Exam 15: Chemical Equilibrium
Exam 1: Introduction153 Questions
Exam 2: Atoms, Molecules, and Ions141 Questions
Exam 3: Stoichiometry168 Questions
Exam 4: Reactions in Aqueous Solution156 Questions
Exam 5: Gases109 Questions
Exam 6: Energy Relationships in Chemical Reactions105 Questions
Exam 7: The Electronic Structure of Atoms115 Questions
Exam 8: The Periodic Table119 Questions
Exam 9: Chemical Bonding I: the Covalent Bond118 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals120 Questions
Exam 11: Introduction to Organic Chemistry57 Questions
Exam 12: Intermolecular Forces and Liquids and Solids138 Questions
Exam 13: Physical Properties of Solutions109 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium99 Questions
Exam 16: Acids and Bases163 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria92 Questions
Exam 18: Thermodynamics112 Questions
Exam 19: Redox Reactions and Electrochemistry138 Questions
Exam 20: The Chemistry of Coordination Compounds76 Questions
Exam 21: Nuclear Chemistry112 Questions
Exam 22: Organic Polymerssynthetic and Natural42 Questions
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Consider the chemical reaction 2NH3(g)
N2(g)+ 3H2(g). The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 * 10-2. Initially, 1,220 moles of NH3(g)are present. Calculate Kp for the reaction.
(Short Answer)
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Kc for the reaction CO2(g)+ H2(g)
H2O(g)+ CO(g)is 1.6 at about 990ºC. Calculate the number of moles of water in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.
(Short Answer)
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Hydrogen iodide decomposes according to the equation 2HI(g)
H2(g)+ I2(g), for which Kc = 0.0156 at 400ºC. 0.550 mol HI was injected into a 2.00 L reaction vessel at 400ºC. Calculate the concentration of H2 at equilibrium.
(Multiple Choice)
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Consider this reaction at equilibrium at a total pressure P1: 2SO2(g)+ O2(g)
2SO3(g)
Suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished. The new equilibrium total pressure will be
(Multiple Choice)
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When the substances in the equation below are at equilibrium, at pressure P and temperature T, the equilibrium can be shifted to favor the products by CuO(s)+ H2(g)
H2O(g)+ Cu(s) Hºrxn = -2.0 kJ/mol
(Multiple Choice)
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The equilibrium constant expression for the reaction
CuO(s)+ H2(g)
Cu(s)+ H2O(g)is Kc = [H2]/[H2O].
(True/False)
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For the following reaction at equilibrium, which choice gives a change that will shift the position of equilibrium to favor formation of more products? 2NOBr(g)
2NO(g)+ Br2(g), Hºrxn = 30 kJ/mol
(Multiple Choice)
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For the reaction at equilibrium 2SO3
2SO2 + O2 ( Hºrxn= 198 kJ/mol), if we increase the reaction temperature, the equilibrium will
(Multiple Choice)
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A solution was prepared such that the initial concentrations of Cu2+(aq)and CN-(aq)were 0.0120 M and 0.0400 M, respectively. These ions react according to the following chemical equation
Cu2+(aq)+ 4CN-(aq)
Cd(CN)42-(aq)Kc = 1.0 * 1025
What will be the concentration of CN-(aq)at equilibrium?
(Essay)
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The data below refer to the following reaction:
2NO(g)+ Br2(g)
2NOBr(g)
Find the concentration of Br2 when the system reaches equilibrium.
(Short Answer)
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Which of these situations will result if some CH4(g)is removed from the reaction CO(g)+ 3H2(g)
CH4(g)+ H2O(g)at equilibrium?
(Multiple Choice)
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Consider the equilibrium equation C(s)+ H2O(g)+ 2296 J
CO(g)+ H2(g). Which way will the reaction shift if the pressure on the system is increased?
(Short Answer)
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Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl4(g)+ 1/2O2(g)
COCl2(g)+ Cl2(g), Kc = 4.4 * 109 at 1,000 K
Calculate Kc for the reaction 2CCl4(g)+ O2(g)
2COCl2(g)+ 2Cl2(g).
(Multiple Choice)
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When the reaction 2O3(g)
3O2(g), for which Kp = 3.0 * 1026 at 773ºC, is at equilibrium, the mixture will contain very little O2 as compared to O3.
(True/False)
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At 700 K, the reaction 2SO2(g)+ O2(g)
2SO3(g)has the equilibrium constant Kc = 4.3 * 106, and the following concentrations are present: [SO2] = 0.010 M; [SO3] = 10. M; [O2] = 0.010 M. Is the mixture at equilibrium? If not at equilibrium, in which direction (as the equation is written), left to right or right to left, will the reaction proceed to reach equilibrium?
(Multiple Choice)
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Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide.
CaCO3(s)
CaO(s)+ CO2(g)
KP for this reaction is 1.16 at 800°C. A 5.00 L vessel containing 10.0 g of CaCO3(s)was evacuated to remove the air, sealed, and then heated to 800°C. Ignoring the volume occupied by the solid, what will be the overall mass percent of carbon in the solid once equilibrium is reached?
(Short Answer)
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Solid ammonium hydrogen sulfide is introduced into a 2.00-L flask, and the flask is sealed. If this solid decomposes according to the equation
NH4HS(s)
NH3(g)+ H2S(g), Kp = 0.108 at 25°C,
What is the minimum mass of ammonium hydrogen sulfide that must be present in the flask initially if equilibrium is to be established at 25°C?
(Multiple Choice)
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For the following reaction at equilibrium in a reaction vessel, which one of these changes would cause the Br2 concentration to increase? 2NOBr(g)
2NO(g)+ Br2(g), Hºrxn= 30 kJ/mol
(Multiple Choice)
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For the following reaction at equilibrium, which one of the changes below would cause the equilibrium to shift to the left? 2NOBr(g)
2NO(g)+ Br2(g), Hºrxn = 30 kJ/mol
(Multiple Choice)
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