Exam 6: Energy Relationships in Chemical Reactions

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Given H2(g)+ (1/2)O2(g) →\rarr H2O(l), Δ\Delta H° = -286 kJ/mol, determine the standard enthalpy change for the reaction 2H2O(l) →\rarr 2H2(g)+ O2(g).

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Potential energy is

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A gas is allowed to expand, at constant temperature, from a volume of 1.0 L to 10.1 L against an external pressure of 0.50 atm. If the gas absorbs 250 J of heat from the surroundings, what are the values of q, w, and Δ\Delta E?  A gas is allowed to expand, at constant temperature, from a volume of 1.0 L to 10.1 L against an external pressure of 0.50 atm. If the gas absorbs 250 J of heat from the surroundings, what are the values of q, w, and  \Delta E?

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Chemical energy is

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For the reaction C(graphite)+ O2(g) →\rarr CO2(g) Δ\Delta H° = -393 kJ/mol How many grams of C(graphite)must be burned to release 275 kJ of heat?

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A 26.2 g piece of copper metal is heated from 21.5°C to 201.6°C. Calculate the amount of heat absorbed by the metal. The specific heat of Cu is 0.385 J/g·°C.

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A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter. The temperature of the calorimeter and the 1.000 kg of water contained therein rose from 20.22°C to 22.82°C. The heat capacity of the calorimeter is 2.21 kJ/°C. The heat capacity of water = 4.184 J/g·°C. What is the heat of combustion, in kilojoules, per gram of pentane?

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The combustion of butane produces heat according to the equation 2C4H10(g)+ 13O2(g) →\rarr 0 8CO2(g)+ 10H2O(l) Δ\Delta H°rxn= -5,314 kJ/mol How many grams of butane must be burned to release 1.00 * 104 kJ of heat?

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When 0.560 g of Na(s)reacts with excess F2(g)to form NaF(s), 13.8 kJ of heat is evolved at standard-state conditions. What is the standard enthalpy of formation ( Δ\Delta H°f)of NaF(s)?

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The combustion of pentane produces heat according to the equation C5H12(l)+ 8O2(g) →\rarr 5CO2(g)+ 6H2O(l) Δ\Delta H°rxn= -3,510 kJ/mol How many grams of CO2 are produced per 2.50 * 103 kJ of heat released?

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Ethanol undergoes combustion in oxygen to produce carbon dioxide gas and liquid water. The standard heat of combustion of ethanol, C2H5OH(l), is -1366.8 kJ/mol. Given that Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol and Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, what is the standard enthalpy of formation of ethanol?

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Find Δ\Delta H°rxn for the reaction CH4(g)+ 2O2(g) →\rarr CO2(g)+ 2H2O(l). [ Δ\Delta H°f (CH4(g))= -74.8 kJ/mol; Δ\Delta H°f (CO2(g))= -393.5 kJ/mol; Δ\Delta H°f (H2O(l))= -285.5 kJ/mol]

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The heat capacity of 20.0 g of water is 83.7 J/°C.

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Styrene, C8H8, is one of the substances used in the production of synthetic rubber. When styrene burns in oxygen to form carbon dioxide and liquid water under standard-state conditions at 25°C, 42.62 kJ are released per gram of styrene. Find the standard enthalpy of formation of styrene at 25°C. (Given: Δ\Delta H°f[CO2(g)] = -393.5 kJ/mol, Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol, Δ\Delta H°f[H2O(g)] = -241.8 kJ/mol)

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Methanol (CH3OH)burns according to the equation 2CH3OH(l)+ 3O2(g) →\rarr 2CO2(g)+ 4H2O(l), Δ\Delta H°rxn = -1454 kJ/mol. How much heat, in kilojoules, is given off when 75.0 g of methanol is burned?

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Solid sodium peroxide (Na2O2)reacts with liquid water yielding aqueous sodium hydroxide and oxygen gas. How much heat is released when 250.0 L of oxygen gas is produced from the reaction of sodium peroxide and water if the reaction is carried out in an open container at 1.000 atm pressure and 25°C? (Given: Δ\Delta H°f[Na2O2(s)] = -510.9 kJ/mol; Δ\Delta H°f[NaOH(aq)] = -469.2 kJ/mol; Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol)

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Pentaborane B5H9(s)burns vigorously in O2 to give B2O3(s)and H2O(l). Calculate Δ\Delta H°rxn for the combustion of 1 mol of B5H9. Δ\Delta 0H°f[B2O3(s)] = -1,273.5 kJ/mol Δ\Delta H°f[B5H9(s)] = 73.2 kJ/mol Δ\Delta H°f[H2O(l)] = -285.8 kJ/mol

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At 25°C, the following heats of reaction are known:  At 25°C, the following heats of reaction are known:   At the same temperature, use Hess's law to calculate  \Delta H°<sub>rxn</sub> for the reaction: ClF(g)+ F<sub>2</sub>(g) \rarr  ClF<sub>3</sub>(g) At the same temperature, use Hess's law to calculate Δ\Delta H°rxn for the reaction: ClF(g)+ F2(g) →\rarr ClF3(g)

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The value of Δ\Delta H°rxn for the following reaction is -6535 kJ/mol. 2C6H6(l)+ 15O2(g) →\rarr 12CO2(g)+ 6H2O(g) How many kilojoules of heat will be evolved during the combustion of 16.0 g of C6H6(l)?

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The heat absorbed by a system at constant pressure is equal to Δ\Delta E + P Δ\Delta V.

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