Exam 6: Energy Relationships in Chemical Reactions
Exam 1: Introduction153 Questions
Exam 2: Atoms, Molecules, and Ions141 Questions
Exam 3: Stoichiometry168 Questions
Exam 4: Reactions in Aqueous Solution156 Questions
Exam 5: Gases109 Questions
Exam 6: Energy Relationships in Chemical Reactions105 Questions
Exam 7: The Electronic Structure of Atoms115 Questions
Exam 8: The Periodic Table119 Questions
Exam 9: Chemical Bonding I: the Covalent Bond118 Questions
Exam 10: Chemical Bonding Ii: Molecular Geometry and Hybridization of Atomic Orbitals120 Questions
Exam 11: Introduction to Organic Chemistry57 Questions
Exam 12: Intermolecular Forces and Liquids and Solids138 Questions
Exam 13: Physical Properties of Solutions109 Questions
Exam 14: Chemical Kinetics114 Questions
Exam 15: Chemical Equilibrium99 Questions
Exam 16: Acids and Bases163 Questions
Exam 17: Acid-Base Equilibria and Solubility Equilibria92 Questions
Exam 18: Thermodynamics112 Questions
Exam 19: Redox Reactions and Electrochemistry138 Questions
Exam 20: The Chemistry of Coordination Compounds76 Questions
Exam 21: Nuclear Chemistry112 Questions
Exam 22: Organic Polymerssynthetic and Natural42 Questions
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Given H2(g)+ (1/2)O2(g) H2O(l), H° = -286 kJ/mol, determine the standard enthalpy change for the reaction 2H2O(l) 2H2(g)+ O2(g).
(Multiple Choice)
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A gas is allowed to expand, at constant temperature, from a volume of 1.0 L to 10.1 L against an external pressure of 0.50 atm. If the gas absorbs 250 J of heat from the surroundings, what are the values of q, w, and E?
(Multiple Choice)
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For the reaction C(graphite)+ O2(g) CO2(g) H° = -393 kJ/mol
How many grams of C(graphite)must be burned to release 275 kJ of heat?
(Multiple Choice)
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A 26.2 g piece of copper metal is heated from 21.5°C to 201.6°C. Calculate the amount of heat absorbed by the metal. The specific heat of Cu is 0.385 J/g·°C.
(Short Answer)
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A 0.3423 g sample of pentane, C5H12, was burned in a bomb calorimeter. The temperature of the calorimeter and the 1.000 kg of water contained therein rose from 20.22°C to 22.82°C. The heat capacity of the calorimeter is 2.21 kJ/°C. The heat capacity of water = 4.184 J/g·°C. What is the heat of combustion, in kilojoules, per gram of pentane?
(Short Answer)
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The combustion of butane produces heat according to the equation 2C4H10(g)+ 13O2(g) 0 8CO2(g)+ 10H2O(l) H°rxn= -5,314 kJ/mol
How many grams of butane must be burned to release 1.00 * 104 kJ of heat?
(Multiple Choice)
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When 0.560 g of Na(s)reacts with excess F2(g)to form NaF(s), 13.8 kJ of heat is evolved at standard-state conditions. What is the standard enthalpy of formation ( H°f)of NaF(s)?
(Multiple Choice)
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The combustion of pentane produces heat according to the equation C5H12(l)+ 8O2(g) 5CO2(g)+ 6H2O(l) H°rxn= -3,510 kJ/mol
How many grams of CO2 are produced per 2.50 * 103 kJ of heat released?
(Multiple Choice)
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Ethanol undergoes combustion in oxygen to produce carbon dioxide gas and liquid water. The standard heat of combustion of ethanol, C2H5OH(l), is -1366.8 kJ/mol. Given that H°f[CO2(g)] = -393.5 kJ/mol and H°f[H2O(l)] = -285.8 kJ/mol, what is the standard enthalpy of formation of ethanol?
(Multiple Choice)
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Find H°rxn for the reaction
CH4(g)+ 2O2(g) CO2(g)+ 2H2O(l).
[ H°f (CH4(g))= -74.8 kJ/mol; H°f (CO2(g))= -393.5 kJ/mol; H°f (H2O(l))= -285.5 kJ/mol]
(Short Answer)
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Styrene, C8H8, is one of the substances used in the production of synthetic rubber. When styrene burns in oxygen to form carbon dioxide and liquid water under standard-state conditions at 25°C, 42.62 kJ are released per gram of styrene. Find the standard enthalpy of formation of styrene at 25°C. (Given: H°f[CO2(g)] = -393.5 kJ/mol, H°f[H2O(l)] = -285.8 kJ/mol, H°f[H2O(g)] = -241.8 kJ/mol)
(Multiple Choice)
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Methanol (CH3OH)burns according to the equation 2CH3OH(l)+ 3O2(g) 2CO2(g)+ 4H2O(l), H°rxn = -1454 kJ/mol.
How much heat, in kilojoules, is given off when 75.0 g of methanol is burned?
(Multiple Choice)
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Solid sodium peroxide (Na2O2)reacts with liquid water yielding aqueous sodium hydroxide and oxygen gas. How much heat is released when 250.0 L of oxygen gas is produced from the reaction of sodium peroxide and water if the reaction is carried out in an open container at 1.000 atm pressure and 25°C? (Given: H°f[Na2O2(s)] = -510.9 kJ/mol; H°f[NaOH(aq)] = -469.2 kJ/mol; H°f[H2O(l)] = -285.8 kJ/mol)
(Multiple Choice)
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Pentaborane B5H9(s)burns vigorously in O2 to give B2O3(s)and H2O(l). Calculate H°rxn for the combustion of 1 mol of B5H9. 0H°f[B2O3(s)] = -1,273.5 kJ/mol
H°f[B5H9(s)] = 73.2 kJ/mol
H°f[H2O(l)] = -285.8 kJ/mol
(Multiple Choice)
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At 25°C, the following heats of reaction are known:
At the same temperature, use Hess's law to calculate H°rxn for the reaction: ClF(g)+ F2(g) ClF3(g)
(Multiple Choice)
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The value of H°rxn for the following reaction is -6535 kJ/mol.
2C6H6(l)+ 15O2(g) 12CO2(g)+ 6H2O(g)
How many kilojoules of heat will be evolved during the combustion of 16.0 g of C6H6(l)?
(Short Answer)
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The heat absorbed by a system at constant pressure is equal to E + P V.
(True/False)
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