Exam 17: Acid-Base Equilibria and Solubility Equilibria
Exam 1: Introduction153 Questions
Exam 2: Atoms, Molecules, and Ions141 Questions
Exam 3: Stoichiometry168 Questions
Exam 4: Reactions in Aqueous Solution156 Questions
Exam 5: Gases109 Questions
Exam 6: Energy Relationships in Chemical Reactions105 Questions
Exam 7: The Electronic Structure of Atoms115 Questions
Exam 8: The Periodic Table119 Questions
Exam 9: Chemical Bonding I: the Covalent Bond118 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals120 Questions
Exam 11: Introduction to Organic Chemistry57 Questions
Exam 12: Intermolecular Forces and Liquids and Solids138 Questions
Exam 13: Physical Properties of Solutions109 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium99 Questions
Exam 16: Acids and Bases163 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria92 Questions
Exam 18: Thermodynamics112 Questions
Exam 19: Redox Reactions and Electrochemistry138 Questions
Exam 20: The Chemistry of Coordination Compounds76 Questions
Exam 21: Nuclear Chemistry112 Questions
Exam 22: Organic Polymerssynthetic and Natural42 Questions
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Which response has both answers correct? Will a precipitate form when 250 mL of 0.33 M Na2CrO4 are added to 250 mL of 0.12 M AgNO3? [Ksp(Ag2CrO4)= 1.1 * 10-12] What is the concentration of the silver ion remaining in solution?
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A
Calculate the pH at the equivalence point for the titration of 0.20 M HCl with 0.20 M NH3 (Kb = 1.8 * 10-5).
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Correct Answer:
C
All indicators are weak acids that are one color in acidic solution and another color in basic solution.
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(True/False)
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Correct Answer:
False
Acid dissociation constants for phosphoric acid are given below.
A buffer with a pH = 7.4 can best be made by using
(Multiple Choice)
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Describe how to prepare 500. mL of a cyanic acid (HCNO)/sodium cyanate (NaCNO)buffer having a pH of 4.80. [Ka(HCNO)= 2.0 * 10-4]
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Will a precipitate of magnesium fluoride form when 300. mL of 1.1 * 10-3 M MgCl2 are added to 500. mL of 1.2 * 10-3 M NaF? [Ksp (MgF2)= 6.9 * 10-9]
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The solubility product for chromium(III)fluoride is Ksp = 6.6 * 10-11. What is the molar solubility of chromium(III)fluoride?
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Write an equation showing the net reaction that occurs when a strong base is added to a CO32-/HCO3- buffer solution (for carbonic acid, Ka1 = 4.2 * 10-7, Ka2 = 2.4 * 10-8):
(Essay)
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You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH)and 0.30 M sodium acetate (CH3COONa). What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka = 1.8 * 10-5]
(Multiple Choice)
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Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of cyanic acid (HCNO)and 0.80 mole of sodium cyanate (NaCNO)in enough water to make 1.0 liter of solution. [Ka(HCNO)= 2.0 * 10-4]
(Multiple Choice)
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Calculate the concentration of chloride ions in a saturated lead(II)chloride (Ksp = 2.4 * 10-4)solution.
(Multiple Choice)
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Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III)fluoride. (For CrF3 , Ksp = 6.6 * 10-11.)
(Multiple Choice)
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The solubility of strontium carbonate is 0.0011 g/100 mL at 20oC. Calculate the Ksp value for this compound.
(Multiple Choice)
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What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCN (Ka = 4.9 * 10-10)with 0.10 M NaOH?
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Describe how to make a sodium formate (HCOONa)/formic acid (HCOOH)buffer that has a pH of 4.77.
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The solubility of Ba(NO3)2 is 130.5 g/L at 0oC. How many moles of dissolved salt are present in 4.0 L of a saturated solution of Ba(NO3)2 at 0oC?
(Short Answer)
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A mixture made from 10 mL of 1 M HCl and 20 mL of 1 M CH3COONa would be classified as a buffer solution.
(True/False)
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Will a precipitate of AgCl form when 0.050 mol NaCl(s)and 0.050 mol AgNO3(s)are dissolved in 500. mL of 3.0 M NH3? [Kf for Ag(NH3)2+ is 1.5 * 107; Ksp(AgCl)= 1.6 * 10-10]
(Short Answer)
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To 1.00 L of a 0.100 M aqueous solution of benzoic acid (C6H5COOH)is added 1.00 mL of 12.0 M HCl. What is the percentage ionization of the benzoic acid in the resulting solution? [Ka(C6H5COOH)= 6.5 * 10-5]
(Multiple Choice)
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Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 * 10-10)solution.
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