBr when the system reaches equilibrium.
(Short Answer)
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Sodium carbonate, Na2CO3(s), can be prepared by heating sodium bicarbonate, NaHCO3(s). 2NaHCO3(s)
Na2CO3(s)+ CO2(g)+ H2O(g)Kp = 0.23 at 100ºC
If a sample of NaHCO3 is placed in an evacuated flask and allowed to achieve equilibrium at 100ºC, what will the total gas pressure be?
(Multiple Choice)
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For the common allotropes of carbon (graphite and diamond), C(gr) C(dia)with equilibrium constant K = 0.32. The molar volumes of graphite and diamond are, respectively, 5.30 cm3/mol and 3.42 cm3/mol; Hf of diamond is 1.90 kJ/mol. This data suggests that the formation of diamond is favored at
(Multiple Choice)
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Consider the following equilibrium,
4NH3(g)+ 3O2(g)
2N2(g)+ 6H2O(g)+ 1531 kJ
State whether the concentrations of the products would increase, decrease, or remain constant after nitrogen gas was removed from the system.
(Short Answer)
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Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide.
CaCO3(s)
CaO(s)+ CO2(g)
KP for this reaction is 1.16 at 800°C. A 5.00 L vessel containing 10.0 g of CaCO3(s)was evacuated to remove the air, sealed, and then heated to 800°C. Ignoring the volume occupied by the solid, what will be the mass of the solid in the vessel once equilibrium is reached?
(Short Answer)
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The reaction A(g)+ 2B(g)
C(g)was allowed to come to equilibrium. The initial amounts of reactants placed into a 5.00 L vessel were 1.0 mol A and 1.8 mol B. After the reaction reached equilibrium, 1.0 mol of B was found. Calculate Kc for this reaction.
(Multiple Choice)
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Consider the following equilibrium,
4NH3(g)+ 3O2(g)
2N2(g)+ 6H2O(g)+ 1531 kJ
State whether the concentrations of the reactants would increase, decrease, or remain constant when the temperature is increased.
(Short Answer)
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