Exam 17: Acid-Base Equilibria and Solubility Equilibria

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Will a precipitate (ppt)form when 300. mL of 5.0 * 10-5 M AgNO3 are added to 200. mL of 2.5 * 10-7 M NaBr? Answer yes or no, and identify the precipitate if there is one.

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Will a precipitate (ppt)form when 300. mL of 2.0 * 10-5 M AgNO3 are added to 200. mL of 2.5 * 10-9 M NaI? Answer yes or no, and identify the precipitate if there is one.

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Consider a buffer solution prepared from HOCl and NaOCl. Which is the net ionic equation for the reaction that occurs when NaOH is added to this buffer?

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What mass of sodium fluoride must be added to 250. mL of a 0.100 M HF solution to give a buffer solution having a pH of 3.50? [Ka(HF)= 7.1 * 10-4]

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For which type of titration will the pH be basic at the equivalence point?

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Calculate the pH of a solution that is 0.15 M CH3COOH and 0.75 M CH3COONa.

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How many moles of NaF must be dissolved in 1.00 liter of a saturated solution of PbF2 at 25°C to reduce the [Pb2+] to 1.0 * 10-6 M? The Ksp for PbF2 at 25 °C is 4.0 * 10-8.

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For PbCl2 (Ksp = 2.4 * 10-4), will a precipitate of PbCl2 form when 0.10 L of 3.0 * 10-2 M Pb(NO3)2 is added to 400 mL of 9.0 * 10-2 M NaCl?

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Calculate the percent ionization of cyanic acid, Ka = 2.0 * 10-4, in a buffer solution that is 0.50 M HCNO and 0.10 M NaCNO.

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Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of sodium cyanate (NaCNO)and 1.0 mole of cyanic acid (HCNO)in enough water to make 1.0 liter of solution. [Ka(HCNO)= 2.0 * 10-4]

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The Ksp of CaF2 is 4 * 10-11. What is the maximum concentration of Ca2+ possible in a 0.10 M NaF solution?

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The Ksp for silver(I)phosphate is 1.8 * 10-18. Determine the silver ion concentration in a saturated solution of silver(I)phosphate.

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