Exam 15: Chemical Equilibrium

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Consider the chemical reaction 2NH3(g) Consider the chemical reaction 2NH<sub>3</sub>(g)   N<sub>2</sub>(g)+ 3H<sub>2</sub>(g). The equilibrium is to be established in a 1.0 L container at 1,000 K, where K<sub>c</sub> = 4.0 * 10<sup>-2</sup>. Initially, 1,220 moles of NH<sub>3</sub>(g)are present. Calculate K<sub>p</sub> for the reaction. N2(g)+ 3H2(g). The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 * 10-2. Initially, 1,220 moles of NH3(g)are present. Calculate Kp for the reaction.

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Kc for the reaction CO2(g)+ H2(g) K<sub>c</sub> for the reaction CO<sub>2</sub>(g)+ H<sub>2</sub>(g)   H<sub>2</sub>O(g)+ CO(g)is 1.6 at about 990ºC. Calculate the number of moles of water in the final equilibrium system obtained by initially adding 1.00 mol of H<sub>2</sub>, 2.00 mol of CO<sub>2</sub>, 0.750 mol of H<sub>2</sub>O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC. H2O(g)+ CO(g)is 1.6 at about 990ºC. Calculate the number of moles of water in the final equilibrium system obtained by initially adding 1.00 mol of H2, 2.00 mol of CO2, 0.750 mol of H2O, and 1.00 mol of CO to a 5.00 L reactor at 990ºC.

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Hydrogen iodide decomposes according to the equation 2HI(g) Hydrogen iodide decomposes according to the equation 2HI(g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g), for which K<sub>c</sub> = 0.0156 at 400ºC. 0.550 mol HI was injected into a 2.00 L reaction vessel at 400ºC. Calculate the concentration of H<sub>2</sub> at equilibrium. H2(g)+ I2(g), for which Kc = 0.0156 at 400ºC. 0.550 mol HI was injected into a 2.00 L reaction vessel at 400ºC. Calculate the concentration of H2 at equilibrium.

(Multiple Choice)
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Consider this reaction at equilibrium at a total pressure P1: 2SO2(g)+ O2(g) Consider this reaction at equilibrium at a total pressure P<sub>1</sub>: 2SO<sub>2</sub>(g)+ O<sub>2</sub>(g)  2SO<sub>3</sub>(g) Suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished. The new equilibrium total pressure will be2SO3(g) Suppose the volume of this system is compressed to one-half its initial volume and then equilibrium is reestablished. The new equilibrium total pressure will be

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When the substances in the equation below are at equilibrium, at pressure P and temperature T, the equilibrium can be shifted to favor the products by CuO(s)+ H2(g)  When the substances in the equation below are at equilibrium, at pressure P and temperature T, the equilibrium can be shifted to favor the products by CuO(s)+ H<sub>2</sub>(g)   H<sub>2</sub>O(g)+ Cu(s) \Delta Hº<sub>rxn</sub> = -2.0 kJ/mol H2O(g)+ Cu(s) Δ\Delta Hºrxn = -2.0 kJ/mol

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The equilibrium constant expression for the reaction CuO(s)+ H2(g) The equilibrium constant expression for the reaction CuO(s)+ H<sub>2</sub>(g)   Cu(s)+ H<sub>2</sub>O(g)is K<sub>c</sub> = [H<sub>2</sub>]/[H<sub>2</sub>O]. Cu(s)+ H2O(g)is Kc = [H2]/[H2O].

