Exam 6: Energy Relationships in Chemical Reactions

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A piece of copper with a mass of 218 g has a heat capacity of 83.9 J/°C. What is the specific heat of copper?

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The combustion of one mole of benzene, C6H6, in oxygen liberates 3268 kJ of heat. The products of the reaction are carbon dioxide and water. How much heat is given off when 183 g of oxygen are reacted with excess benzene?

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A gas is compressed in a cylinder from a volume of 20.0 L to 2.0 L by a constant pressure of 10.0 atm. Calculate the amount of work done on the system.

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Given the following Δ\Delta H° values, H2(g)+  Given the following  \Delta H° values, H<sub>2</sub>(g)+   O<sub>2</sub>(g) \rarr  H<sub>2</sub>O(l) \Delta H°<sub>f</sub> = -285.8 kJ/mol H<sub>2</sub>O<sub>2</sub>(l) \rarr  H<sub>2</sub>(g)+ O<sub>2</sub>(g) \Delta H°<sub>rxn</sub> = 187.6 kJ/mol calculate  \Delta H°<sub>rxn</sub> for the reaction H<sub>2</sub>O<sub>2</sub>(l) \rarr H<sub>2</sub>O(l)+   O<sub>2</sub>(g), O2(g) →\rarr H2O(l) Δ\Delta H°f = -285.8 kJ/mol H2O2(l) →\rarr H2(g)+ O2(g) Δ\Delta H°rxn = 187.6 kJ/mol calculate Δ\Delta H°rxn for the reaction H2O2(l) →\rarr H2O(l)+  Given the following  \Delta H° values, H<sub>2</sub>(g)+   O<sub>2</sub>(g) \rarr  H<sub>2</sub>O(l) \Delta H°<sub>f</sub> = -285.8 kJ/mol H<sub>2</sub>O<sub>2</sub>(l) \rarr  H<sub>2</sub>(g)+ O<sub>2</sub>(g) \Delta H°<sub>rxn</sub> = 187.6 kJ/mol calculate  \Delta H°<sub>rxn</sub> for the reaction H<sub>2</sub>O<sub>2</sub>(l) \rarr H<sub>2</sub>O(l)+   O<sub>2</sub>(g), O2(g),

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The heat released when one mole of water is formed from the elements is 1,198 kJ. An experiment was conducted that permitted water to form in this manner, and the heat was contained in 2.0 liters of water. The water temperature before the reaction was 34.5°C, and after the reaction it had risen to 52.0°C. How many moles of water were formed? (The specific heat of water is 4.184 J/g·°C.)

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The heat of combustion of propane, C3H8, 2220 kJ/mol. The specific heat of copper is 0.385 J/g.°C. How many grams of propane must be burned to raise the temperature of a 10.0 kg block of copper from 25.0°C to 65.0°C, assuming none of the heat is lost to the surroundings?

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A 0.1946 g piece of magnesium metal is burned in a constant-volume calorimeter that has a heat capacity of 1349 J/°C. The calorimeter contains 500. g of water and the temperature rise is 1.40°C. Calculate the heat of combustion of magnesium metal in kJ/g, given that the specific heat of water = 4.184 J/g·°C.

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If 2Mg(s)+ O2(g) →\rarr 2MgO(s), Δ\Delta H° = -1203.6 kJ/mol. For Mg(s)+ (1/2)O2(g) →\rarr MgO(s), the enthalpy change is Δ\Delta H = -601.8 kJ/mol.

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Thermal energy is

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Find Δ\Delta H°rxn for the reaction 2Na(s)+ 2H2O(l) →\rarr 2NaOH(aq)+ 2H2(g). [ Δ\Delta H°f (NaOH(aq))= -426.8 kJ/mol; Δ\Delta H°f (H2O(l))= -285.5 kJ/mol]

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The heat of solution of ammonium nitrate is 26.2 kJ/mol. If a 5.368 g sample of NH4NO3 is added to 40.0 mL of water in a calorimeter at 23.5°C, what is the minimum temperature reached by the solution? (The specific heat of water = 4.18 J/g·°C; the heat capacity of the calorimeter = 650. J/°C.)

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The combustion of butane produces heat according to the equation 2C4H10(g)+ 13O2(g) →\rarr 8CO2(g)+ 10H2O(l) Δ\Delta H°rxn = -5,314 kJ/mol What is the heat of combustion per gram of butane?

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The combustion of octane produces heat according to the equation 2C8H18(l)+ 25O2(g) →\rarr 16CO2(g)+ 18H2O(l) Δ\Delta H°rxn= -11,020 kJ/mol What is the heat of combustion per gram of octane?

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A 0.1326 g sample of magnesium was burned in an oxygen bomb calorimeter. The total heat capacity of the calorimeter plus water was 5,760 J/°C. If the temperature rise of the calorimeter with water was 0.570°C, calculate the enthalpy of combustion of magnesium. Mg(s)+ 1/2O2(g) →\rarr MgO(s)

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A 100. mL sample of 0.200 M aqueous hydrochloric acid is added to 100. mL of 0.200 M aqueous ammonia in a calorimeter whose heat capacity (excluding any water)is 480. J/K. The following reaction occurs when the two solutions are mixed. HCl(aq)+ NH3(aq) →\rarr NH4Cl(aq) The temperature increase is 2.34°C. Calculate Δ\Delta H per mole of HCl and NH3 reacted.

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Find the heat absorbed from the surroundings when 15 g of O2 reacts according to the equation O + O2 →\rarr O3, Δ\Delta H°rxn= -103 kJ/mol.

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Naphthalene combustion can be used to calibrate the heat capacity of a bomb calorimeter. The heat of combustion of naphthalene is -40.1 kJ/g. When 0.8210 g of naphthalene was burned in a calorimeter containing 1,000. g of water, a temperature rise of 4.21°C was observed. What is the heat capacity of the bomb calorimeter excluding the water?

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Define specific heat.

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Calcium oxide and water react in an exothermic reaction: CaO(s)+ H2O(l) →\rarr Ca(OH)2(s) Δ\Delta H°rxn = -64.8 kJ/mol How much heat would be liberated when 7.15 g CaO(s)is dropped into a beaker containing 152g H2O?

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Ethanol (C2H5OH)burns according to the equation C2H5OH(l)+ 3O2(g) →\rarr 2CO2(g)+ 3H2O(l), Δ\Delta H°rxn = -1367 kJ/mol. How much heat is released when 35.0 g of ethanol is burned?

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