Exam 17: Acid-Base Equilibria and Solubility Equilibria

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NaCl is added slowly to a solution that is 0.010 M each in Cu+, Ag+, and Au+. The Ksp's for CuCl, AgCl, and AuCl are 1.9 * 10-7, 1.8 * 10-10, and 2.0 * 10-13, respectively. Which compound will precipitate first?

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Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 9.2-9.3?

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Will a precipitate of magnesium fluoride form when 200. mL of 1.9 * 10-3 M MgCl2 are added to 300. mL of 1.4 * 10-2 M NaF? [Ksp (MgF2)= 6.9 * 10-9]

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Calculate the silver ion concentration in a saturated solution of silver(I)carbonate (Ksp = 8.1 * 10-12).

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What is the net ionic equation for the reaction that occurs when small amounts of hydrochloric acid are added to a HOCl/NaOCl buffer solution?

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You are asked to go into the lab and prepare an acetic acid - sodium acetate buffer solution with a pH of 4.00 ± 0.02. What molar ratio of CH3COOH to CH3COONa should be used?

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The molar solubility of tin(II)iodide is 1.28 * 10-2 mol/L. What is Ksp for this compound?

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The molar solubility of magnesium carbonate is 1.8 * 10-4 mol/L. What is Ksp for this compound?

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Assuming equal concentrations of conjugate base and acid, which one of the following mixtures is suitable for making a buffer solution with an optimum pH of 4.6-4.8?

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A saturated sodium carbonate solution at 100°C contains 45.5 g of dissolved sodium carbonate per 100. mL of solution. The solubility product constant for sodium carbonate at this temperature is

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The solubility of a salt increases as its Ksp increases.

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An environmental chemist obtained a 200. mL sample of lake water believed to be contaminated with a single monoprotic strong acid. Titrating this sample with a 0.0050 M NaOH(aq)required 7.3 mL of the NaOH solution to reach the endpoint. What is the pH of the lake?

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A solution is prepared by mixing 500. mL of 0.10 M NaOCl and 500. mL of 0.20 M HOCl. What is the pH of this solution? [Ka(HOCl)= 3.2 * 10-8]

(Multiple Choice)
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A 50.0 mL sample of 2.0 * 10-4 M CuNO3 is added to 50.0 mL of 4.0 M NaCN. The formation constant of the complex ion Cu(CN)32- is 1.0 * 109. What is the copper(I)ion concentration in this system at equilibrium?

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Write an equation showing the net reaction that occurs when a strong acid is added to a CO32-/HCO3- buffer solution (for carbonic acid, Ka1 = 4.2 * 10-7, Ka2 = 2.4 * 10-8):

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What mass of ammonium nitrate must be added to 350. mL of a 0.150 M solution of ammonia to give a buffer having a pH of 9.00? (Kb(NH3)= 1.8 * 10-5)

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Which of the following would decrease the Ksp for PbI2?

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The solubility product for calcium phosphate is Ksp = 1.3 * 10-26. What is the molar solubility of calcium phosphate?

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Find the concentration of calcium ions in a solution made by adding 3.50 g of calcium fluoride to 750. mL of 0.125 M NaF. [For CaF2, Ksp = 3.95 * 10-11.]

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What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCl with 0.10 M NaOH?

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