Exam 15: Chemical Equilibrium
Exam 1: Introduction153 Questions
Exam 2: Atoms, Molecules, and Ions141 Questions
Exam 3: Stoichiometry168 Questions
Exam 4: Reactions in Aqueous Solution156 Questions
Exam 5: Gases109 Questions
Exam 6: Energy Relationships in Chemical Reactions105 Questions
Exam 7: The Electronic Structure of Atoms115 Questions
Exam 8: The Periodic Table119 Questions
Exam 9: Chemical Bonding I: the Covalent Bond118 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals120 Questions
Exam 11: Introduction to Organic Chemistry57 Questions
Exam 12: Intermolecular Forces and Liquids and Solids138 Questions
Exam 13: Physical Properties of Solutions109 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium99 Questions
Exam 16: Acids and Bases163 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria92 Questions
Exam 18: Thermodynamics112 Questions
Exam 19: Redox Reactions and Electrochemistry138 Questions
Exam 20: The Chemistry of Coordination Compounds76 Questions
Exam 21: Nuclear Chemistry112 Questions
Exam 22: Organic Polymerssynthetic and Natural42 Questions
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Hydrogen iodide decomposes according to the equation:
2HI(g)
H2(g)+ I2(g), Kc = 0.0156 at 400ºC
A 0.660 mol sample of HI was injected into a 2.00 L reaction vessel held at 400ºC.
Calculate the concentration of H2 equilibrium.
(Short Answer)
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Kc for the reaction CO2(g)+ H2(g)
H2O(g)+ CO(g)is 1.6 at about 990ºC.Calculate the number of moles of carbon monoxide in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.
(Short Answer)
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At 400ºC, Kc = 64 for the equilibrium H2(g)+ I2(g)
2HI(g). If 3.00 mol H2 and 3.00 mol I2 are introduced into an empty 4.0 L vessel, find the equilibrium concentration of HI at 400ºC.
(Multiple Choice)
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Consider the two gaseous equilibria: SO2(g)+ 1/2O2(g)
SO3(g)K1
2SO3(g)
SO2(g)+ O2(g)K2
The values of the equilibrium constants K1 and K2 are related by
(Multiple Choice)
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A solution was prepared such that the initial concentrations of Cu2+(aq)and CN-(aq)were 0.0120 M and 0.0400 M, respectively. These ions react according to the following chemical equation
Cu2+(aq)+ 4CN-(aq)
Cu(CN)42-(aq)Kc = 1.0 * 1025
What will be the concentration of Cu2+(aq)at equilibrium?
(Short Answer)
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The reaction 2NO(g)
N2(g)+ O2(g)is exothermic, Hºrxn = -180 kJ/mol. Which one of these statements is true?
(Multiple Choice)
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Describe why addition of a catalyst does not affect the equilibrium constant for a reaction.
(Essay)
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Consider the equilibrium equation C(s)+ H2O(g)+ 2296 J
CO(g)+ H2(g). If additional gaseous water is added to this reaction mixture, what will happen to the temperature of the mixture?
(Short Answer)
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On analysis, an equilibrium mixture for the reaction 2H2S(g)
2H2(g)+ S2(g)was found to contain 1.0 mol H2S, 4.0 mol H2, and 0.80 mol S2 in a 4.0 L vessel. Calculate the equilibrium constant, Kc, for this reaction.
(Multiple Choice)
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Consider the equilibrium equation C(s)+ H2O(g)+ 2296 J
CO(g)+ H2(g). What will happen to the mass of carbon if we add gaseous water to the system?
(Short Answer)
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What is the correct equilibrium constant expression for this reaction?
2HI(g)
H2(g)+ I2(g)
(Essay)
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For the equilibrium reaction 2SO2(g)+ O2(g)
2SO3(g), Hºrxn = -198 kJ/mol. Which one of these factors would cause the equilibrium constant to increase?
(Multiple Choice)
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In which of these gas-phase equilibria is the yield of products increased by increasing the total pressure on the reaction mixture?
(Multiple Choice)
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The following reactions occur at 500 K. Arrange them in order of increasing tendency to proceed to completion (least completion greatest completion).
1)2NOCl
2NO + Cl2 Kp = 1.7 * 10- 2
2)N2O4 11ec7153_21b4_20f5_88eb_03ce8bf4f194_TB3244_11 2NO2 Kp = 1.5 * 103
3)2SO3 11ec7153_21b4_20f5_88eb_03ce8bf4f194_TB3244_11 2SO2 + O2 Kp = 1.3 * 10 -5
4)2NO2 11ec7153_21b4_20f5_88eb_03ce8bf4f194_TB3244_11 2NO + O2 Kp = 5.9 * 10 -5
(Multiple Choice)
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Consider the following equilibrium,
4NH3(g)+ 3O2(g)
2N2(g)+ 6H2O(g)+ 1531 kJ
State whether the concentrations of the reactants would increase, decrease, or remain constant after nitrogen gas was removed from the system.
(Short Answer)
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Consider the chemical reaction 2NH3(g)
N2(g)+ 3H2(g). The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 * 10-2. Initially, 1,220 moles of NH3(g)are present. Estimate the equilibrium concentration of H2(g).
(Short Answer)
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The data below refer to the following reaction:
2NO(g)+ Br2(g)
2NOBr(g)
Calculate Kc.
(Short Answer)
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Two moles of PCl5 are placed in a 5.0 L container. Dissociation takes place according to the equation PCl5 (g)
PCl3(g)+ Cl2(g). At equilibrium, 0.40 mol of Cl2 are present. Calculate the equilibrium constant (Kc)for this reaction under the conditions of this experiment.
(Short Answer)
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Consider the chemical reaction 2NH3(g)
N2(g)+ 3H2(g). The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 * 10-2. Initially, 1,220 moles of NH3(g)are present. Estimate the equilibrium concentration of N2(g).
(Short Answer)
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