Exam 17: Acid-Base Equilibria and Solubility Equilibria

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Which response has both answers correct? Will a precipitate form when 250 mL of 0.33 M Na2CrO4 are added to 250 mL of 0.12 M AgNO3? [Ksp(Ag2CrO4)= 1.1 * 10-12] What is the concentration of the silver ion remaining in solution?

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A

Calculate the pH at the equivalence point for the titration of 0.20 M HCl with 0.20 M NH3 (Kb = 1.8 * 10-5).

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C

All indicators are weak acids that are one color in acidic solution and another color in basic solution.

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Acid dissociation constants for phosphoric acid are given below. Acid dissociation constants for phosphoric acid are given below.   A buffer with a pH = 7.4 can best be made by using A buffer with a pH = 7.4 can best be made by using

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Describe how to prepare 500. mL of a cyanic acid (HCNO)/sodium cyanate (NaCNO)buffer having a pH of 4.80. [Ka(HCNO)= 2.0 * 10-4]

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Will a precipitate of magnesium fluoride form when 300. mL of 1.1 * 10-3 M MgCl2 are added to 500. mL of 1.2 * 10-3 M NaF? [Ksp (MgF2)= 6.9 * 10-9]

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The solubility product for chromium(III)fluoride is Ksp = 6.6 * 10-11. What is the molar solubility of chromium(III)fluoride?

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Write an equation showing the net reaction that occurs when a strong base is added to a CO32-/HCO3- buffer solution (for carbonic acid, Ka1 = 4.2 * 10-7, Ka2 = 2.4 * 10-8):

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You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH)and 0.30 M sodium acetate (CH3COONa). What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka = 1.8 * 10-5]

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Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of cyanic acid (HCNO)and 0.80 mole of sodium cyanate (NaCNO)in enough water to make 1.0 liter of solution. [Ka(HCNO)= 2.0 * 10-4]

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Calculate the concentration of chloride ions in a saturated lead(II)chloride (Ksp = 2.4 * 10-4)solution.

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Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III)fluoride. (For CrF3 , Ksp = 6.6 * 10-11.)

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The solubility of strontium carbonate is 0.0011 g/100 mL at 20oC. Calculate the Ksp value for this compound.

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What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCN (Ka = 4.9 * 10-10)with 0.10 M NaOH?

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Describe how to make a sodium formate (HCOONa)/formic acid (HCOOH)buffer that has a pH of 4.77.

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The solubility of Ba(NO3)2 is 130.5 g/L at 0oC. How many moles of dissolved salt are present in 4.0 L of a saturated solution of Ba(NO3)2 at 0oC?

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A mixture made from 10 mL of 1 M HCl and 20 mL of 1 M CH3COONa would be classified as a buffer solution.

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Will a precipitate of AgCl form when 0.050 mol NaCl(s)and 0.050 mol AgNO3(s)are dissolved in 500. mL of 3.0 M NH3? [Kf for Ag(NH3)2+ is 1.5 * 107; Ksp(AgCl)= 1.6 * 10-10]

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To 1.00 L of a 0.100 M aqueous solution of benzoic acid (C6H5COOH)is added 1.00 mL of 12.0 M HCl. What is the percentage ionization of the benzoic acid in the resulting solution? [Ka(C6H5COOH)= 6.5 * 10-5]

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Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 * 10-10)solution.

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