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For the following reaction at equilibrium, which choice gives a change that will shift the position of equilibrium to favor formation of more products? 2NOBr(g)  For the following reaction at equilibrium, which choice gives a change that will shift the position of equilibrium to favor formation of more products? 2NOBr(g)   2NO(g)+ Br<sub>2</sub>(g),  \Delta Hº<sub>rxn</sub> = 30 kJ/mol 2NO(g)+ Br2(g), Δ\Delta Hºrxn = 30 kJ/mol

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For the reaction at equilibrium 2SO3  For the reaction at equilibrium 2SO<sub>3</sub>   2SO<sub>2</sub> + O<sub>2</sub> <sub> </sub>( \Delta Hº<sub>rxn</sub>= 198 kJ/mol), if we increase the reaction temperature, the equilibrium will 2SO2 + O2 ( Δ\Delta Hºrxn= 198 kJ/mol), if we increase the reaction temperature, the equilibrium will

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For the reaction H2(g)+ I2(g) For the reaction H<sub>2</sub>(g)+ I<sub>2</sub>(g)   2HI(g), K<sub>P</sub> = K<sub>c</sub>. 2HI(g), KP = Kc.

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A solution was prepared such that the initial concentrations of Cu2+(aq)and CN-(aq)were 0.0120 M and 0.0400 M, respectively. These ions react according to the following chemical equation Cu2+(aq)+ 4CN-(aq) A solution was prepared such that the initial concentrations of Cu<sup>2+</sup>(aq)and CN<sup>-</sup>(aq)were 0.0120 M and 0.0400 M, respectively. These ions react according to the following chemical equation Cu<sup>2+</sup>(aq)+ 4CN<sup>-</sup>(aq)   Cd(CN)<sub>4</sub><sup>2-</sup>(aq)K<sub>c</sub> = 1.0 * 10<sup>25</sup> <sup> </sup>What will be the concentration of CN<sup>-</sup>(aq)at equilibrium? Cd(CN)42-(aq)Kc = 1.0 * 1025 What will be the concentration of CN-(aq)at equilibrium?

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The data below refer to the following reaction: 2NO(g)+ Br2(g) The data below refer to the following reaction: 2NO(g)+ Br<sub>2</sub>(g)   2NOBr(g)   Find the concentration of Br<sub>2</sub> when the system reaches equilibrium. 2NOBr(g) The data below refer to the following reaction: 2NO(g)+ Br<sub>2</sub>(g)   2NOBr(g)   Find the concentration of Br<sub>2</sub> when the system reaches equilibrium. Find the concentration of Br2 when the system reaches equilibrium.

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Which of these situations will result if some CH4(g)is removed from the reaction CO(g)+ 3H2(g) Which of these situations will result if some CH<sub>4</sub>(g)is removed from the reaction CO(g)+ 3H<sub>2</sub>(g)   CH<sub>4</sub>(g)+ H<sub>2</sub>O(g)at equilibrium? CH4(g)+ H2O(g)at equilibrium?

(Multiple Choice)
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Consider the equilibrium equation C(s)+ H2O(g)+ 2296 J Consider the equilibrium equation C(s)+ H<sub>2</sub>O(g)+ 2296 J    CO(g)+ H<sub>2</sub>(g). Which way will the reaction shift if the pressure on the system is increased? CO(g)+ H2(g). Which way will the reaction shift if the pressure on the system is increased?

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Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl4(g)+ 1/2O2(g) Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl<sub>4</sub>(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub>COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g), K<sub>c</sub> = 4.4 * 10<sup>9</sup> at 1,000 K Calculate K<sub>c</sub> for the reaction 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   <sub> </sub>2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g). COCl2(g)+ Cl2(g), Kc = 4.4 * 109 at 1,000 K Calculate Kc for the reaction 2CCl4(g)+ O2(g) Carbon tetrachloride reacts at high temperatures with oxygen to produce two toxic gases, phosgene and chlorine. CCl<sub>4</sub>(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub>COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g), K<sub>c</sub> = 4.4 * 10<sup>9</sup> at 1,000 K Calculate K<sub>c</sub> for the reaction 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   <sub> </sub>2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g). 2COCl2(g)+ 2Cl2(g).

(Multiple Choice)
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When the reaction 2O3(g) When the reaction 2O<sub>3</sub>(g)   3O<sub>2</sub>(g), for which K<sub>p</sub> = 3.0 * 10<sup>26</sup> at 773ºC, is at equilibrium, the mixture will contain very little O<sub>2</sub> as compared to O<sub>3</sub>. 3O2(g), for which Kp = 3.0 * 1026 at 773ºC, is at equilibrium, the mixture will contain very little O2 as compared to O3.

