Exam 6: Energy Relationships in Chemical Reactions
Exam 1: Introduction153 Questions
Exam 2: Atoms, Molecules, and Ions141 Questions
Exam 3: Stoichiometry168 Questions
Exam 4: Reactions in Aqueous Solution156 Questions
Exam 5: Gases109 Questions
Exam 6: Energy Relationships in Chemical Reactions105 Questions
Exam 7: The Electronic Structure of Atoms115 Questions
Exam 8: The Periodic Table119 Questions
Exam 9: Chemical Bonding I: the Covalent Bond118 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals120 Questions
Exam 11: Introduction to Organic Chemistry57 Questions
Exam 12: Intermolecular Forces and Liquids and Solids138 Questions
Exam 13: Physical Properties of Solutions109 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium99 Questions
Exam 16: Acids and Bases163 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria92 Questions
Exam 18: Thermodynamics112 Questions
Exam 19: Redox Reactions and Electrochemistry138 Questions
Exam 20: The Chemistry of Coordination Compounds76 Questions
Exam 21: Nuclear Chemistry112 Questions
Exam 22: Organic Polymerssynthetic and Natural42 Questions
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A piece of copper with a mass of 218 g has a heat capacity of 83.9 J/°C. What is the specific heat of copper?
(Multiple Choice)
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The combustion of one mole of benzene, C6H6, in oxygen liberates 3268 kJ of heat. The products of the reaction are carbon dioxide and water. How much heat is given off when 183 g of oxygen are reacted with excess benzene?
(Short Answer)
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A gas is compressed in a cylinder from a volume of 20.0 L to 2.0 L by a constant pressure of 10.0 atm. Calculate the amount of work done on the system.
(Multiple Choice)
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Given the following H° values,
H2(g)+
O2(g) H2O(l) H°f = -285.8 kJ/mol
H2O2(l) H2(g)+ O2(g) H°rxn = 187.6 kJ/mol
calculate H°rxn for the reaction H2O2(l) H2O(l)+
O2(g),
(Short Answer)
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The heat released when one mole of water is formed from the elements is 1,198 kJ. An experiment was conducted that permitted water to form in this manner, and the heat was contained in 2.0 liters of water. The water temperature before the reaction was 34.5°C, and after the reaction it had risen to 52.0°C. How many moles of water were formed? (The specific heat of water is 4.184 J/g·°C.)
(Short Answer)
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The heat of combustion of propane, C3H8, 2220 kJ/mol. The specific heat of copper is 0.385 J/g.°C. How many grams of propane must be burned to raise the temperature of a 10.0 kg block of copper from 25.0°C to 65.0°C, assuming none of the heat is lost to the surroundings?
(Short Answer)
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A 0.1946 g piece of magnesium metal is burned in a constant-volume calorimeter that has a heat capacity of 1349 J/°C. The calorimeter contains 500. g of water and the temperature rise is 1.40°C. Calculate the heat of combustion of magnesium metal in kJ/g, given that the specific heat of water = 4.184 J/g·°C.
(Short Answer)
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If 2Mg(s)+ O2(g) 2MgO(s), H° = -1203.6 kJ/mol.
For Mg(s)+ (1/2)O2(g) MgO(s), the enthalpy change is H = -601.8 kJ/mol.
(True/False)
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Find H°rxn for the reaction
2Na(s)+ 2H2O(l) 2NaOH(aq)+ 2H2(g).
[ H°f (NaOH(aq))= -426.8 kJ/mol; H°f (H2O(l))= -285.5 kJ/mol]
(Short Answer)
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The heat of solution of ammonium nitrate is 26.2 kJ/mol. If a 5.368 g sample of NH4NO3 is added to 40.0 mL of water in a calorimeter at 23.5°C, what is the minimum temperature reached by the solution? (The specific heat of water = 4.18 J/g·°C; the heat capacity of the calorimeter = 650. J/°C.)
(Multiple Choice)
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The combustion of butane produces heat according to the equation 2C4H10(g)+ 13O2(g) 8CO2(g)+ 10H2O(l) H°rxn = -5,314 kJ/mol
What is the heat of combustion per gram of butane?
(Multiple Choice)
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The combustion of octane produces heat according to the equation 2C8H18(l)+ 25O2(g) 16CO2(g)+ 18H2O(l) H°rxn= -11,020 kJ/mol
What is the heat of combustion per gram of octane?
(Multiple Choice)
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A 0.1326 g sample of magnesium was burned in an oxygen bomb calorimeter. The total heat capacity of the calorimeter plus water was 5,760 J/°C. If the temperature rise of the calorimeter with water was 0.570°C, calculate the enthalpy of combustion of magnesium. Mg(s)+ 1/2O2(g) MgO(s)
(Multiple Choice)
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A 100. mL sample of 0.200 M aqueous hydrochloric acid is added to 100. mL of 0.200 M aqueous ammonia in a calorimeter whose heat capacity (excluding any water)is 480. J/K. The following reaction occurs when the two solutions are mixed. HCl(aq)+ NH3(aq) NH4Cl(aq)
The temperature increase is 2.34°C. Calculate H per mole of HCl and NH3 reacted.
(Multiple Choice)
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Find the heat absorbed from the surroundings when 15 g of O2 reacts according to the equation O + O2 O3, H°rxn= -103 kJ/mol.
(Multiple Choice)
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Naphthalene combustion can be used to calibrate the heat capacity of a bomb calorimeter. The heat of combustion of naphthalene is -40.1 kJ/g. When 0.8210 g of naphthalene was burned in a calorimeter containing 1,000. g of water, a temperature rise of 4.21°C was observed. What is the heat capacity of the bomb calorimeter excluding the water?
(Multiple Choice)
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Calcium oxide and water react in an exothermic reaction: CaO(s)+ H2O(l) Ca(OH)2(s) H°rxn = -64.8 kJ/mol
How much heat would be liberated when 7.15 g CaO(s)is dropped into a beaker containing 152g H2O?
(Multiple Choice)
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Ethanol (C2H5OH)burns according to the equation C2H5OH(l)+ 3O2(g) 2CO2(g)+ 3H2O(l), H°rxn = -1367 kJ/mol.
How much heat is released when 35.0 g of ethanol is burned?
(Multiple Choice)
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