(True/False)
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At 700 K, the reaction 2SO2(g)+ O2(g) At 700 K, the reaction 2SO<sub>2</sub>(g)+ O<sub>2</sub>(g)   2SO<sub>3</sub>(g)has the equilibrium constant K<sub>c</sub> = 4.3 * 10<sup>6</sup>, and the following concentrations are present: [SO<sub>2</sub>] = 0.010 M; [SO<sub>3</sub>] = 10. M; [O<sub>2</sub>] = 0.010 M. Is the mixture at equilibrium? If not at equilibrium, in which direction (as the equation is written), left to right or right to left, will the reaction proceed to reach equilibrium? 2SO3(g)has the equilibrium constant Kc = 4.3 * 106, and the following concentrations are present: [SO2] = 0.010 M; [SO3] = 10. M; [O2] = 0.010 M. Is the mixture at equilibrium? If not at equilibrium, in which direction (as the equation is written), left to right or right to left, will the reaction proceed to reach equilibrium?

(Multiple Choice)
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Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide. CaCO3(s) Calcium carbonate decomposes at high temperatures to give calcium oxide and carbon dioxide. CaCO<sub>3</sub>(s)   CaO(s)+ CO<sub>2</sub>(g) K<sub>P</sub> for this reaction is 1.16 at 800°C. A 5.00 L vessel containing 10.0 g of CaCO<sub>3</sub>(s)was evacuated to remove the air, sealed, and then heated to 800°C. Ignoring the volume occupied by the solid, what will be the overall mass percent of carbon in the solid once equilibrium is reached? CaO(s)+ CO2(g) KP for this reaction is 1.16 at 800°C. A 5.00 L vessel containing 10.0 g of CaCO3(s)was evacuated to remove the air, sealed, and then heated to 800°C. Ignoring the volume occupied by the solid, what will be the overall mass percent of carbon in the solid once equilibrium is reached?

(Short Answer)
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Solid ammonium hydrogen sulfide is introduced into a 2.00-L flask, and the flask is sealed. If this solid decomposes according to the equation NH4HS(s) Solid ammonium hydrogen sulfide is introduced into a 2.00-L flask, and the flask is sealed. If this solid decomposes according to the equation NH<sub>4</sub>HS(s)<sub> </sub> <sub> </sub>   NH<sub>3</sub>(g)+ H<sub>2</sub>S(g), K<sub>p</sub> = 0.108 at 25°C, What is the minimum mass of ammonium hydrogen sulfide that must be present in the flask initially if equilibrium is to be established at 25°C? NH3(g)+ H2S(g), Kp = 0.108 at 25°C, What is the minimum mass of ammonium hydrogen sulfide that must be present in the flask initially if equilibrium is to be established at 25°C?

(Multiple Choice)
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For the following reaction at equilibrium in a reaction vessel, which one of these changes would cause the Br2 concentration to increase? 2NOBr(g)  For the following reaction at equilibrium in a reaction vessel, which one of these changes would cause the Br<sub>2</sub> concentration to increase? 2NOBr(g)   2NO(g)+ Br<sub>2</sub>(g),  \Delta Hº<sub>rxn</sub>= 30 kJ/mol 2NO(g)+ Br2(g), Δ\Delta Hºrxn= 30 kJ/mol

(Multiple Choice)
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For the following reaction at equilibrium, which one of the changes below would cause the equilibrium to shift to the left? 2NOBr(g)  For the following reaction at equilibrium, which one of the changes below would cause the equilibrium to shift to the left? 2NOBr(g)   2NO(g)+ Br<sub>2</sub>(g),  \Delta Hº<sub>rxn</sub> = 30 kJ/mol 2NO(g)+ Br2(g), Δ\Delta Hºrxn = 30 kJ/mol

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